Light Induced Cobalt(III) Carbene Radical Formation from Dimethyl Malonate As Carbene Precursor DOI Creative Commons
Demi D. Snabilié, Rens Ham, Joost N. H. Reek

et al.

Organometallics, Journal Year: 2024, Volume and Issue: 43(11), P. 1299 - 1307

Published: May 24, 2024

Radical-type carbene transfer catalysis is an efficient method for the direct functionalization of C–H and C═C bonds. However, radical complexes are currently formed via high-energy precursors, such as diazo compounds or iodonium ylides. Many these precursors require additional synthetic steps, have explosive nature, generate halogenated waste. Consequently, utilization limited by specific that access intermediate. In this study, we a cobalt(III) complex from dimethyl malonate, which commercially available bench-stable. EPR NMR spectroscopy were used to identify intermediates showed upon light irradiation. presence styrene, occurred, forming cyclopropane product. With photochemical method, demonstrate malonate can be alternative precursor in formation complex.

Language: Английский

Light Induced Cobalt(III) Carbene Radical Formation from Dime-thyl Malonate as Carbene Precursor DOI Creative Commons
Demi D. Snabilié, Bas de Bruin, Rens Ham

et al.

Published: April 3, 2024

Radical-type carbene transfer catalysis is an efficient method for the direct functionalization of C–H and C=C bonds. However, radical complexes are currently formed via high-energy precursors, such as diazo compounds or iodonium ylides. Many these precursors require additional synthetic steps, have explosive nature generate halogenated waste. Con-sequently, utilization limited by specific to access inter-mediate. In this study, we a cobalt(III) complex from dimethyl malonate, which commercially available bench-stable. EPR NMR spectroscopy were used identify intermediates showed that upon light irradiation. presence styrene, occurred, forming cyclopropane product. With photochemical method, demonstrate malonate can be alternative precursor in formation complex.

Language: Английский

Citations

2
Light Induced Cobalt(III) Carbene Radical Formation from Dimethyl Malonate As Carbene Precursor DOI Creative Commons
Demi D. Snabilié, Rens Ham, Joost N. H. Reek

et al.

Organometallics, Journal Year: 2024, Volume and Issue: 43(11), P. 1299 - 1307

Published: May 24, 2024

Radical-type carbene transfer catalysis is an efficient method for the direct functionalization of C–H and C═C bonds. However, radical complexes are currently formed via high-energy precursors, such as diazo compounds or iodonium ylides. Many these precursors require additional synthetic steps, have explosive nature, generate halogenated waste. Consequently, utilization limited by specific that access intermediate. In this study, we a cobalt(III) complex from dimethyl malonate, which commercially available bench-stable. EPR NMR spectroscopy were used to identify intermediates showed upon light irradiation. presence styrene, occurred, forming cyclopropane product. With photochemical method, demonstrate malonate can be alternative precursor in formation complex.

Language: Английский

Citations

0