Principles of Photocatalysts and Their Different Applications: A Review

Topics in Current Chemistry, Journal Year: 2023, Volume and Issue: 381(6)

Published: Oct. 31, 2023

Abstract Human existence and societal growth are both dependent on the availability of clean fresh water. Photocatalysis is a type artificial photosynthesis that uses environmentally friendly, long-lasting materials to address energy environmental issues. There currently considerable demand for low-cost, high-performance wastewater treatment equipment. By changing structure, size, characteristics nanomaterials, use nanotechnology in field water filtration has evolved dramatically. Semiconductor-assisted photocatalysis recently advanced become among most promising techniques fields sustainable generation ecological cleanup. It beneficial, cost-effective, strictly linked zero waste discharge principle used industrial effluent treatment. Owing reduction or removal created unwanted byproducts, green synthesis photoactive nanomaterial more beneficial than chemical approaches. Furthermore, unlike methods, method does not require expensive, dangerous, poisonous ingredients, making it less costly, easy, photocatalyst synthesis. This work focuses distinct greener utilized production new photocatalysts, including metals, metal doped-metal oxides, plasmonic nanostructures, application intelligence machine learning design selection an innovative context challenges. A brief overview applications photocatalysts also presented. Finally, recommendations future research given create photocatalytic systems with greatly improved stability efficiency.

Language: Английский

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Recent advances in synthesis methods and surface structure manipulating strategies of copper selenide (CuSe) nanoparticles for photocatalytic environmental and energy applications

Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: 12(4), P. 113125 - 113125

Published: May 23, 2024

Language: Английский

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Exploring zeolite-based composites in adsorption and photocatalysis for toxic wastewater treatment: Preparation, mechanisms, and future perspectives

Environmental Pollution, Journal Year: 2024, Volume and Issue: 349, P. 123922 - 123922

Published: April 3, 2024

Language: Английский

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Tailored carbon materials (TCM) for enhancing photocatalytic degradation of polyaromatic hydrocarbons

Progress in Materials Science, Journal Year: 2024, Volume and Issue: 144, P. 101289 - 101289

Published: March 28, 2024

This comprehensive review explores the potential of tailored carbon materials (TCM) for efficient photocatalytic degradation polyaromatic hydrocarbons (PAHs), which are persistent and toxic organic pollutants posing significant environmental challenges. The unique structure properties TCM including graphene nanotubes to activated dots, have projected them as next-generation technological innovation. A careful critical discussion state-of-the-art research sheds light on their effectiveness in catalyzing breakdown PAHs, projects suitable management environment. Beyond this viewpoint, article expands scope 1) biomedical healthcare, 2) energy storage conversion, 3) advanced electronics. challenges, opportunities, future perspectives related role applications, inspiring further research, innovation photo-induced techniques also carefully discussed article. focused serves a valuable resource researchers industrialists interested harnessing capabilities carbon-based sustainable PAHs other pollutants. It addresses pressing need effective remediation pollution control strategies.

Language: Английский

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Harnessing visible light: enhancing TiO2 photocatalysis with photosensitizers for sustainable and efficient environmental solutions

Frontiers in Chemical Engineering, Journal Year: 2024, Volume and Issue: 6

Published: Feb. 2, 2024

The emerging field of using titanium dioxide (TiO 2 )-based photosensitizers for enhancing photocatalytic removal thiazine dyes such as methylene blue (MB) from water has long been recognized its exceptional properties, making it an attractive material environmental remediation and energy conversion. However, wide bandgap limits responsiveness to visible light. As such, the utilization TiO -based dyes, presents a promising avenue diverse applications. In addressing dual challenges pollution harnessing sustainable sources, this review focuses on their subsequent application materials. Thiazine ubiquitous in industrial effluents, pose concerns due persistence potential toxicity. Conversely, innovative approach involves employing materials photocatalysts, utilizing unique properties enhance light absorption. Studies have shown that beyond conventional role colorants, they can serve effective when coupled with . This tandem not only facilitates elimination MB, but also augments improvement performance synergy between dye sensitizers enhances overall efficiency processes like degradation splitting. Dye sensitizers, acting absorbers, efficiently transfer , thereby promoting electron generating reactive oxygen species (ROS). These ROS, turn, initiate chemical reactions, rendering valuable applications wastewater treatment, solar conversion, remediation. is crucial acknowledge drawbacks associated including toxicity non-biodegradability. Consequently, careful consideration must be given disposal. Therefore, manuscript delves into comprehensive exploration photosensitizers, shedding efficacy various removal.

