Method for Valorization of Coffee Cherry Waste via Hydrothermal Valorization Using Organic and Inorganic Acids as Catalysts DOI Creative Commons
Alejandra Sophia Lozano Pérez,

Valentina Romero Mahecha,

Carlos Alberto Guerrero Fajardo

et al.

Methods and Protocols, Journal Year: 2024, Volume and Issue: 7(6), P. 87 - 87

Published: Oct. 29, 2024

The valorization of coffee cherry waste through hydrothermal carbonization (HTC) was investigated using various organic and inorganic acid catalysts to produce platform chemicals. This study aimed evaluate the effectiveness these for enhancing reaction rates, improving yields, promoting selectivity. results showed that sulfuric adipic were most effective, each resulting in a 20% increase total yield, demonstrating potential acids as efficient HTC. Other catalysts, such benzoic phenylacetic acid, also promising results, while butyric significantly decreased yield. abundantly produced chemicals sugars, followed by formic levulinic HMF, furfural. These findings highlight valuable resource producing key chemicals, feasibility sustainable approach biomass valorization. emphasizes importance selecting appropriate optimize conversion process maximize extraction environmental economic implications are significant, they can contribute development utilization technologies could transform agricultural into high-value products reducing circular economy.

Language: Английский

Advancements in Lignin Valorization for Energy Storage Applications: Sustainable Technologies for Lignin Extraction and Hydrothermal Carbonization DOI Creative Commons
Haoyu Wang,

H.Y. Meng,

Joshua O. Olowoyo

et al.

Nanomaterials, Journal Year: 2025, Volume and Issue: 15(4), P. 309 - 309

Published: Feb. 18, 2025

The conversion of industrial waste lignin into sustainable carbon materials is an essential step towards reducing dependency on fossil fuels and mitigating environmental impacts. This review explores various aspects utilization, with particular focus the extraction application lignin-derived in energy storge applications. advanced chemical methods to improve efficiency biomass conversion, detailing emerging technologies for from biomasses using innovative solvents techniques, such as Ionic Liquids Deep Eutectic Solvents (DESs). Additionally, it discusses parameters that impact hydrothermal carbonization (HTC) process. produced hydrochar shows potential use optimized precursors storage also considers implications these sustainability circular economy, suggesting future research directions enhance scale processes global impact. comprehensive analysis highlights critical role achieving outlines pathways lignin-based innovations.

Language: Английский

Citations

0

Hydrothermal carbonization of plastic wastes and effect of influential parameters on performance and challenges: a review DOI
Sakine Shekoohiyan,

A. Sajadi,

Gholamreza Moussavi

et al.

International Journal of Environmental Science and Technology, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 19, 2025

Language: Английский

Citations

0

Conversion of cellulose to highly aromatic hydrochar by catalytic hydrothermal carbonization: The role of lanthanide(III) ions DOI

Sung-Chul Han,

Mingshu Chi, Xiuling Xu

et al.

Biomass Conversion and Biorefinery, Journal Year: 2025, Volume and Issue: unknown

Published: March 3, 2025

Language: Английский

Citations

0

From Cellulose to Highly Aromatic Hydrochar: Catalytic Carbonization and Catalytic Aromatization Mechanism of Lanthanide (III) Ions DOI Open Access

Sung-Chul Han,

Mingshu Chi, Xiuling Xu

et al.

Catalysts, Journal Year: 2025, Volume and Issue: 15(3), P. 245 - 245

Published: March 5, 2025

Hydrothermal carbonization (HTC) is an efficient method for converting lignocellulosic biomass into biofuels. However, traditional Brønsted acid-catalyzed HTC processes face challenges such as high costs and limited catalytic efficiency. In this study, the mechanism was investigated within temperature range of 180–220 °C by analyzing evolution functional groups in hydrochar under lanthanide (III)-catalyzed non-catalyzed conditions. The results indicate that compared to acid catalysis, (III) exhibits superior performance during low-temperature cellulose. At 200 °C, accelerates conversion cellulose char microparticles, while at 220 it promotes complete hydrolysis microparticles enriched with furan structures. Characterization analyses revealed enhances formation HMF (5-hydroxymethylfurfural), suppresses its LA (levulinic acid), polymerization indirectly oligosaccharides.

