Water-Soluble Self-Assembled Molecular Cage and Two-Dimensional Framework through Flexibility Adjustment of the Precursors DOI Creative Commons

Hui Fang,

Hui Liu, Hui Wang

et al.

Published: Dec. 6, 2023

The diversified self-assembly in water is a versatile and significant phenomenon with far-reaching implications materials science, medicine, biotechnology, various other fields. Through subtle tailoring the amphipathic molecular structures, two completely different behaviors were obtained. precursors M1-X (X= I- or Cl-) rigid shorter bridges between hydrophobic core hydrophilic edge form 2D framework while precursor M2-I molecule flexible vinyl gives 3D cube-like supramolecular cages. Notbatly, all single crystals of assem-blies single-crystal X-ray diffraction analysis provided unambiguous evidence structures.

Language: Английский

Water-Soluble Self-Assembled Molecular Cage and Two-Dimensional Framework through Flexibility Adjustment of the Precursors DOI Creative Commons

Hui Fang,

Hui Liu, Hui Wang

et al.

Published: Dec. 6, 2023

The diversified self-assembly in water is a versatile and significant phenomenon with far-reaching implications materials science, medicine, biotechnology, various other fields. Through subtle tailoring the amphipathic molecular structures, two completely different behaviors were obtained. precursors M1-X (X= I- or Cl-) rigid shorter bridges between hydrophobic core hydrophilic edge form 2D framework while precursor M2-I molecule flexible vinyl gives 3D cube-like supramolecular cages. Notbatly, all single crystals of assem-blies single-crystal X-ray diffraction analysis provided unambiguous evidence structures.

Language: Английский

Citations

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