Facile Sol–Gel Synthesis of C, N Codoped-TiO2 for Efficient Degradation of Palm Oil Mill Effluent DOI Creative Commons
Bo Tan, Nur Aziemah Abd Rashid,

Nurul Hidayah Mohamad Idris

et al.

ACS Omega, Journal Year: 2025, Volume and Issue: 10(3), P. 2858 - 2870

Published: Jan. 11, 2025

Wastewater treatment has been regarded as an effective solution in lowering the potential environmental hazards caused by palm oil mill effluent (POME). To ensure efficient remediation of POME, implementation a promising strategy is necessary to overcome limitations conventional water methods for this pollutant. In study, synthesis carbon, nitrogen codoped titanium dioxide nanoparticles (C, N-TiO2 NPs) was successfully performed sol-gel approach POME model pollutant under solar light irradiation. The synthesized C, NPs displayed unique characteristics including anatase phase with average crystallite size 11.35 nm and irregular spherical structures. Additionally, possessed lower band gap energy 2.95 eV than 3.2 V bulk TiO2 slower electron-hole (e--h+) pair recombination rate evidenced photoluminescence (PL) studies. adsorption isotherm study most compatible Langmuir model, degradation kinetics proceeded according first-order kinetics. Accordingly, photocatalytic maximum efficiency 100% optimum condition pH 7 presence 0.12 g photocatalyst within 150 min. scavenging showed that superoxide radical (•O2 -) primary active species photodegradation. Finally, reusability analysis confirmed could be reused five cycles, making them photocatalysts wastewater treatment.

Language: Английский

Pharmaceuticals in wastewater and their photocatalytic degradation using nano-enabled photocatalysts DOI Creative Commons

Deborah T. Ruziwa,

Abimbola E. Oluwalana,

Mathew Mupa

et al.

Journal of Water Process Engineering, Journal Year: 2023, Volume and Issue: 54, P. 103880 - 103880

Published: June 16, 2023

Pharmaceuticals in the concentration range of hundreds ng/L to μg/L occur wastewater and end up surface water, groundwater agricultural land where they cause various health risks. These pollutants are classified as emerging cannot be efficiently removed by conventional treatment processes. The use nano-enabled photocatalysts removal pharmaceuticals aquatic systems has recently received research attention owing their enhanced properties effectiveness. industrial scale application photocatalytic technology is still limited. A comprehensive review on from real using therefore necessary. This paper reviews literature occurrence, fate, nano-sized strategies wastewater. Modifications through doping, deposition supports, introducing magnetic character enhance efficiency recyclability were discussed. synthetic routes influence physical chemical which can either or inhibit benefits degradation include easy recycling exhibit excellent stability, used for several cycles. Going forward, should focus on: (1) elucidation photodegradation mechanisms, (2) at remove multiple pharmaceutical compounds, (3) regeneration, disposal particularly towards large application, (4) life cycle assessment synthesis (5) lowering cost improving efficiency, (6) investigating toxicity intermediates photocatalyst environment.

Language: Английский

Citations

98

Graphene-like graphitic carbon nitride (g-C3N4) as a semiconductor photocatalyst: Properties, classification, and defects engineering approaches DOI
Tahir Muhmood, Imtiaz Ahmad, Zeeshan Haider

et al.

Materials Today Sustainability, Journal Year: 2023, Volume and Issue: 25, P. 100633 - 100633

Published: Dec. 12, 2023

Language: Английский

Citations

46

Superwetting materials as catalysts in photocatalysis: State-of-the-Art review DOI
Lagnamayee Mohapatra, Seung Hwa Yoo

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 481, P. 148537 - 148537

Published: Jan. 10, 2024

Language: Английский

Citations

28

Current progress in heterojunctions based on Nb2O5 for photocatalytic water treatment and energy applications DOI
Amit Kumar,

Sahil Rana,

Pooja Dhiman

et al.

Journal of Molecular Liquids, Journal Year: 2024, Volume and Issue: 399, P. 124360 - 124360

Published: Feb. 27, 2024

Language: Английский

Citations

20

Advancements in the application of metal oxide nanocatalysts for sustainable biodiesel production DOI Creative Commons
Omojola Awogbemi, A. A. Ojo, Samson Adedayo Adeleye

et al.

