ChemCatChem, Journal Year: 2024, Volume and Issue: unknown
Published: Aug. 1, 2024
Abstract Aminoindanol‐derived N‐heterocyclic carbene catalysts have been widely used to achieve highly enantioselective reactions. Recently, substitution at the indane moiety of has found a great impact on outcome some reactions, even though substituted position is distant from catalytic center. Especially, introduction an electron‐withdrawing group improves yield and enantioselectivity. This review provides overview recent reports improvement N‐heterocyclic‐carbene‐catalyzed asymmetric reactions by introducing remote substituents.
Language: Английский