Advanced Degradation of Aniline in Secondary Effluent from a Chemical Industry Park by Cobalt Ferrite/Peracetic Acid System DOI Open Access

Jinxiang Gao,

Peipei Yang, Mingxin Zhu

et al.

Catalysts, Journal Year: 2025, Volume and Issue: 15(5), P. 410 - 410

Published: April 23, 2025

The residual emerging pollutants in secondary effluent from a chemical industry park contain potential risks for natural waters. Herein, the cobalt ferrite/peracetic acid system was employed to destroy aniline, typical pollutant, with reaction rate of 0.0147 min−1 at pH 7.0. Singlet oxygen (1O2) served as predominant reactive species aniline degradation, superoxide radicals (O2−) and organic (R-O) acting roles. valence transition between Co(II) Co(III) on CoFe2O4 surface played determining role progression. presence anions humic acids low concentrations had minimal impact removal. Additionally, catalyst demonstrated excellent recyclability, maintaining pollutant removal above 93% over five consecutive cycles. Lastly, CoFe2O4/PAA demonstrates effective treatment pollutants, including phenolic compounds, pesticides, antibiotics, dyes, achieving rates 77.48% 99.99%. Furthermore, it significantly enhances water quality actual effluent, offering novel theoretical foundation practical insights applying this catalytic wastewater treatment.

Language: Английский

The role of cobalt-based catalysts in activating peracetic acid for environmental pollutants degradation: A mini review DOI
Usman Farooq, Ahmad Hassan, Roshan Kumar

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 160649 - 160649

Published: Feb. 1, 2025

Language: Английский

Citations

2
The Microbial Assay for Risk Assessment (MARA) in the Assessment of the Antimicrobial Activity of Ofloxacin and Its Photoproducts DOI Open Access
Grzegorz Nałęcz‐Jawecki,

Jakub Mielniczek,

Milena Wawryniuk

et al.

International Journal of Molecular Sciences, Journal Year: 2025, Volume and Issue: 26(6), P. 2595 - 2595

Published: March 13, 2025

Ofloxacin is one of the most commonly used antibacterial substances in world. Like medicines, it ends up environment through municipal sewage and undergoes various transformations, e.g., photodegradation. The aim this study was an extensive analysis ofloxacin photodegradation both pure antibiotic a commercial eye drop forms. In study, sunlight simulator, chromatographic methods quantitative qualitative determination, biological for evaluation toxicity (Microbial Assay Risk Assessment (MARA), Microtox® Spirotox) were used. results showed that decomposed almost completely over 2 h irradiation. Based on high resolution mass spectrometry, 22 photoproducts identified. sensitive strain bacteria MARA test (Delftia acidovorans) responded at concentration 7.6 µg L−1 ofloxacin. activity irradiated samples higher than predicted based concentration. This suggests resulting may have bacteriostatic effect. additional acute tests indicate formation toxic photoproducts, so reasonable to use other organisms are not focused specific target. Such actions allow capture other, unexpected effects formed photoproducts.

Language: Английский

Citations

1
Advanced Degradation of Aniline in Secondary Effluent from a Chemical Industry Park by Cobalt Ferrite/Peracetic Acid System DOI Open Access

Jinxiang Gao,

Peipei Yang, Mingxin Zhu

et al.

Catalysts, Journal Year: 2025, Volume and Issue: 15(5), P. 410 - 410

Published: April 23, 2025

The residual emerging pollutants in secondary effluent from a chemical industry park contain potential risks for natural waters. Herein, the cobalt ferrite/peracetic acid system was employed to destroy aniline, typical pollutant, with reaction rate of 0.0147 min−1 at pH 7.0. Singlet oxygen (1O2) served as predominant reactive species aniline degradation, superoxide radicals (O2−) and organic (R-O) acting roles. valence transition between Co(II) Co(III) on CoFe2O4 surface played determining role progression. presence anions humic acids low concentrations had minimal impact removal. Additionally, catalyst demonstrated excellent recyclability, maintaining pollutant removal above 93% over five consecutive cycles. Lastly, CoFe2O4/PAA demonstrates effective treatment pollutants, including phenolic compounds, pesticides, antibiotics, dyes, achieving rates 77.48% 99.99%. Furthermore, it significantly enhances water quality actual effluent, offering novel theoretical foundation practical insights applying this catalytic wastewater treatment.

Language: Английский

Citations

0