Silver Anniversary of the Renaissance in Metallocorrole Chemistry DOI
Atif Mahammed, Harry B. Gray, Zeev Gross

et al.

Chemical Reviews, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 12, 2025

The 1999 discovery of one-pot corrole synthesis opened the floodgates for research on these unique macrocyclic chelating agents. enormous impact this has been documented in numerous reviews describing advances synthetic chemistry corroles and selected applications which are key components. Our silver anniversary review focuses structures reactions all well characterized corrole-chelated d- p-block metal complexes, including discussions their electronic excited-state physics chemistry. Emphasis is placed structure trinegative N4 coordination core, stabilizes high-valent metals activates low-valent ones, and, importantly, profoundly influences ground- reactivity. story highlights properties that have made them molecular components choice a plethora applications. These include utility sensing gases anions, rescue vital biomolecules from oxidative damage, destruction cancerous cells, catalysis critical organic synthesis, as those involved clean energy processes such production hydrogen reduction oxygen. In our view, will continue to grow by leaps bounds, most especially areas human health renewable science technology.

Language: Английский

mer-[InCl3(C5D5N)3]2·C5D5N: A New d5-pyridine Derivative of Indium(III) Chloride Complex DOI Open Access
Ali Tuna, Anastassios C. Papageorgiou, Anssi Peuronen

et al.

Journal of the Turkish Chemical Society Section A Chemistry, Journal Year: 2025, Volume and Issue: 12(1), P. 15 - 22

Published: Feb. 1, 2025

In this study, we report the crystal structure of a meridional octahedral pyridine-indium(III) chloride adduct, mer-trichlorotris(d5-pyridine)indium(III)·0.5(d5-pyridine), InCl3(C5D5N)3·0.5(C5D5N), which exhibits an unreported molecule-to-solvent ratio compared to other substituted and unsubstituted adducts described in earlier literature. The bonding characteristics d5-pyridine complex are analogous complexes that have already been reported. Furthermore, role metal indium insertion into corrole ligands is discussed.

Language: Английский

Citations

0
Silver Anniversary of the Renaissance in Metallocorrole Chemistry DOI
Atif Mahammed, Harry B. Gray, Zeev Gross

et al.

Chemical Reviews, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 12, 2025

The 1999 discovery of one-pot corrole synthesis opened the floodgates for research on these unique macrocyclic chelating agents. enormous impact this has been documented in numerous reviews describing advances synthetic chemistry corroles and selected applications which are key components. Our silver anniversary review focuses structures reactions all well characterized corrole-chelated d- p-block metal complexes, including discussions their electronic excited-state physics chemistry. Emphasis is placed structure trinegative N4 coordination core, stabilizes high-valent metals activates low-valent ones, and, importantly, profoundly influences ground- reactivity. story highlights properties that have made them molecular components choice a plethora applications. These include utility sensing gases anions, rescue vital biomolecules from oxidative damage, destruction cancerous cells, catalysis critical organic synthesis, as those involved clean energy processes such production hydrogen reduction oxygen. In our view, will continue to grow by leaps bounds, most especially areas human health renewable science technology.

Language: Английский

Citations

0