Organic
transistors
are
becoming
an
appealing
alternative
to
conventional
semiconducting
devices
in
a
wide
range
of
application
industries
thanks
their
unique
characteristics.
Nonetheless,
it
might
be
good
idea
use
the
proper
circuital
models
simulate
behavior
during
construction
electronic
circuits
and/or
boards
before
fully
utilizing
them.
Hence,
is
imperative
precisely
extract
stricture
value
from
those
order
provide
valuable
libraries
for
hardware
design
surroundings.
To
solve
this
issue,
method
that
continuously
optimizes
model
parameters
Transistors
on
thin
Film
(OTFT)
using
Single-
and
Proposed
Multi-Objective
Evolutionary
(MOE)
Algorithms
presented.
In
establish
optimum
fit
with
empirical
transfer
features,
initially
coarsely
approximated;
estimations
then
refined
by
matching
experimental
mobility
values
multi-objective
technique.
P'type
N'type
OTFTs
have
various
channel
lengths,
so
estimating
was
necessary
assess
method's
performance.
The
findings
demonstrate
all
assessed
lengths
can
suitable
obtained
recommended
method.
The Journal of Physical Chemistry Letters,
Journal Year:
2024,
Volume and Issue:
15(7), P. 2057 - 2065
Published: Feb. 15, 2024
The
kinetics
of
electron
extraction
at
the
transfer
layer/perovskite
interface
strongly
affects
efficiency
a
perovskite
solar
cell.
By
combining
transient
absorption
and
time-resolved
photoluminescence
spectroscopy,
process
between
FA0.83Cs0.17Pb(I0.83Br0.17)3
TiO2
single
crystals
with
different
orientations
(100),
(110),
(111)
were
probed
from
subpicosecond
to
several
hundred
nanoseconds.
It
was
revealed
that
band
alignment
constituents
influenced
relative
process.
TiO2(100)
showed
fastest
overall
hot
transfer,
owing
largest
conduction
Fermi
level
offset
compared
FA0.83Cs0.17Pb(I0.83Br0.17)3.
found
an
early
accumulation
in
these
systems
can
have
influence
on
following
nanosecond
time
scale.
Furthermore,
existence
potential
barrier
TiO2/perovskite
also
by
performing
excitation
fluence-dependent
measurements.
Inorganics,
Journal Year:
2024,
Volume and Issue:
12(7), P. 188 - 188
Published: July 8, 2024
Cu-doped
TiO2
films
were
synthesized
directly
on
FTO
glass
with
a
spin
coating
method.
With
variation
in
copper
amount,
samples
prepared
0%,
1%,
2%,
4%
and
8%
of
dopant
concentrations.
Morphological
structural
characterization
undoped
investigated
the
obtained
results
showed
small,
spherical
shapes
nanoparticles
forming
thin
film
top
their
preferred
orientation
anatase
(101),
which
is
same
for
each
sample.
However,
this
peak
exhibited
slight
shift
2%
sample,
related
to
inflation
microstrain
compared
other
samples.
For
optical
properties,
sample
displayed
highest
transmittance
whereas
lowest
band
gap
energy
2.96
eV.
Moreover,
PL
intensity
seems
be
at
its
due
present
peaking
defects
structure,
shows
whole
new
signal
that
oxide.
These
properties
make
material
potential
candidate
perform
as
an
electron
transport
layer
(ETL)
solar
cells
enhance
power
conversion
efficiency.
This
study
follows
our
previous
investigation
of
charge
carrier
dynamics
at
the
hole
transport
layer
(HTL)/perovskite
(CsPbBr3)
interface,
where
pattern-illumination
time-resolved
phase
microscopy
(PI-PM)
revealed
that
HTLs
significantly
influence
extraction
and
recombination
processes.
