Physica Scripta,
Journal Year:
2024,
Volume and Issue:
99(8), P. 085915 - 085915
Published: July 4, 2024
Abstract
In
this
work,
Niobium-doped
(1%,
3%,
and
5%)
titanium
dioxide
(Nb-TiO
2
)
nanosheets
were
successfully
formed
via
the
hydrothermal
route
further
characterized
using
TEM,
XRD,
XPS
UV–vis
absorption
spectroscopy
techniques.
Phase
purity
structural
information
of
prepared
materials
analysed
by
XRD
measurements.
The
band
gap
values
ranged
from
3.27
to
2.98
eV
as
Nb
doping
increased,
leading
improved
photocatalytic
activity
creating
new
energy
levels
close
conduction
band.
results
confirm
amalgamation
5+
ions
into
TiO
without
affecting
crystallinity,
structure
or
orientation
occurrence
oxygen
vacancies.
3%
Nb-doped
,
degradation
efficiency
for
removing
(Methylene
blue)
MB
dye
increased
∼96%
removal
within
70
min
in
comparison
pure
other
doped
catalysts
better
Nb-TiO
is
due
longer
time
between
electron–hole
pairs
before
they
recombine
one
pair.
Hydroxyl
radicals
(HO•)
superoxide
(O
•−
are
primary
reactive
entities
responsible
deterioration
dye.
Therefore,
incorporating
nanostructures
represents
an
auspicious
material
decomposition
hazardous
toxic
pollutants
aquatic
environments.
Microscopy Research and Technique,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Feb. 24, 2025
The
current
investigation
documented
the
construction
of
eco-friendly
zinc
oxide
nanoparticles
(ZnO
NPs)
using
Araucaria
heterophylla
leaf
extract.
synthesized
material
is
characterized
through
various
techniques.
x-ray
diffraction
(XRD)
spectrum
depicted
prominent
peaks.
31.9
nm
was
determined
to
be
average
particle
size.
spherical
and
aggregated
ZnO
NPs
were
visible
in
scanning
electron
microscope
(SEM)
results.
Energy
dispersive
(EDX)
spectra
results
confirmed
existence
Zinc
oxygen
elemental
FTIR
extract
elaborated
on
participation
phytochemical
constituents.
Catalytic
activity
investigated
for
Methylene
blue
(MB)
Congo
red
dye
(CR).
For
both
dyes,
best
outcomes
are
achieved
when
concentration
5
mg/L
adsorbent
dose
10
mg,
with
a
contact
duration
20
min.
Adsorption
isotherms
(Langmuir
Freundlich)
kinetic
models
including
pseudo
first
order,
Elovich,
intraparticle
diffusion,
Boyd
also
applied
degradation
studies.
Antioxidant
potential
assessed
three
different
approaches:
total
antioxidant,
2,2-diphenyl-1-picrylhydrazyl
(DPPH)
activity,
phenolic
contents.
scavenging
free
radical
percentage
calculated
82
±
0.07
1500
μg/mL
concentration.
In
comparison
standard,
antioxidant
0.569
(%
w/w).
While
contents
244
1.4
mg
GAE/g.
Hence,
this
study
demonstrated
that
biosynthesized
exhibit
adequate
environmental
remediation
Luminescence,
Journal Year:
2024,
Volume and Issue:
39(5)
Published: May 1, 2024
The
ability
of
heterogeneous
photocatalysis
to
effectively
remove
organic
pollutants
from
wastewater
has
shown
great
promise
as
a
tool
for
environmental
remediation.
Pure
zinc
ferrites
(ZnFe
Physica Scripta,
Journal Year:
2024,
Volume and Issue:
99(8), P. 085915 - 085915
Published: July 4, 2024
Abstract
In
this
work,
Niobium-doped
(1%,
3%,
and
5%)
titanium
dioxide
(Nb-TiO
2
)
nanosheets
were
successfully
formed
via
the
hydrothermal
route
further
characterized
using
TEM,
XRD,
XPS
UV–vis
absorption
spectroscopy
techniques.
Phase
purity
structural
information
of
prepared
materials
analysed
by
XRD
measurements.
The
band
gap
values
ranged
from
3.27
to
2.98
eV
as
Nb
doping
increased,
leading
improved
photocatalytic
activity
creating
new
energy
levels
close
conduction
band.
results
confirm
amalgamation
5+
ions
into
TiO
without
affecting
crystallinity,
structure
or
orientation
occurrence
oxygen
vacancies.
3%
Nb-doped
,
degradation
efficiency
for
removing
(Methylene
blue)
MB
dye
increased
∼96%
removal
within
70
min
in
comparison
pure
other
doped
catalysts
better
Nb-TiO
is
due
longer
time
between
electron–hole
pairs
before
they
recombine
one
pair.
Hydroxyl
radicals
(HO•)
superoxide
(O
•−
are
primary
reactive
entities
responsible
deterioration
dye.
Therefore,
incorporating
nanostructures
represents
an
auspicious
material
decomposition
hazardous
toxic
pollutants
aquatic
environments.