Reaction Chemistry & Engineering,
Journal Year:
2024,
Volume and Issue:
10(3), P. 605 - 613
Published: Dec. 5, 2024
In
an
umbrella-shaped
microchannel
reactor,
the
continuous
selective
aerobic
oxidation
of
toluene
derivatives
to
aromatic
aldehydes
over
a
Co/Mn/Br
catalytic
system
using
acetic
acid/water
as
solvent
was
studied.
Processes,
Journal Year:
2023,
Volume and Issue:
11(8), P. 2360 - 2360
Published: Aug. 5, 2023
The
amount
of
microplastics
(MPs)
present
in
marine
ecosystems
are
a
growing
concern,
with
potential
impacts
on
human
health
because
they
associated
an
increase
the
ecotoxicity
certain
foods,
such
as
fish.
As
result,
there
has
been
interest
developing
effective
methods
for
analysis
MPs
waters.
Traditional
MP
involve
visual
inspection
and
manual
sorting,
which
can
be
time-consuming
subject
to
error.
However,
novel
have
developed
that
offer
more
efficient
accurate
analyses.
One
method
is
based
spectroscopy,
Fourier
transform
infrared
spectroscopy
(FTIR).
Another
involves
use
fluorescent
dyes,
selectively
bind
allow
their
detection
under
UV
light.
Additionally,
machine
learning
approaches
analyze
large
volumes
water
samples
classification.
These
specialized
algorithms
identify
classify
size,
shape,
texture.
Overall,
these
analyses
waters,
essential
understanding
extent
pollution
mitigation
strategies.
still
need
continued
research
development
optimize
improve
sensitivity
accuracy.
Foods,
Journal Year:
2023,
Volume and Issue:
12(16), P. 3058 - 3058
Published: Aug. 15, 2023
Scientific
mapping
using
bibliometric
data
network
analysis
was
applied
to
analyze
research
works
related
lipases
and
their
industrial
applications,
evaluating
the
current
state
of
research,
challenges,
opportunities
in
use
these
biocatalysts,
based
on
evaluation
a
large
number
publications
topic,
allowing
comprehensive
systematic
analysis,
which
had
not
yet
been
conducted
relation
studies
specifically
covering
applications.
Thus,
involving
lipase
enzymes
published
from
2018
2022
were
accessed
Web
Science
database.
The
extracted
records
result
terms
bibliographic
compatibility
among
articles,
co-occurrence
keywords,
co-citation
journals
VOSviewer
algorithm
construction
maps.
This
review
357
documents,
including
original
revealed
inspired
by
period,
showing
that
development
together
with
different
areas
knowledge,
presents
good
results
applications
lipases,
due
information
synchronization.
Furthermore,
this
showed
main
challenges
regarding
increased
production
operational
stability;
establishing
well-defined
criteria,
such
as
cultivation
conditions,
activity,
biocatalyst
stability,
type
support
reactor;
thermodynamic
studies;
reuse
cycles;
it
can
assist
defining
goals
for
successful
large-scale
several
points
improvement
future
enzymes.
Catalysts,
Journal Year:
2024,
Volume and Issue:
14(1), P. 39 - 39
Published: Jan. 5, 2024
The
morphology
of
catalysts
in
microchannels
plays
a
crucial
role
the
orbital
maneuvering
and
networking
applications
micro/nano
satellites
using
hydrogen
peroxide
as
unit
propellant.
In
this
paper,
microfluidic
reaction
chip
was
designed
fabricated
to
detect
rate
catalytic
decomposition
solution
by
microchannel
bed.
addition,
silver
thin
film
prepared
constant-current
electroplating
used
substrate
for
catalyst.
results
show
that
ratio
surface
area
average
particle
size
particles
have
significant
positive
correlation
on
decomposition,
while
thickness,
content,
roughness
no
effect
decomposition.
performance
bed
is
greatly
influenced
conditions
electroplating,
namely,
temperature
(T),
time
(t),
current
(I).
And
when
I
=
0.3
mA,
t
180
s,
T
60
°C,
reaches
optimal
solution.
This
study
has
best
process
parameters
design
optimization
heterogeneous
applied
reactors.
Molecules,
Journal Year:
2024,
Volume and Issue:
29(15), P. 3651 - 3651
Published: Aug. 1, 2024
Microstructured
reactors
offer
fast
chemical
engineering
transfer
and
precise
microfluidic
control,
enabling
the
determination
of
reactions'
kinetic
parameters.
This
review
examines
recent
advancements
in
measuring
microreaction
kinetics.
It
explores
modeling,
reaction
mechanisms,
intrinsic
equations
pertaining
to
two
types
microreaction:
esterification
transesterification
reactions
involving
acids,
bases,
or
biocatalysts.
The
utilization
a
micro
packed-bed
reactor
successfully
achieves
harmonious
combination
micro-dispersion
state
characteristics.
Additionally,
this
presents
micro-process
simulation
software
advanced
integration
microreactors
with
spectroscopic
analyses
for
monitoring
data
acquisition.
Furthermore,
it
elaborates
on
control
principles
platform.
superiority
online
measurement,
automation,
digitalization
process
measurements
is
highlighted,
showcasing
vast
prospects
artificial
intelligence
applications.
ACS Catalysis,
Journal Year:
2023,
Volume and Issue:
13(19), P. 12960 - 12969
Published: Sept. 20, 2023
The
enantioselective
synthesis
of
chiral
fluorinated
amines
is
great
importance
but
highly
challenging
in
synthetic
chemistry
and
the
pharmaceutical
industry.
Herein,
we
established
a
chemoenzymatic
cascade
for
α-mono-
difluoromethyl
from
easily
available
β-keto-acid
esters
water–oil–solid
multiphasic
systems
via
two
catalytic
modules,
i.e.,
organo-enzymatic
decarboxylative
fluorination
bienzymatic
reductive
amination.
An
efficient
continuous
system
was
constructed
by
stepwise
enzyme
immobilization,
biphasic
construction,
continuous-flow
operation
to
achieve
process
intensification.
flow
achieved
high
space-time
yield
up
19.7
g
L–1
h–1,
which
35-fold
enhancement
compared
batch
using
free
enzymes,
also
demonstrated
operational
stability,
maintaining
87%
production
activity
after
96
h
with
half-life
443.9
h.
Bioresources and Bioprocessing,
Journal Year:
2024,
Volume and Issue:
11(1)
Published: July 18, 2024
Abstract
Reductive
amination
by
amine
dehydrogenases
is
a
green
and
sustainable
process
that
produces
only
water
as
the
by-product.
In
this
study,
continuous
flow
was
designed
utilizing
packed
bed
reactor
filled
with
co-immobilized
dehydrogenase
wh84
glucose
for
highly
efficient
biocatalytic
synthesis
of
chiral
amino
alcohols.
The
immobilized
exhibited
better
thermo-,
pH
solvent
stability
high
activity
recovery.
(
S
)-2-aminobutan-1-ol
produced
in
up
to
99%
conversion
ee
processes,
space-time
yields
were
124.5
g
L
-1
d
.
reactions
also
extended
48
h
affording
91.8%
average
conversions.
This
study
showcased
important
potential
production
alcohols
processes.