Ultrafine PtGa Clusters Confined in Porous ZrOx/SiO2 Nanofibers for Enhanced Propane Dehydrogenation DOI

P Li,

Jingyi Jiang, Han Yan

et al.

ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown

Published: May 8, 2025

Ultrafine Pt clusters exhibit superior activity for propane dehydrogenation compared to larger nanoparticles; however, they are prone sintering at high operating temperatures, leading a decline in both and selectivity. In this work, porous ZrOx/SiO2 nanofibers featuring highly dispersed ZrOx nanodomains within SiO2 matrix were successfully fabricated via high-throughput blow-spinning process. The abundant thermal-stable 1.6 nm micropores significantly stabilize 1.5 PtGa against temperatures over 800 °C, due the pore confinement. Moreover, electron transfer from Ga is enhanced close proximity ZrOx, contributing metallic with exceptional toward C-H bond activation. Thereby, sinter-resistant PtGa/ZrOx/SiO2 maintained 98.8% propylene selectivity 43.2% conversion rate 100 h of reaction, deactivation constant down 0.0045 h-1. This work explores catalytic system based on oxide elaborates new logic design high-performance catalysts long-term stability.

Language: Английский

Construction of a heterojunction between Ni/Al layered double oxides and CdS quantum dots for efficient photocatalytic hydrogen production DOI
Zhirong Li,

Jing Liu,

Jingyi Sun

et al.

Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: unknown, P. 137531 - 137531

Published: April 1, 2025

Language: Английский

Citations

0
Influence of surface acidity/basicity of selected metal oxide catalysts and reaction atmospheres on the ketonisation of propionic acid to produce 3-pentanone as a liquid biofuel precursor DOI Creative Commons
Abarasi Hart, Himanshu Patel, Eyüp Yıldırır

et al.

Renewable Energy, Journal Year: 2025, Volume and Issue: unknown, P. 123386 - 123386

Published: May 1, 2025

Language: Английский

Citations

0
Ultrafine PtGa Clusters Confined in Porous ZrOx/SiO2 Nanofibers for Enhanced Propane Dehydrogenation DOI

P Li,

Jingyi Jiang, Han Yan

et al.

ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown

Published: May 8, 2025

Ultrafine Pt clusters exhibit superior activity for propane dehydrogenation compared to larger nanoparticles; however, they are prone sintering at high operating temperatures, leading a decline in both and selectivity. In this work, porous ZrOx/SiO2 nanofibers featuring highly dispersed ZrOx nanodomains within SiO2 matrix were successfully fabricated via high-throughput blow-spinning process. The abundant thermal-stable 1.6 nm micropores significantly stabilize 1.5 PtGa against temperatures over 800 °C, due the pore confinement. Moreover, electron transfer from Ga is enhanced close proximity ZrOx, contributing metallic with exceptional toward C-H bond activation. Thereby, sinter-resistant PtGa/ZrOx/SiO2 maintained 98.8% propylene selectivity 43.2% conversion rate 100 h of reaction, deactivation constant down 0.0045 h-1. This work explores catalytic system based on oxide elaborates new logic design high-performance catalysts long-term stability.

Language: Английский

Citations

0