Language: Английский

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Photocatalysis Meets Piezoelectricity in a Type-I Oxygen Vacancy-Rich BaTiO₃/BiOBr Heterojunction: Mechanism Insights from Characterizations to DFT Calculations

Inorganic Chemistry, Journal Year: 2024, Volume and Issue: 63(14), P. 6500 - 6513

Published: March 27, 2024

It is a challenging task to design piezoelectric photocatalyst with excellent performance under mechanical agitation instead of ultrasonic irradiation. Integrating vacancy defects into heterojunction seems be an effective strategy for synergistically increasing its piezo-photocatalytic performance. For this goal, two-step hydrothermal method was adopted architect type-I oxygen-vacancy-rich BaTiO3/BiOBr surge the degradation Rhodamine B (RhB) combined action simulated sunlight irradiation and agitation. Various instrumental techniques demonstrated formation high crystallinity. The existence surface oxygen vacancies confirmed by XPS EPR tests. PFM results manifested that had properties, response value 30.31 pm V–1. Comparative experiments indicated RhB efficiency piezo-photocatalysis over largely exceeded total sum those piezocatalysis photocatalysis. h+, ·O2–, 1O2 were dominant reactive species degradation. improved separation photogenerated charges verified electrochemical measurements. DFT calculations polarization BaTiO3 could affect electronic band structure BiOBr. This work will provide comprehensive insights mechanism at microcosmic level help develop new-styled photocatalysts.

Language: Английский

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Review on the impact of heavy metals from industrial wastewater effluent and removal technologies

Heliyon, Journal Year: 2024, Volume and Issue: 10(23), P. e40370 - e40370

Published: Nov. 15, 2024

The incidence of water pollution in developing countries is high due to the lack regulatory policies and laws that protect bodies from anthropogenic activities industrial wastewater. Industrial wastewater contains significant amounts heavy metals are detrimental human health, aquatic organisms, ecosystem. focus this review was evaluate sources treatment methods wastewater, with an emphasis on technologies, advantages, disadvantages, innovation. It observed conventional (such as flotation, coagulation/flocculation, adsorption) had shown promising results but posed certain limitations, such generation volumes sludge, relatively low removal rates, inefficiency treating metal concentrations, sensitivity varying pH. Recent technologies like nanotechnology, photocatalysis, electrochemical coagulation have advantages over for removing metals, including higher improved energy efficiency, greater selectivity specific contaminants. However, costs associated these advanced remain a major drawback. Therefore, we recommend future developments technology reducing both waste generation.

Language: Английский

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Insights into energy and environmental sustainability through photoactive graphene-based advanced materials: perspectives and promises

New Journal of Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Unlocking sustainability with photoactive graphene-based advanced materials for clean energy and environment our present posterity. Green solutions aiming at scalability, stability, cost effectiveness are provided herein.

Language: Английский

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Sulfur Vacancy‐Induced Enhancement of Piezocatalytic H₂ Production in MoS₂

Small, Journal Year: 2025, Volume and Issue: 21(11)

Published: Feb. 3, 2025

Abstract This study explores the role of S vacancies in MoS 2 enhancing its piezocatalytic efficiency. Sulfur crystal lattice introduce localized changes electronic structure and charge distribution, improving material's piezoelectric response. Characterization catalysts involved techniques like field‐emission scanning electron microscopy (FESEM), X‐ray diffraction (XRD), transmission (TEM), photoelectron spectroscopy (XPS). Electrochemical measurements, including impedance (EIS) Mott–Schottky (M‐S) analysis, are performed to assess performance. The also employed density functional theory (DFT) calculations investigate hydrogen adsorption properties with vacancies. results demonstrated that S‐deficient significantly enhanced H evolution. production rates different vacancy concentrations measured under ultrasonic vibration. sample an optimal concentration (MS‐1) exhibited highest rate 1423.29 µmol g −1 h , compared 439.06 for pristine (MS‐0). improved performance is attributed increased polarization efficient separation facilitated by

Language: Английский

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Polyaniline-Modified Iron and Copper Co-Doped Cerium Oxide Nanocomposites for Enhanced Photocatalytic Degradation of methylene blue: Synthesis, and Characterization

Colloids and Surfaces A Physicochemical and Engineering Aspects, Journal Year: 2025, Volume and Issue: unknown, P. 136469 - 136469

Published: Feb. 1, 2025

Language: Английский

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