Journal of Kufa for Chemical Sciences,
Journal Year:
2023,
Volume and Issue:
2(10), P. 270 - 289
Published: Nov. 5, 2023
The
term
"nano
gold,"
also
known
as
"gold
nanoparticles,"
is
commonly
used.
These
particles
are
extremely
small,
with
a
diameter
of
less
than
100
nm,
which
only
fraction
the
width
human
hair.
Due
to
their
tiny
size,
nano
gold
often
found
in
colloidal
solution,
where
they
suspended
liquid
stabilizer.
This
essentially
another
name
for
gold.
main
method
producing
nanoparticles
solution
citrate
synthesis
technique,
involves
combining
different
solutions
precipitate
nanoparticles[1-5].
In
biological
systems,
copper
complexes
play
significant
role
at
active
sites
many
metalloproteins.
have
potential
applications
various
catalytic
processes
that
occur
living
organisms,
such
electron
transfer
reactions
and
activation
specific
antitumor
substances.
relevant
fields
medicinal
chemistry
bioinorganic
chemistry.
interaction
chelates
systems
noteworthy
activities
against
neoplastic,
bacterial,
fungal,
cancerous
cells
important.
Many
(II)
N,
S,
O
/
N-donor
chelators
function
effective
anticancer
agents
due
ability
bind
DNA
base
pairs[6-10].
Using
hydrophilic
(AuNPs)
carriers
novel
purposeful
strategy
Could
raise
these
compounds'
stability
solubility
H2O
aqueous.,
thus
enhancing
bioavailability.
regulated
release
Cu-complexes
made
possible
by
this
creates
possibility
fruitful
vivo
vitro
tests.
definition,
significance,
numerous
connection
nanogold
presented
review
study[11-15].
New Journal of Chemistry,
Journal Year:
2023,
Volume and Issue:
47(39), P. 18251 - 18259
Published: Jan. 1, 2023
This
article
reports
on
the
synthesis
and
structure
of
novel
cationic
gold(
i
)
complexes
with
BIAN/MIAN
ligands,
displaying
redox
activity
antichelate
effect.
Chinese Physics B,
Journal Year:
2024,
Volume and Issue:
33(8), P. 083101 - 083101
Published: May 15, 2024
Abstract
A
segmented
basis
set
of
quadruple
zeta
valence
quality
plus
polarization
functions
(QZP)
for
H
through
Xe
was
developed
to
be
used
in
conjunction
with
the
ZORA
Hamiltonian.
This
augmented
diffuse
describe
electrons
farther
away
from
nuclei
adequately.
Using
ZORA-CCSD(T)/QZP-ZORA
theoretical
model,
atomic
ionization
energies
and
bond
lengths,
harmonic
vibrational
frequencies,
atomization
some
molecules
were
calculated.
The
addition
core-valence
corrections
has
been
shown
improve
agreement
between
experimental
results
molecular
properties.
For
energies,
a
similar
observation
emerges
when
considering
spin-orbit
couplings.
With
QZP-ZORA
set,
static
mean
dipole
polarizabilities
atoms
calculated
compared
previously
published
recommended
values.
Performance
evaluations
Douglas–Kroll–Hess
Hamiltonians
made
each
property
studied.