Hydrogen Embrittlement Resistance of Ferritic–Pearlitic Pipeline Steel with Non-Electrochemically Deposited Copper- or Nickel–Phosphorus-Based Coating DOI Open Access
Ladislav Falat, Lucia Čiripová, František Kromka

et al.

Coatings, Journal Year: 2025, Volume and Issue: 15(5), P. 585 - 585

Published: May 15, 2025

This work deals with the effects of a non-electrochemically deposited copper- or nickel–phosphorus-based coating on resulting resistance traditional X42 grade pipeline steel against hydrogen embrittlement (HE). The susceptibility to HE was determined by evaluation index (HEI) from results conventional room-temperature tensile tests using cylindrical specimens. Altogether, three individual material systems were studied, namely uncoated (X42) and two coated steels, specifically either copper-based (X42_Cu) (X42_Ni-P). HEI values calculated as relative changes in mechanical properties corresponding non-hydrogenated electrochemically hydrogen-precharged test conditions. Both applied coatings considerably improved investigated terms decreasing related yield stress, ultimate strength, reduction area. In contrast, hydrogenation both had detrimental value total elongation, which resulted an increase value. behavior likely earlier onset necking during straining due strain localizations induced coatings’ surface imperfections. findings fractographic observations indicated that studied acted like protective barriers permeation. However, quality pores other superficial defects considered remains challenging issue.

Language: Английский

The Influence of Ti and Al on the Evolution of Microstructure and Mechanical Properties in Medium-Entropy and High-Entropy Alloys Based on AlxTixCrFe2Ni2 DOI Open Access
Róbert Kočiško, Patrik Petroušek, Karel Saksl

et al.

Materials, Journal Year: 2025, Volume and Issue: 18(6), P. 1382 - 1382

Published: March 20, 2025

This study focuses on the cobalt-free medium-to-high-entropy alloys AlxCrFe2Ni2 and AlxTixCrFe2Ni2, investigating influence of Alx Tix (where x = 0.2, 0.3, 0.4, 0.5, 0.6) development microstructural mechanical properties in as-cast annealed states. Structural changes were examined using optical microscopy, scanning electron microscopy (SEM), X-ray diffraction (XRD) measurements, while evaluated through Vickers hardness testing compression testing. analysis confirmed that increasing Al content state leads to formation a BCC phase, which completely dissolves into FCC matrix after homogenization annealing. These single-phase exhibit good ductility with relatively high strain hardening, such as Al0.6CrFe2Ni2 alloy, achieved maximum compressive strength σmax=1511 MPa at 50% deformation. A significant strengthening effect Ti was observed AlxTixCrFe2Ni2 alloys, are closely linked higher phase homogenized structure. The highest strength, σmax=2239 MPa, by Al0.5Ti0.5CrFe2Ni2 fractured via transcrystalline brittle fracture 43% All investigated offer an excellent balance between ductility, could meet requirements demanding structural applications.

Language: Английский

Citations

0

Hydrogen Embrittlement Resistance of Ferritic–Pearlitic Pipeline Steel with Non-Electrochemically Deposited Copper- or Nickel–Phosphorus-Based Coating DOI Open Access
Ladislav Falat, Lucia Čiripová, František Kromka

et al.

Coatings, Journal Year: 2025, Volume and Issue: 15(5), P. 585 - 585

Published: May 15, 2025

This work deals with the effects of a non-electrochemically deposited copper- or nickel–phosphorus-based coating on resulting resistance traditional X42 grade pipeline steel against hydrogen embrittlement (HE). The susceptibility to HE was determined by evaluation index (HEI) from results conventional room-temperature tensile tests using cylindrical specimens. Altogether, three individual material systems were studied, namely uncoated (X42) and two coated steels, specifically either copper-based (X42_Cu) (X42_Ni-P). HEI values calculated as relative changes in mechanical properties corresponding non-hydrogenated electrochemically hydrogen-precharged test conditions. Both applied coatings considerably improved investigated terms decreasing related yield stress, ultimate strength, reduction area. In contrast, hydrogenation both had detrimental value total elongation, which resulted an increase value. behavior likely earlier onset necking during straining due strain localizations induced coatings’ surface imperfections. findings fractographic observations indicated that studied acted like protective barriers permeation. However, quality pores other superficial defects considered remains challenging issue.

Language: Английский

Citations

0