Electrocatalytic Production of a Liquid Organic Hydrogen Carrier with Anodic Valorization of the Process: Review and Outlook DOI Creative Commons
Jiaqi Wang, Yongdan Li,

Christin Hummel

et al.

Energy & Fuels, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 25, 2024

Green hydrogen plays a crucial role in decarbonization and the future of low-carbon society. Still, its transport/distribution cost production, mainly realized by electrolysis, are major hurdles. Liquid H2 carriers reduce costs but add further expenses for their production. To address this challenge, we proposed novel strategy electrocatalytic production liquid organic carrier with anodic valorization process. This review summarizes state art outlooks new concept. The process is briefly introduced, main components discussed. Subsequently, oxidation from to processes, together paired processes reactors, analyzed, highlighting challenges prospects.

Language: Английский

Electrochemical Oxidation of Small Molecules for Energy‐Saving Hydrogen Production DOI
Hainan Sun, Xiaomin Xu, Liangshuang Fei

et al.

Advanced Energy Materials, Journal Year: 2024, Volume and Issue: 14(30)

Published: May 27, 2024

Abstract Electrochemical water splitting is a promising technique for the production of high‐purity hydrogen. Substituting slow anodic oxygen evolution reaction with an oxidation that thermodynamically more favorable enables energy‐efficient Moreover, this approach facilitates degradation environmental pollutants and synthesis value‐added chemicals through rational selection small molecules as substrates. Strategies small‐molecule electrocatalyst design are critical to electrocatalytic performance, focus on achieving high current density, selectivity, Faradaic efficiency, operational durability. This perspective discusses key factors required further advancement, including technoeconomic analysis, new reactor system design, meeting requirements industrial applications, bridging gap between fundamental research practical product detection separation. aims advance development hybrid electrolysis applications.

Language: Английский

Citations

41
Mechanistic Insights into the Role of Elements in Ni‐Co‐P Catalysts for Electrochemical Conversion of 5‐Hydroxymethylfurfural to 2,5‐Furandicarboxylic Acid DOI Creative Commons

Jongin Woo,

Jinu Choi,

Juhyung Choi

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Aug. 29, 2024

Abstract Ni phosphides and NiCo alloys are extensively explored for their remarkable efficiency in biomass alcohol oxidations, yet the underlying mechanisms remain inadequately understood. This study thoroughly elucidates roles of Ni, Co, P improving catalytic performance Ni‐Co‐P catalysts electrochemical conversion 5‐hydroxymethylfurfural (HMF) to 2,5‐furandicarboxylic acid (FDCA), a promising biomass‐derived building block replacing terephthalic acid. Phosphorization results partial formation 2 phase significantly boosts reactive NiOOH on surface, which is crucial converting HMF into FDCA. The integration Co heterojunction between enhances oxidation reactivity 5‐formyl‐2‐furancarboxylic (FFCA), pivotal intermediate influencing FDCA productivity, by selectively stabilizing aldehydes, thereby promoting further rather than surface desorption. situ /operando spectroscopic analyses consistently highlight equal significance rapid generation robust adsorption reactant molecules at achieving high performance. These insights elemental contributions set new standard designing multi‐component electrocatalysts efficient oxidation.

Language: Английский

Citations

5
Search for the Sustainable Optimum: Review of 5-(Hydroxymethyl)furfural Stability Under Various Reaction Conditions DOI Creative Commons
Anastasia N. Golysheva, Denis A. Kolykhalov, Bogdan Ya. Karlinskii

et al.

Korean Journal of Chemical Engineering, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 20, 2025

Language: Английский

Citations

0
Synthesis of 5-Hydroxymethylfurfural (HMF) from Agricultural and Food Residues: An Intermediate for 2,5-Furandicarboxylic Acid (FDCA) Production DOI
Surabhi Pandey, Valérie Orsat, Marie‐Josée Dumont

et al.

Biofuels and biorefineries, Journal Year: 2025, Volume and Issue: unknown, P. 153 - 223

Published: Jan. 1, 2025

Language: Английский

Citations

0
Research Progress on Supported Metal Catalysts for Thermal Catalytic Oxidation of 5-Hydroxymethylfurfural to 2,5-Furan Dicarboxylic Acid DOI

Yanxing Wang,

Lian Xiong, Xuefang Chen

et al.

Korean Journal of Chemical Engineering, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 15, 2025

Language: Английский

Citations

0
Enhanced electrooxidation of 5-hydroxymethylfurfural over a ZIF-67@β-Ni(OH)2/NF heterostructure catalyst: Synergistic effects and mechanistic insights DOI

Sheng Liao,

Shunli Shi,

Jie Hu

et al.

Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 688, P. 806 - 817

Published: Feb. 27, 2025

Language: Английский

Citations

0
Anionic regulation Fe/NiOOH electrocatalysts to boost electrooxidation performance of biomass derived 5-hydroxymethylfurfural DOI

Junpu An,

Hongchen Liu, Fan Yang

et al.

Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: unknown, P. 137510 - 137510

Published: April 1, 2025

Language: Английский

Citations

0
Refining Electrocatalyst Design for 5-Hydroxymethylfurfural Oxidation: Insights into Electrooxidation Mechanisms, Structure–Property Correlations, and Optimization Strategies DOI
Xupo Liu, Jianbo Tang, Ye Chen

et al.

ACS Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 7308 - 7339

Published: April 18, 2025

Language: Английский

Citations

0
Plastic Waste‐Derived Carbon Materials: Construction Strategies and Functional Applications in Energy Storage, Environmental Remediation and Organic Synthesis DOI Open Access
Zhi-Ming Ma, Lei Wang, Zijian Wang

et al.

ChemCatChem, Journal Year: 2024, Volume and Issue: unknown

Published: Aug. 14, 2024

Abstract The escalating severity of plastic waste's impact on the ecological environment and human health emphasize crucial importance developing resource‐conserving disposal technologies for sustainable development. Carbon‐based materials possess extensive functional applications across various fields, however, their high production costs heavy reliance fossil fuels pose challenges. Plastic wastes serve as ideal precursors green carbon‐based due to carbon content low‐cost. This review provides a comprehensive summary recent research progress waste‐derived (PWCMs) including primary strategies constructing PWCMs current in energy storage, environmental remediation organic synthesis.

Language: Английский

Citations

0
Electrocatalytic Production of a Liquid Organic Hydrogen Carrier with Anodic Valorization of the Process: Review and Outlook DOI Creative Commons
Jiaqi Wang, Yongdan Li,

Christin Hummel

et al.

Energy & Fuels, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 25, 2024

Green hydrogen plays a crucial role in decarbonization and the future of low-carbon society. Still, its transport/distribution cost production, mainly realized by electrolysis, are major hurdles. Liquid H2 carriers reduce costs but add further expenses for their production. To address this challenge, we proposed novel strategy electrocatalytic production liquid organic carrier with anodic valorization process. This review summarizes state art outlooks new concept. The process is briefly introduced, main components discussed. Subsequently, oxidation from to processes, together paired processes reactors, analyzed, highlighting challenges prospects.

Language: Английский

Citations

0