Deleted Journal, Journal Year: 2024, Volume and Issue: 6(5)

Published: May 7, 2024

Abstract The growing population and the unpalatable ecological impact of exploration utilization fossil-based fuels have resulted in increased demand for biofuel as an alternative fuel engines power generation. global biodiesel, a prominent member biofuels family, has continued to increase over past decades with researchers devising various means intensify cost-effective production. use metal oxide nanocatalysts is one feasible strategies meet quality biodiesel. This study reviews recent advances deployment commonly used nanoparticles such MgO, CaO, TiO 2 , ZnO, ZrO accelerate sustainable biodiesel Converting conventional heterogeneous catalysts into enhances surface configuration, chemical thermal stability, porosity, crystallinity nanocatalysts. hasten transesterification reaction, reduces reaction temperature time, yield. Biodiesel synthesized aid impeccable meets international standards. Notwithstanding few challenges, application engenders production contributes energy security. More innovative collaborative studies are needed reduce ethical, economic, infrastructural, environmental consequences usage nanomaterials

Language: Английский

Citations

20

Recent Trends in the Application of Photocatalytic Membranes in Removal of Emerging Organic Contaminants in Wastewater DOI Open Access

Kipchumba Nelson,

Achisa C. Mecha, Humphrey Mutuma Samuel

et al.

Processes, Journal Year: 2025, Volume and Issue: 13(1), P. 163 - 163

Published: Jan. 9, 2025

Increasing water pollution by bio-recalcitrant contaminants necessitates the use of robust treatment methods. Individual methods are not effective against these emerging organic pollutants due to their stability in environment. This has necessitated advanced integrated systems such as photocatalytic membranes. Synergy reactive membranes effectively degrades pollutants. review presents state art synthesis and application wastewater treatment. The study critically evaluates pertinent aspects required improve performance membranes, tailored material synthesis, membrane fouling control, improved photocatalyst light absorption, visible from sunlight, enhanced reaction kinetics through synergy, regeneration reuse. Previous studies report on effectiveness removal synthetic actual wastewater. As such, they show great potential decontamination; however, also face limitations that need be addressed. identifies challenges provides a way forward increasing photoactivity titanium oxide, mitigation, scalability, improving cost effectiveness, enhancing stability, other relevant scaling up efforts lab scale industrial scale.

Language: Английский

Citations

3

Enhanced photocatalytic performance of CeO2/ZnO/TiO2nanocomposite: Role of reduced bandgap and core-shell heterojunction morphology DOI
S.M. Fathima Khyrun, S.M. Fathima Khyrun, Suresh Sagadevan

et al.

Optical Materials, Journal Year: 2025, Volume and Issue: unknown, P. 116990 - 116990

Published: March 1, 2025

Language: Английский

Citations

3

Microbial synthesis of titanium dioxide nanoparticles and their importance in wastewater treatment and antimicrobial activities: a review DOI Creative Commons

Chandani Rathore,

Virendra Kumar Yadav, Amel Gacem

et al.

Frontiers in Microbiology, Journal Year: 2023, Volume and Issue: 14

Published: Oct. 16, 2023

Nanotechnology (NT) and nanoparticles (NPs) have left a huge impact on every field of science today, but they shown tremendous importance in the fields cosmetics environmental cleanup. NPs with photocatalytic effects positive responses wastewater treatment, cosmetics, biomedical field. The chemically synthesized TiO2 (TiO2 NPs) utilize hazardous chemicals to obtain desired-shaped TiO2. So, microbial-based synthesis has gained popularity due its eco-friendly nature, biocompatibility, etc. Being NPs, high surface area-to-volume ratio addition their degradation nature. In present review, authors emphasized microbial (algae, bacterial, fungi, virus-mediated) NPs. Furthermore, exhibited food sector, automobile, aerospace, medical,

Language: Английский

Citations

28

Experimental assessment of the pH effect and ions on the photocatalytic activity of iron-doped titanium dioxide supported on polystyrene pellets: Batch and continuous tests DOI Creative Commons
Domenico Rosa,

Giada Manetta,

Luca Di Palma

et al.

Chemical Engineering Science, Journal Year: 2024, Volume and Issue: 291, P. 119918 - 119918

Published: Feb. 28, 2024

Experimental tests in batch and continuous modes studied the impact of pH presence inorganic ions on photocatalytic properties a visible light-activated titanium oxide catalyst doped with iron. Significantly enhanced photocatalysis was observed nitrate iron ions, while chloride hindered adsorption using Rhodamine B. A strong correlation between performance noted, along connection target molecule subsequent degradation. Supporting polystyrene pellets reduced performance. However, reuse for four cycles optimal dosages were achieved. In system, consistent chemical efficiency maintained. Over 8 days, removal rates remained around 35 % 43 NO3–. Mechanically, no loss from support observed. These findings set stage potential industrial-scale applications.

Language: Английский

Citations

16

Innovations in metal oxides-biochar nanoparticles for dye removal DOI

Attiqa Ahmad,

Zia Ul Haq Khan,

Sana Sabahat

et al.

Nano-Structures & Nano-Objects, Journal Year: 2024, Volume and Issue: 39, P. 101269 - 101269

Published: July 24, 2024

Language: Английский

Citations

16