Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 160151 - 160151
Published: Feb. 1, 2025
Language: Английский
Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 160151 - 160151
Published: Feb. 1, 2025
Language: Английский
Science China Chemistry, Journal Year: 2023, Volume and Issue: 66(7), P. 1886 - 1904
Published: June 9, 2023
Language: Английский
Citations
14Chemical Synthesis, Journal Year: 2024, Volume and Issue: 4(3)
Published: July 8, 2024
A new method was developed for post-modification of porous aromatic framework-1 (PAF-1) with chloride and then amine groups confirmed by different characterizations such as nuclear magnetic resonance (NMR), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared (FTIR). Compared to PAF-1, the amine-functionalized PAF-1 (PAF-1-NH2) exhibits a 50% improvement in carbon dioxide (CO2) adsorption capacity reaching 42 cm3·g-1 at room temperature 1 bar, uptakes under CO2 concentration air (4 kPa) flue gas (150 also greatly increase. The column breakthrough experiments showed that PAF-1-NH2 can separate from simulated CO2/N2 (15:85, v/v) indicating its potential applications post-combustion systems.
Language: Английский
Citations
5ChemSusChem, Journal Year: 2023, Volume and Issue: 17(7)
Published: Dec. 18, 2023
Electrochemical CO
Language: Английский
Citations
11AIChE Journal, Journal Year: 2024, Volume and Issue: 70(6)
Published: March 4, 2024
Abstract CO 2 electrolysis to value‐added chemicals and fuels shows tremendous potential store renewable electricity. It features with H O as the hydrogen source of electroreduction. Here, we aim at effect hydrophobicity‐tuned catalyst microenvironment in gas diffusion electrode (GDE) on boosting electrolysis. The hydrophobic polytetrafluoroethylene (PTFE) nanoparticles are introduced Sn layer GDE. PTFE‐modified GDE compared non‐PTFE delivers a higher HCOOH Faraday efficiency lower overpotential current densities 50–250 mA cm −2 . A two‐dimensional axisymmetric model jointly electrochemical impedance spectroscopy is developed provide mechanistic insights into hydrophobicity regulation. simulated polarization keeping experimental results. boosted attributed decrease distance from gas–liquid phase boundary electrocatalyst. understanding established here can be generalized other gas‐involved electrocatalytic reactions.
Language: Английский
Citations
4Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 160151 - 160151
Published: Feb. 1, 2025
Language: Английский
Citations
0