Language: Английский

Citations

0

Preparation of Biochar through Low-Temperature Carbonization of Hydroxyl-Rich Biopolymers Using N-Bromosuccinimide DOI

Km Shelly,

Kartik Ravishankar, R. Dhamodharan

et al.

ACS Sustainable Resource Management, Journal Year: 2025, Volume and Issue: unknown

Published: April 15, 2025

Language: Английский

Citations

0

Pea Pod Valorization: Exploring the Influence of Biomass/Water Ratio, Particle Size, Stirring, and Catalysts on Chemical Platforms and Biochar Production DOI Open Access

Daniel Esteban Galvis Sandoval,

Alejandra Sophia Lozano Pérez, Carlos Alberto Guerrero Fajardo

et al.

Sustainability, Journal Year: 2024, Volume and Issue: 16(17), P. 7352 - 7352

Published: Aug. 27, 2024

This study delves into the valorization of pea pod waste using hydrothermal processes, focusing on optimizing key parameters such as temperature, biomass-to-water ratio, particle size, and catalyst influence. Noteworthy findings include significant impact temperature variations product yields, with 180 °C favoring sugars, HMF, furfural, while 220 260 lead to distinct platform chemical productions. The utilization a 1:20 ratio consistently enhances yields by 10%, underscoring its importance in promoting efficient hydrolysis without excessive degradation. Furthermore, investigation size reveals that smaller dimensions, particularly 1 mm particles, improved heat mass transfer, reduced diffusion barriers, enhanced digestibility, ultimately boosting overall efficiency production. Moreover, sheds light role catalysts showcasing differential acid basic yields. Acid demonstrate notable increase up 135.5% production chemicals, emphasizing their crucial enhancing reaction efficiency. complex relationship between agitation, formation is elucidated, experiments revealing varying outcomes based presence or absence agitation at different temperatures. These provide valuable insights valorization, offering pathway towards sustainable conversion agricultural residues chemicals.

Language: Английский

Citations

2

Textile microfibers valorization by catalytic hydrothermal carbonization towards high-tech carbonaceous materials DOI Creative Commons

S. Parrilla-Lahoz,

Marielis C. Zambrano, Joel J. Pawlak

et al.

iScience, Journal Year: 2024, Volume and Issue: 27(12), P. 111427 - 111427

Published: Nov. 19, 2024

Microplastics fibers shed from washing synthetic textiles are released directly into the waters and make up 35% of primary microplastics discharged to aquatic environment. While filtration devices regulations in development, safe disposal methods remain absent. Herein, we investigate catalytic hydrothermal carbonization (HTC) as a means integrating this waste (0.28 million tons microfibers per year) circular economy by upcycling carbon nanomaterials. show that cotton polyester can be converted filamentous solid nanostructures using Fe-Ni catalyst during HTC. Results revealed conversion amorphous graphitic structures, including nanotubes cotton/polyethylene terephthalate (PET) mixture. HTC at 200°C 22 bar pressure produced all samples, demonstrating mixed microfiber wastes valorized provide potentially valuable structures modifying reaction parameters formulation.

Language: Английский

Citations

2

Method for Valorization of Coffee Cherry Waste via Hydrothermal Valorization Using Organic and Inorganic Acids as Catalysts DOI Creative Commons
Alejandra Sophia Lozano Pérez,

Valentina Romero Mahecha,

Carlos Alberto Guerrero Fajardo

et al.

Methods and Protocols, Journal Year: 2024, Volume and Issue: 7(6), P. 87 - 87

Published: Oct. 29, 2024

The valorization of coffee cherry waste through hydrothermal carbonization (HTC) was investigated using various organic and inorganic acid catalysts to produce platform chemicals. This study aimed evaluate the effectiveness these for enhancing reaction rates, improving yields, promoting selectivity. results showed that sulfuric adipic were most effective, each resulting in a 20% increase total yield, demonstrating potential acids as efficient HTC. Other catalysts, such benzoic phenylacetic acid, also promising results, while butyric significantly decreased yield. abundantly produced chemicals sugars, followed by formic levulinic HMF, furfural. These findings highlight valuable resource producing key chemicals, feasibility sustainable approach biomass valorization. emphasizes importance selecting appropriate optimize conversion process maximize extraction environmental economic implications are significant, they can contribute development utilization technologies could transform agricultural into high-value products reducing circular economy.

Language: Английский

Citations

0