Realization of Antithermal Quenching of Eu3+ for High‐Sensitivity Luminescence Thermometry via an Indirect Energy Transfer Route
Advanced Optical Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 20, 2025
Abstract
Luminescence
intensity
decreasing
with
rising
temperature
is
a
common
phenomenon
called
thermal
quenching.
However,
the
Bi
3+
‐Eu
co‐doped
NaGd
2
Ga
3
Ge
O
12
(NGGG)
phosphor
exhibits
antithermal
quenching
luminescence
of
Eu
.
has
pair
thermally
coupled
energy
levels
(TCLs),
where
higher
level
P
1
and
lower
derived
from
metal‐to‐metal
charge‐transfer
(MMCT).
As
concentration
increases,
lifetime
decreases,
while
MMCT
remains
unchanged.
It
means
that
transfer
(ET)
only
happens
between
Interestingly,
excited,
emission
still
observed.
This
because
when
exciting
level,
as
upper
TCLs,
can
also
be
which
consequently
leads
to
Accordingly,
⁺
will
increased
show
coupling
process
enhanced
temperature.
Taking
advantage
unique
ET
⁺,
⁺‐Eu
NGGG
demonstrates
sensitivity
2.08%
K
−
¹
at
500
K,
distinct
most
fluorescence
thermometers
maximum
low
temperatures.
Language: Английский
Large energy gap between singlet and triplet states is no longer a problem: intermediate charge transfer state boosts overall quantum yield up to 67% in Eu3+ complexes
Rare Metals,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 14, 2025
Language: Английский
Bi3+ doped Sr3Y2(BO3)4 phosphors for full-spectrum WLEDs and temperature sensing
Chen Yang,
No information about this author
Qiang Wang,
No information about this author
Jun Wen
No information about this author
et al.
Ceramics International,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 1, 2025
Language: Английский
Eu2+ Induced Crystal Field Modulation and Luminescence Enhancement in Ca9Ga(PO4)7:Zn2+,Cr3+
Z.H. Xia,
No information about this author
Lan Yao,
No information about this author
Xin Pan
No information about this author
et al.
Journal of Luminescence,
Journal Year:
2025,
Volume and Issue:
unknown, P. 121129 - 121129
Published: Feb. 1, 2025
Language: Английский
Tunable Luminescence and Temperature Sensing in Tb3+ mono-doped Mg3Gd2Ge3O12 Phosphor with High Quantum Yield
Jinping Bai,
No information about this author
Jinsu Zhang,
No information about this author
Chuwei Kong
No information about this author
et al.
Ceramics International,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Feb. 1, 2025
Language: Английский
A heat-resistant red-emitting K6Bi13(PO4)15:Sm3+,Eu3+ phosphor toward high color rendering LED lights
Haonan Cui,
No information about this author
Yuting Li,
No information about this author
Li Ran
No information about this author
et al.
Ceramics International,
Journal Year:
2025,
Volume and Issue:
unknown
Published: April 1, 2025
Language: Английский
Energy transfer from the [WO6]6− group to Er3+ in Lu2WO6 and favorable optical thermometry with strong emission color variability
Xuyan Xue,
No information about this author
Changshuai Gong,
No information about this author
Sihan Yang
No information about this author
et al.
New Journal of Chemistry,
Journal Year:
2024,
Volume and Issue:
48(44), P. 18890 - 18899
Published: Jan. 1, 2024
Non-contact
optical
temperature
measurement
has
attracted
intense
attention
in
recent
years
due
to
its
advantages
of
high
speed
and
safety.
Language: Английский