In
absence
an
HTL,
CsPbBr3
exhibited
dominant
dynamics,
which
were
mitigated
by
introduction
Spiro-OMeTAD
P3HT,
with
latter
showing
superior
efficiency.
this
follow-up
study,
we
extend
analysis
to
electron
layers
(ETLs)
full
ETL/perovskite/HTL
structure,
investigate
modulation
separation
interfaces.
Our
results
show
TiO2,
a
widely
used
ETL,
enhances
but
still
exhibits
due
interfacial
states.
Li
Pt
doping
further
improve
separation,
Pt-doped
TiO2
demonstrating
most
significant
reduction
in
longest
lifetimes.
When
combined
HTLs,
choice
HTL
impacts
extraction:
P3HT
facilitates
more
efficient
removal
than
Spiro-OMeTAD.
The
effective
configuration
for
suppression
residual
carriers
was
achieved
as
ETL
HTL.
These
findings
provide
comprehensive
understanding
inorganic
perovskite
solar
cells,
importance
both
selection
optimizing
photovoltaic
performance.
Energy Science & Engineering,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Dec. 18, 2024
Abstract
Perovskite
solar
cells
(PSCs)
hold
great
promise
for
cost‐effective
and
high‐efficiency
energy
conversion.
However,
in
practice,
they
face
practical
limitations
due
to
suboptimal
electron
transport,
inadequate
hole‐suppression,
photocatalytic
instability,
susceptibility
other
environmental
factors.
Many
transition
metal
oxides
such
as
ZnO
TiO
2
have
important
excitonic
properties
that
make
them
good
transport
layer
(ETL)
materials
PSCs.
many
of
the
PS
arise
from
inherent
issues
with
these
oxides.
The
high
interest
is
its
low
toxicity,
chemical
stability,
potential
enhance
performance
through
doping
materials.
main
are
poor
visible‐light
response
by
virtue
wide
bandgap
~3.2
eV,
electron‐hole
(e‐h)
recombination
rates,
which
directly
responsible
current
densities.
Transition
oxide
enhancements
occur
using
either
internal
or
surface
sensitization.
Of
added
materials,
graphene
has
exceptional
electrical
conductivity,
mobility,
large
area,
excellent
mechanical
properties,
making
it
a
near‐ideal
candidate
improve
.
This
review
examines
advances
graphene‐TiO
(g‐TiO
)
composites
ETL
application.
By
forming
composite
,
can
significantly
reduce
losses,
overall
stability
We
present
detailed
rationale
analysis
g‐TiO
improved
efficiency,
enhanced
boosted
PSC
objective
providing
an
authoritative
resource
field.
Solar,
Journal Year:
2023,
Volume and Issue:
3(3), P. 347 - 361
Published: June 27, 2023
Perovskite
solar
cells
have
become
a
popular
alternative
to
traditional
silicon
due
their
potential
provide
high-efficiency,
low-cost,
and
lightweight
energy
harvesting
solutions.
However,
the
multilayer
architecture
of
perovskite
demands
careful
investigation
interaction
interfacing
between
various
layers,
as
they
play
crucial
role
in
determining
overall
performance
cell.
In
this
context,
present
work
aims
at
analyzing
coupling
spongy
transparent
electron-transporting
layer
(ETL)
formulation
CsPbI3:EuI2.
The
ETL
used
is
mesoporous
TiO2
called
“gig-lox”
(grazing
incidence
angle
geometry–local
oxidation),
which
has
been
optimized
boost
with
for
achieving
highly
interconnected
blend
materials.
gig-lox
shows
high
surface
wettability
respect
solution,
especially
after
pre-annealing
500
°C,
enables
material
deeply
infiltrate
throughout
it.
estimated
by
contact
measurements,
while
deep
infiltration
demonstrated
through
X-ray
diffraction
transmission
electron
microscopy
analyses.
Thanks
achieved
infiltration,
photo-generated
charge
injection
from
into
oxide
enhanced
use
planar
compact
oxide,
shown
photoluminescence
measurements.
mainstay
approach
resides
that
deposited
solvent-free
sputtering
method
up-scalable
industrial
throughput.