Reka Bentuk Pasir Pantai Mesoliang bagi Penyahoksigenan Bermangkin Minyak Masak Terpakai kepada Bahan Api Keterbaharuan DOI Open Access
Darfizzi Derawi,

Nurul Huda Mohd Zahidi,

Khairul Basyar Baharudin

et al.

Sains Malaysiana, Journal Year: 2023, Volume and Issue: 52(11), P. 3177 - 3187

Published: Nov. 30, 2023

Kajian ini memfokus kepada reka bentuk mangkin dwilogam NiCo tersokong atas permukaan pasir pantai terawat HCl (P-HCl) untuk tindak balas penyahoksigenan minyak masak terpakai bagi menghasilkan hidrokarbon cecair gasolin, diesel dan bahan api jet. Mangkin berkandungan Ni (10 %bt.) Co disediakan melalui kaedah pengisitepuan NiCo/P-HCl. Po, P-HCl NiCo/P-HCl telah dilakukan pencirian fizikal aktiviti pemangkinan diuji penyahoksigenan. Prestasi dinilai dari segi peratusan hasil kepilihan mengikut julat karbon gasolin (C8-C11), (C11-C17) jet (C8-C16). Perawatan bertindak dengan logam oksida yang mempunyai keelektropositifan lebih tinggi (Al2O3 Fe2O3), seterusnya menyebabkan pengurangan komposisi tersebut, masing-masing sebanyak 10.0% 12.5%. Pengurangan mempengaruhi keporosan penyokong dirawat. Setelah pemuatan Co, berstruktur mesoliang (5.9 nm) terhasil peningkatan luas (22.5 m2/g) isi padu liang (0.032 cm3/g). berjaya menukarkan 71%, keutamaan produk iaitu (86%), (83%) (17%). Penukaran keterbaharuan bakal memberikan nilai tambah menyokong inisiatif teknologi hijau serta kitaran ekonomi mampan.

Hydrogen-Free Deoxygenation of Oleic Acid and Industrial Vegetable Oil Waste on CuNiAl Catalysts for Biofuel Production DOI Creative Commons
José Sabino da Silva Neto, Denisson O. Liborio, Santiago Arias

et al.

Energies, Journal Year: 2023, Volume and Issue: 16(17), P. 6131 - 6131

Published: Aug. 23, 2023

The pyrolysis of vegetable oil waste is an alternative way to convert biomass into high-quality second-generation biofuels, with social, economic and environmental sustainability. present work deals the oleic acid as a model compound industrial residue on CuNiAl mixed oxide catalysts, derived from layered double hydroxides. Reactions oils pre-adsorbed catalysts (catalyst:oil mass ratio 5:1) were performed at 550 °C micro-pyrolysis system analyses volatile products carried out online using GC/MS. Copper addition NiAl increased cracking acid. Increasing copper content also decreased formation aromatics coke precursors, well oxygenated compounds. catalyst Cu/Ni 0.4 showed strong catalytic activity in conversion high volume free fatty acids produced. Compared non-catalytic reaction, reduced oxygenates hydrocarbons, particularly gasoline range (C5–C9). was able residues hydrocarbons gasoline, kerosene diesel, linear alkylbenzenes chemical precursors for surfactant production.

Language: Английский

Citations

13
In-situ preparation of MnFeCoNiCu/C for the sustainable co-production of bio-jet fuel and green diesel under solvent-free and low hydrogen pressure conditions DOI
Kaiyue Wu,

Yao Quan,

Dechao Wang

et al.

Energy Conversion and Management, Journal Year: 2024, Volume and Issue: 318, P. 118875 - 118875

Published: Aug. 6, 2024

Language: Английский

Citations

4
Lipids of Yeasts and Filamentous Fungi and Their Importance to Biotechnology DOI
Volkmar Passoth, Bettina Müller

Grand challenges in biology and biotechnology, Journal Year: 2025, Volume and Issue: unknown, P. 163 - 227

Published: Jan. 1, 2025

Language: Английский

Citations

0
Catalytic Upgrading of Bio-crude Oil to Synthetic Transportation Fuels DOI

Angélica Avila-Anguis,

Carlos Eduardo Guzmán-Martínez, Salvador Hernández

et al.

Biofuel and biorefinery technologies, Journal Year: 2025, Volume and Issue: unknown, P. 263 - 284

Published: Jan. 1, 2025

Language: Английский

Citations

0
Production of Green Diesel via the Ni/Al Mo Hydrotalcite Catalyzed Deoxygenation of Rapeseed Oil DOI Creative Commons
Giuseppe Di Vito Nolfi, Katia Gallucci,

Vittoria Mucciante

et al.

