Oxygen‐Tolerant ATRP Depolymerization Enabled by an External Radical Source DOI Open Access
Stella Afroditi Mountaki, Richard Whitfield, Athina Anastasaki

et al.

Macromolecular Rapid Communications, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 22, 2025

Abstract Although the chemical recycling of polymers synthesized by controlled radical polymerization enables recovery pristine monomer at low temperatures, it operates efficiently under strictly anaerobic conditions. Instead, oxygen‐tolerant depolymerizations are scarce, and either restricted to use a boiling co‐solvent or performed in closed vessels, often suffering from conversions. Here, an open‐vessel, depolymerization atom transfer (ATRP)‐synthesized is introduced, leading high percentages regeneration (>90% efficiency). Dissolved oxygen eliminated utilizing catalyst loadings, lower loadings combined with initiator. Notably, methodology compatible various solvents (i.e., anisole, 1,2,4‐trichlorobenzene (TCB), 1,2‐dichlorobenzene (DCB), etc.) range commercially available ligands including tris 2‐(dimethylamino)ethylamine (Me 6 TREN) tris(2‐pyridylmethyl)amine (TPMA), as well more inexpensive alternatives such tris(2‐aminoethyl)amine (TREN) N,N,N‘,N‘‘,N‘‘ ‐pentamethyldiethylenetriamine (PMDETA).

Language: Английский

Addressing Plastic Waste Challenges in Africa: The Potential of Pyrolysis for Waste-to-Energy Conversion DOI Creative Commons
Milon Selvam Dennison, S. Paramasivam, Titus Wanazusi

et al.

Clean Technologies, Journal Year: 2025, Volume and Issue: 7(1), P. 20 - 20

Published: March 5, 2025

Plastic waste poses a significant challenge in Africa and around the world, with its volume continuing to increase at an alarming rate. In Africa, estimated 25–33% of daily is made up plastic, posing threat environment, marine life, human health. One potential solution this problem waste-to-energy recycling, such as pyrolysis, which involves conversion materials into oil, char, non-condensable gasses through thermochemical process absence oxygen. Given abundance continent’s energy challenges, pyrolysis offers sustainable solution. This review delves concept products, thermodynamics, endothermic kinetics, presenting it promising way address plastic Africa. Despite African Union’s goal recycle waste, continent faces barriers achieving target, including infrastructural, economic, social difficulties. It crucial implement strategies for managing mitigate environmental degradation promote cleaner healthier living environment. Pyrolysis technology highlighted viable management, can convert valuable byproducts syngas. Case studies from countries like South Nigeria demonstrate scaling management issues while generating job opportunities. underscores need investment, regulatory support, public awareness overcome challenges unlock full Embracing method could lead economic benefits continent.

Language: Английский

Citations

0

Quantitative and Qualitative Characterization of Food Waste for Circular Economy Strategies in the Restaurant Sector of Riobamba, Ecuador: A Case Study Approach DOI Creative Commons
Angélica María Saeteros Hernández, Francisco Javier Chalen Moreano, Ronald Mauricio Zurita Gallegos

et al.

Biomass, Journal Year: 2025, Volume and Issue: 5(2), P. 18 - 18

Published: March 25, 2025

The aim of this study is the quantitative and qualitative characterization food waste from restaurant sector in Riobamba, Ecuador as part circular economy efforts. A weekly analysis generation data collected 13 participating restaurants showed that average daily generated was 18.48 kg/restaurant/day. highest percentage (55%) produced by organic waste, which primarily composed vegetables. Plastics represented most recyclable (21%), 24% disposable. With a low dry matter content 24.33 ± 5.12% an moisture level 75.68 5.12%, high indicates its potential for value-adding through biological recycling processes like anaerobic digestion composting. Fruit vegetable had levels (80.3 2.54% 81.2 2.75%, respectively), made them perfect composting biogas production. However, contents differed greatly amongst categories. increased concentration animal protein (54.5 4.30%) indicated it may be converted into products with added value, such meal oils. Plant needs to processed quickly avoid spoiling because extraordinarily (95.7 3.20%) (4.3 3.20%). findings underscore necessity focused measures, composting, digestion, enhanced recycling, optimize resource recovery mitigate environmental consequences.

Language: Английский

Citations

0

Global Trends and Strategic Pathways for Waste Plastics Depolymerization in the Circular Economy DOI Creative Commons
Godlisten G. Kombe

Cleaner Waste Systems, Journal Year: 2025, Volume and Issue: unknown, P. 100292 - 100292

Published: April 1, 2025

Language: Английский

Citations

0

Thermal Conversion of Non-recyclable Discarded Fishing Nets from the Gulf of Thailand for Marketable Resource Recovery DOI
Duangduen Atong, Kanit Soongprasit, Viboon Sricharoenchaikul

et al.

Process Safety and Environmental Protection, Journal Year: 2025, Volume and Issue: unknown, P. 107228 - 107228

Published: April 1, 2025

Language: Английский

Citations

0

Oxygen‐Tolerant ATRP Depolymerization Enabled by an External Radical Source DOI Open Access
Stella Afroditi Mountaki, Richard Whitfield, Athina Anastasaki

et al.

Macromolecular Rapid Communications, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 22, 2025

Abstract Although the chemical recycling of polymers synthesized by controlled radical polymerization enables recovery pristine monomer at low temperatures, it operates efficiently under strictly anaerobic conditions. Instead, oxygen‐tolerant depolymerizations are scarce, and either restricted to use a boiling co‐solvent or performed in closed vessels, often suffering from conversions. Here, an open‐vessel, depolymerization atom transfer (ATRP)‐synthesized is introduced, leading high percentages regeneration (>90% efficiency). Dissolved oxygen eliminated utilizing catalyst loadings, lower loadings combined with initiator. Notably, methodology compatible various solvents (i.e., anisole, 1,2,4‐trichlorobenzene (TCB), 1,2‐dichlorobenzene (DCB), etc.) range commercially available ligands including tris 2‐(dimethylamino)ethylamine (Me 6 TREN) tris(2‐pyridylmethyl)amine (TPMA), as well more inexpensive alternatives such tris(2‐aminoethyl)amine (TREN) N,N,N‘,N‘‘,N‘‘ ‐pentamethyldiethylenetriamine (PMDETA).

Language: Английский

Citations

0