Comment on “Assessing the atmospheric fate of trifluoroacetaldehyde (CF3CHO) and its potential as a new source of fluoroform (HFC-23) using the AtChem2 box model” by Pérez-Peña et al., Environ. Sci.: Atmos., 2023, 3, 1767–1777, DOI: 10.1039/D3EA00120B
Environmental Science Atmospheres,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 1, 2025
Trifluoroacetaldehyde
is
a
degradation
product
from
the
atmospheric
of
some
common
hydrofluoroolefins
(HFOs).
In
commentary
we
discuss
potential
fates
trifluoro
acetaldehyde:
OH
reaction,
photolysis
and
wet
dry
deposition.
Language: Английский
Reply to the ‘Comment on “Assessing the atmospheric fate of trifluoroacetaldehyde (CF3CHO) and its potential as a new source of fluoroform (HFC-23) using the AtChem2 box model”’ by O. J. Nielsen, M. P. Sulbaek Andersen and J. Franklin, Environ. Sci.: Atmos., 2025, 5, DOI: 10.1039/D4EA00123K
Environmental Science Atmospheres,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 1, 2025
In
Pérez-Peña
et
al.
(DOI:
https://doi.org/10.1039/d3ea00120b),
we
used
a
suite
of
box
model
simulations
to
determine
how
trifluoroacetaldehyde
(CF
3
CHO)
produced
from
HFO-1234ze
is
lost
in
the
atmosphere
and
much
fluoroform
(CHF
or
HFC-23)
could
potentially
be
as
result.
For
first
time
any
modelling
study,
our
included
both
minor
CF
CHO
photolytic
loss
channel
leading
CHF
production
physical
removal
via
wet
dry
deposition.
their
comment,
Sulbaek
Andersen,
Nielsen,
Franklin
query
assumptions
simulate
these
processes.
Here,
show
that
importance
pathway
remains
matter
community
debate
results
are
relatively
insensitive
underlying
simulation
We
reiterate
need
for
measurements
properties
reduce
uncertainties
processes
pave
way
more
sophisticated
models.
Language: Английский
Temperature rise characteristics of C5F10O/CO2 gas mixture AC high voltage switch bus
High Voltage,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Dec. 31, 2024
Abstract
C
5
F
10
O/CO
2
gas
mixture
is
one
of
the
most
promising
alternatives
to
SF
6
as
an
insulating
in
high‐voltage
switchgear.
As
a
key
performance
index
product
design,
temperature
rise
characteristics
are
rarely
reported.
In
this
paper,
thermodynamic
parameters
were
calculated
first.
Then,
calculation
model
transient
was
constructed
for
252
kV/3150
A
bus,
and
experimental
platform
built
verify
reliability
proposed
model.
On
basis,
influence
different
factors
such
load
current,
charging
pressure,
mixing
ratio,
structure
size
on
bus
further
analysed,
it
found
that
increasing
pressure
ratio
O
could
effectively
reduce
but
still
not
reach
level
.
The
main
affects
outer
diameter
conductor,
which
increases
by
10.2%,
same
original
bus.
Finally,
high‐precision
surrogate
model,
combined
with
Latin
hypercube
coefficient
prognosis,
Kriging
fitting
method
established
facilitate
structural
design.
Language: Английский