Molecules, Journal Year: 2025, Volume and Issue: 30(8), P. 1699 - 1699

Published: April 10, 2025

Growing concern about anthropogenic climate change and the continuous increase in energy demand have driven need to explore new sources, particularly transportation sector. Biodiesel is one of most widely used biofuels, but its disadvantages restrict use blends with conventional diesel. A better alternative green diesel, a hydrocarbon biofuel that can be pure form produced through catalytic deoxygenation vegetable oils. In this study, NiMoAl catalyst derived from layered double hydroxides (LDHs) was synthesized for rapeseed oil produce The characterized using IR, XRD, BET analysis. reactions were carried out batch reactor, parameters such as temperature, pressure, loading, reaction time examined. results demonstrated complete conversion achieved under optimal conditions (320 °C, 40 bar H2, 4 wt% catalyst), diesel-range content over 90%. recyclability also evaluated, showing sustained activity multiple cycles while maintaining high selectivity toward hydrocarbons diesel range.

Language: Английский

Citations

0
Hexanoic acid upgrading into hexyl hexanoate: An efficient way to obtain a new sustainable biofuel DOI
Valeria D’Ambrosio, Antonella Angelini, Carlo Pastore

et al.

Fuel, Journal Year: 2024, Volume and Issue: 368, P. 131631 - 131631

Published: April 11, 2024

Language: Английский

Citations

3
Sustainable biofuel synthesis from non-edible oils: a mesoporous ZSM-5/Ni/Pt catalyst approach DOI Creative Commons

V.L. Mangesh,

P. Tamizhdurai,

S. Santhosh

et al.

RSC Advances, Journal Year: 2024, Volume and Issue: 14(11), P. 7728 - 7739

Published: Jan. 1, 2024

This work examines the hydrodeoxygenation (HDO) activity of non-edible oils using a high surface area catalyst.

Language: Английский

Citations

2
ScCO2 decarboxylation of oleic acid to green diesel DOI

Alex Stephen Morgan,

Md. Zakir Hossain,

Muhammad B.I. Chowdhury

et al.

The Journal of Supercritical Fluids, Journal Year: 2023, Volume and Issue: 205, P. 106120 - 106120

Published: Nov. 23, 2023

Language: Английский

Citations

5
Influence of Nickel Loading and the Synthesis Method on the Efficiency of Ni/TiO2 Catalysts for Renewable Diesel Production DOI Creative Commons
George Petropoulos,

John Zafeiropoulos,

Eleana Kordouli

et al.

Energies, Journal Year: 2023, Volume and Issue: 16(11), P. 4333 - 4333

Published: May 25, 2023

The efficiency of Ni/TiO2 catalysts for renewable diesel production was evaluated in the present study. Two series were synthesized and characterized using various physicochemical techniques (N2 physisorption, XRD, SEM, XPS, H2-TPR, NH3–TPD). In first catalysts, successive dry impregnations (SDI) used depositing 10, 20, 30, 50, 60 wt.% Ni. yield towards is maximized over catalyst with 50 Ni loading. Selecting this optimum loading, a second via three additional preparation methods: wet impregnation (WI) deposition–precipitation either ammonia (DP-NH3) or urea (DP-Urea) as precipitation agent. catalysts’ green influenced by method following order: DP-Urea > DP-NH3 WI ≈ SDI. metallic surface area balanced acidity mainly determine performance catalysts.

Language: Английский

Citations

4
Transition metal oxide nanocatalysts for the deoxygenation of palm oil to green diesel DOI Creative Commons

C. E. Guerrero-Corona,

J.A. Melo‐Banda, Mayda Lam-Maldonado

et al.

Frontiers in Chemical Engineering, Journal Year: 2024, Volume and Issue: 6

Published: Feb. 22, 2024

This study investigated the hydrodeoxygenation of palm oil by different oxide nanocatalysts transition metals α -Fe 2 O 3 , NiO, and NiFe 4 which were synthesized hot injection. All nanomaterials characterized X-ray diffraction, Fourier transform infrared spectroscopy, dynamic light dispersion. The catalytic evaluation was performed in a Parr-type reactor at 350°C, 3.5 MPa H pressure, h reaction. liquid product obtained analyzed ultraviolet-visible spectroscopy to identify n-C 16 generated during activity deoxygenation fatty acids produce hydrocarbons has following order: α-Fe < NiO.

Language: Английский

Citations

1