Chalcogen-Bonded [Se–N]2 Cyclic Supramolecular Synthons Enhanced by Halogen Bonds: Studies in the Gas Phase and Crystalline Phase DOI Open Access
Shaobin Miao, Xiaotian Sun, Yu Zhang

et al.

International Journal of Molecular Sciences, Journal Year: 2025, Volume and Issue: 26(5), P. 2324 - 2324

Published: March 5, 2025

Chalcogen-bonded [Se-N]2 is a strong cyclic supramolecular synthon in chemistry. Selenadiazole commonly used the synthesis of [Se-N]2. One nitrogen atom selenadiazole molecule participates formation [Se-N]2, while other can participate types noncovalent bonds. Investigating effect neighboring bonds on beneficial for its further and application. In this study, we combined theoretical calculations crystallography to explore I···N halogen both gas phase crystalline phase. Gas-phase show that increases strength bond directly proportional phase, influenced by more addition bonds, making results complex. However, if relatively small, remains It believed conclusions drawn from are also applicable

Language: Английский

Chalcogen-Bonded [Se–N]2 Cyclic Supramolecular Synthons Enhanced by Halogen Bonds: Studies in the Gas Phase and Crystalline Phase DOI Open Access
Shaobin Miao, Xiaotian Sun, Yu Zhang

et al.

International Journal of Molecular Sciences, Journal Year: 2025, Volume and Issue: 26(5), P. 2324 - 2324

Published: March 5, 2025

Chalcogen-bonded [Se-N]2 is a strong cyclic supramolecular synthon in chemistry. Selenadiazole commonly used the synthesis of [Se-N]2. One nitrogen atom selenadiazole molecule participates formation [Se-N]2, while other can participate types noncovalent bonds. Investigating effect neighboring bonds on beneficial for its further and application. In this study, we combined theoretical calculations crystallography to explore I···N halogen both gas phase crystalline phase. Gas-phase show that increases strength bond directly proportional phase, influenced by more addition bonds, making results complex. However, if relatively small, remains It believed conclusions drawn from are also applicable

Language: Английский

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