Sustainable Solutions for Desalination Plant Outfall Brine: Modified Halloysite Nanoclay-Based Remediation of Heavy Metals and Salinity DOI Creative Commons

Naif S. Aljohani,

Yasar N. Kavil,

Radwan Kh Al-Farawati

et al.

Desalination and Water Treatment, Journal Year: 2024, Volume and Issue: 318, P. 100410 - 100410

Published: April 1, 2024

The aim of this research is to craft a material that effectively curbs the higher level heavy metals and salinity in brine from desalination plants. Through thorough experimentation, an optimized form Halloysite Nanoclay was achieved, which further enhanced with 8-hydroxyquinoline for increased metal removal efficiency. nanoclay's adsorption capabilities were carefully fine-tuned, displaying type III isotherm significant surface area (72.8 m² g–1). modified nanoclay demonstrates improved efficiency removing ions, achieving rates 79.12% Zn, 83.33% Fe, 81.18% Ni, 79.81% Cu. Notably, advanced proved its prowess purifying metals. prepared displayed noteworthy recycling capacity, substantiated through series experiments. This study highlights effectiveness using treat plant sustainably, opening avenues practical applications area.

Language: Английский

Adsorption of REEs: A Comprehensive Review on Spinel Ferrites and their Magnetic Composites as Highly Efficient Adsorbents DOI Creative Commons
Seyed Faridedin Rafie, Nidal Abu‐Zahra, Mika Sillanpää

et al.

Emerging contaminants, Journal Year: 2024, Volume and Issue: 11(1), P. 100429 - 100429

Published: Oct. 29, 2024

Language: Английский

Citations

3

Synthesis and Modification of Magnetic Nanoparticles for Biosensing and Bioassay Applications: A Review DOI Creative Commons
Soledad Carinelli, Maximina Luis-Sunga, José Luis González–Mora

et al.

Chemosensors, Journal Year: 2023, Volume and Issue: 11(10), P. 533 - 533

Published: Oct. 10, 2023

Biosensors are analytical devices that use biological interactions to detect and quantify single molecules, clinical biomarkers, contaminants, allergens, microorganisms. By coupling bioreceptors with transducers, such as nucleic acids or proteins, biosensors convert into electrical signals. Electrochemical optical transductions the most widely used methods due their high detection capability compatibility miniaturization. valuable in chemistry, especially for health diagnostics, they offer simplicity sensitivity. Despite usefulness, challenges persist immobilizing biorecognition elements on transducer surface, leading issues loss of sensitivity selectivity. To address these problems, introduction nanomaterials, particular magnetic nanoparticles (MNPs) beads, has been implemented. MNPs combine properties other interesting characteristics, small size, surface-to-volume ratio, easy handling, excellent biocompatibility, resulting improved specificity reduced matrix effects. They can be tailored specific applications have extensively various fields, including biosensing diagnosis. In addition, simplify sample preparation by isolating target analytes via separation, thus reducing analysis time interference phenomena improving performance detection. The synthesis modification play a crucial role adjusting different applications. This review presents an overview surface modifications contributions development bioassays across areas. future MNP integration assays focused stability, multiplex detection, simplification portability test platforms, vivo applications, among areas development.

Language: Английский

Citations

8

Two alternative approaches for the magnetic adsorption of the hydrophobic dye Methylene Blue DOI Creative Commons
Filomena Sannino, Paolo Allia, Gabriele Barrera

et al.

Journal of Molecular Liquids, Journal Year: 2024, Volume and Issue: 409, P. 125395 - 125395

Published: June 29, 2024

Many of the most harmful pollutants contained in wastewaters are hydrophobic compounds. Consequently, selection suitable adsorbents to remove Methylene Blue (MB), adopted as model contaminant, was carried out evaluating two alternative approaches. First, nanocomposites containing biochar were tested exploit interaction between adsorbent and adsorbate. As an approach, a nanocomposite based on chitosan, material substantially hydrophilic though methyl groups, found allow adsorption by both hydrogen-bond interactions. Both biochar- chitosan- inserted magnetic nanoparticles crosslinking impregnation simpler solid/liquid separation. XRD, FTIR SEM analyses elucidated properties nanocomposites, showing fraction be mainly composed maghemite, with crystallite size about 8 mm. The M(H) curves showed pure superparamagnetic behaviour nanoparticles, larger moments comparison chitosan (5.8 × 10−20 Am2 against 3.5 Am2). mechanism MB discussed considering zero-point charges oxidation–reduction system molecules. higher capacity shown lower range concentration (1.57 105 mg/kg) explained taking into account overlapping effects polar Kinetics isotherms modelling suggested multistep process, due different phases constituting nanocomposites. An efficient regeneration procedure developed for chitosan-based nanocomposite, incubation acetic acid/ethanol mixture.

Language: Английский

Citations

2

Recent Developments in Metal‐Organic Frameworks for Water Purification: A Mini Review DOI
Smriti Rana, Yogesh Kumar,

Rahul Kaushik

et al.

ChemistrySelect, Journal Year: 2024, Volume and Issue: 9(35)

Published: Sept. 12, 2024

Abstract Heavy metals, pharmaceuticals, microplastics, dyes, and radionuclides in wastewater increasingly threaten environmental sustainability. Metal‐organic frameworks (MOFs) are versatile materials for mitigating these contaminants through efficient detection, capture, adsorption, degradation. These crystalline structures, formed by combining metal ions with organic ligands, offer high surface area, tailored porosity, reproducibility, robust chemical stability. This review compiles recent advancements MOFs pollutant removal, highlighting innovations selective adsorption mechanisms heavy functionalized pharmaceutical microplastic enhanced photocatalytic degradation dyes. Unique to this is the integration of such as ion exchange capabilities under visible light, addressing advanced applications that significantly enhance removal efficiency other reviews have not covered comprehensively. The also cites our group's work on a curcumin‐immobilized zeolitic imidazolate framework‐8 (Cmim@ZIF‐8) nanoprobe, demonstrating selectivity Fe 2+ water (detection limit: 7.64 μM) its applicability live‐cell imaging HepG2 cells. Advanced techniques like density functional theory (DFT) simulations employed elucidate mechanisms, bridging theoretical insights experimental findings. By critically evaluating developments, identifies promising avenues optimizing MOF design advancing effective treatment solutions.

Language: Английский

Citations

2

Sustainable Solutions for Desalination Plant Outfall Brine: Modified Halloysite Nanoclay-Based Remediation of Heavy Metals and Salinity DOI Creative Commons

Naif S. Aljohani,

Yasar N. Kavil,

Radwan Kh Al-Farawati

et al.

Desalination and Water Treatment, Journal Year: 2024, Volume and Issue: 318, P. 100410 - 100410

Published: April 1, 2024

The aim of this research is to craft a material that effectively curbs the higher level heavy metals and salinity in brine from desalination plants. Through thorough experimentation, an optimized form Halloysite Nanoclay was achieved, which further enhanced with 8-hydroxyquinoline for increased metal removal efficiency. nanoclay's adsorption capabilities were carefully fine-tuned, displaying type III isotherm significant surface area (72.8 m² g–1). modified nanoclay demonstrates improved efficiency removing ions, achieving rates 79.12% Zn, 83.33% Fe, 81.18% Ni, 79.81% Cu. Notably, advanced proved its prowess purifying metals. prepared displayed noteworthy recycling capacity, substantiated through series experiments. This study highlights effectiveness using treat plant sustainably, opening avenues practical applications area.

Language: Английский

Citations

2