The effects of solid acids as cocatalysts on the chelation-assisted hydroacylation of alkenes and alkynes DOI Creative Commons
Blanca Ivonne Vergara-Arenas, Eréndira García-Ríos, Rubén Gaviño

et al.

Published: April 15, 2024

The use of homogeneous Bronsted acid cocatalysts (such as benzoic acid) in hydroacylation reactions via imine intermediates has been extensively studied, but the heterogeneous limited to montmorillonite K10. Thus, we can other solid acids increase efficiency reaction. Here, described effects sulfated zirconia, Al-MCM-41 or superacid modified on alkenes and alkynes with aldehydes presence Wilkinson complex. Furthermore, addressed dual role montmorillonite, a redox reagent TEMPO an solid, allowing direct benzyl alcohols substrates generate saturated a-b unsaturated ketones.

Language: Английский

The effects of solid acids as cocatalysts on the chelation-assisted hydroacylation of alkenes and alkynes DOI Creative Commons
Blanca Ivonne Vergara-Arenas, Eréndira García-Ríos, Rubén Gaviño

et al.

Published: April 15, 2024

The use of homogeneous Bronsted acid cocatalysts (such as benzoic acid) in hydroacylation reactions via imine intermediates has been extensively studied, but the heterogeneous limited to montmorillonite K10. Thus, we can other solid acids increase efficiency reaction. Here, described effects sulfated zirconia, Al-MCM-41 or superacid modified on alkenes and alkynes with aldehydes presence Wilkinson complex. Furthermore, addressed dual role montmorillonite, a redox reagent TEMPO an solid, allowing direct benzyl alcohols substrates generate saturated a-b unsaturated ketones.

Language: Английский

Citations

1