State of the Art and Prospects in Metal–Organic Framework (MOF)-Based and MOF-Derived Nanocatalysis

Chemical Reviews, Journal Year: 2019, Volume and Issue: 120(2), P. 1438 - 1511

Published: June 27, 2019

Metal–organic framework (MOF) nanoparticles, also called porous coordination polymers, are a major part of nanomaterials science, and their role in catalysis is becoming central. The extraordinary variability richness structures afford engineering synergies between the metal nodes, functional linkers, encapsulated substrates, or nanoparticles for multiple selective heterogeneous interactions activations these MOF-based nanocatalysts. Pyrolysis MOF-nanoparticle composites forms highly N- P-doped graphitized MOF-derived that increasingly used as efficient catalysts especially electro- photocatalysis. This review first briefly summarizes this background MOF nanoparticle then comprehensively reviews fast-growing literature reported during last years. parts organic molecular reactions, electrocatalysis, photocatalysis, views prospects. Major challenges our society addressed using well-defined fields synthesis, energy, environment. In spite many achievements, enormous progress still necessary to improve understanding processes involved beyond proof-of-concept, particularly methane oxidation, hydrogen production, water splitting, CO2 reduction methanol, nitrogen fixation, depollution.

Language: Английский

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Recent advances in MOF-based photocatalysis: environmental remediation under visible light

Inorganic Chemistry Frontiers, Journal Year: 2019, Volume and Issue: 7(2), P. 300 - 339

Published: Oct. 30, 2019

Highly photoactive MOFs can be engineered via various strategies for the purpose of extended visible light absorption, more efficient generation, separation and transfer charge carriers, as well good recyclability.

Language: Английский

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A review of metal organic framework (MOFs)-based materials for antibiotics removal via adsorption and photocatalysis

Chemosphere, Journal Year: 2021, Volume and Issue: 272, P. 129501 - 129501

Published: Jan. 7, 2021

Language: Английский

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Metal-organic framework membranes for wastewater treatment and water regeneration

Coordination Chemistry Reviews, Journal Year: 2019, Volume and Issue: 404, P. 213116 - 213116

Published: Nov. 18, 2019

Language: Английский

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Review on Metal–Organic Framework Classification, Synthetic Approaches, and Influencing Factors: Applications in Energy, Drug Delivery, and Wastewater Treatment

ACS Omega, Journal Year: 2022, Volume and Issue: 7(49), P. 44507 - 44531

Published: Dec. 2, 2022

Metal ions or clusters that have been bonded with organic linkers to create one- more-dimensional structures are referred as metal–organic frameworks (MOFs). Reticular synthesis also forms MOFs properly designated components can result in crystals high porosities and great chemical thermal stability. Due the wider surface area, huge pore size, crystalline nature, tunability, numerous shown be potential candidates various fields like gas storage delivery, energy storage, catalysis, chemical/biosensing. This study provides a quick overview of current MOF techniques order familiarize newcomers sciences field fast-growing research. Beginning classification nomenclature MOFs, approaches demonstrated. We emphasize applications such drug rechargeable batteries, supercapacitors, separation membranes. Lastly, future scope is discussed along prospective opportunities for application nano-MOFs, which will help promote their uses multidisciplinary

Language: Английский

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Removal of emerging contaminants from wastewater using advanced treatments. A review

Environmental Chemistry Letters, Journal Year: 2022, Volume and Issue: 20(2), P. 1333 - 1375

Published: Jan. 12, 2022

Language: Английский

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Recent Progress and Prospects in Catalytic Water Treatment

Chemical Reviews, Journal Year: 2021, Volume and Issue: 122(3), P. 2981 - 3121

Published: Dec. 7, 2021

Presently, conventional technologies in water treatment are not efficient enough to completely mineralize refractory contaminants. In this context, the implementation of catalytic processes could be an alternative. Despite advantages provided terms kinetics transformation, selectivity, and energy saving, numerous attempts have yet led at industrial scale. This review examines investigations different scales for which controversies limitations must solved bridge gap between fundamentals practical developments. Particular attention has been paid development solar-driven some other emerging processes, such as microwave assisted catalysis, plasma-catalytic or biocatalytic remediation, taking into account their specific drawbacks. Challenges a better understanding related complexity systems coexistence various solid-liquid-gas interfaces identified.

Language: Английский

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Metal-organic framework as a photocatalyst: Progress in modulation strategies and environmental/energy applications

Progress in Energy and Combustion Science, Journal Year: 2020, Volume and Issue: 81, P. 100870 - 100870

Published: July 7, 2020

Language: Английский

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Syntheses, design strategies, and photocatalytic charge dynamics of metal–organic frameworks (MOFs): a catalyzed photo-degradation approach towards organic dyes

Catalysis Science & Technology, Journal Year: 2021, Volume and Issue: 11(12), P. 3946 - 3989

Published: Jan. 1, 2021

The presented review focuses on design strategies to develop tailor-made MOFs/CPs of main group, transition and inner-transition elements their photocatalytic properties decompose dyes in wastewater discharge mechanism.

Language: Английский

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Fe-based metal organic frameworks (Fe-MOFs) for organic pollutants removal via photo-Fenton: A review

Chemical Engineering Journal, Journal Year: 2021, Volume and Issue: 431, P. 133932 - 133932

Published: Dec. 3, 2021

Language: Английский

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