Major and Trace Element Accumulation in Soils and Crops (Wheat, Corn, Sunflower) around Steel Industry in the Lower Danube Basin and Associated Ecological and Health Risks
Applied Sciences,
Journal Year:
2024,
Volume and Issue:
14(13), P. 5616 - 5616
Published: June 27, 2024
The
study
aimed
to
evaluate
for
the
first
time
degree
of
contamination
soil
and
crops
with
major
trace
elements
(Cd,
Co,
Cr,
Cu,
Ni,
Pb,
Zn,
F,
Na,
Mg,
Si,
P,
Cl,
Fe,
Al)
in
agricultural
lands
situated
Lower
Danube
Basin,
Galati
Braila
counties
(SE
Romania),
impacted
by
steel
industry.
Soil
samples,
as
well
leaves
seeds
wheat,
corn,
sunflower,
were
collected
from
two
depths
11
different
sites.
Along
elemental
mineralogical
analyses,
performed
HR-CS
AAS,
PIGE,
SEM-EDX,
ATR-FTIR,
pH,
texture,
organic
matter,
electric
conductivity,
CaCO3
content
investigated.
results
showed
that
levels
Cr
(83.27–383.10
mg
kg−1),
Cu
(17.11–68.15
Ni
(30.16–55.66
F
(319–544
kg−1)
exceeded
Romanian
regulations
sensitive
use
land.
Igeo,
EF,
PI,
PERI
pollution
indices
indicate
is
moderate
highly
contaminated
while
CSI
mERMQ
suggested
a
relatively
low
risk
metal
contamination.
concentrations
plant
tissues
bioaccumulation
factors
(BFs)
provide
valuable
insights
into
soil–plant
relationship,
health
risks,
selectivity
compartments
elements.
Thus,
revealed
wheat
plants
tended
exclude
particular
their
tissues,
exhibiting
pattern
Zn
Cu.
In
case
most
BFs
below
one,
indicating
limited
phytoaccumulation
capacity.
However,
exceptions
observed
Cd,
sunflower
higher
bioconcentration
these
compared
other
Chromium
(Cr)
contributes
non-carcinogenic
dermal
contact
ingestion
hazards,
children
being
more
susceptible
adverse
effects
this
contaminant.
Language: Английский
Major and Trace Elements in Soils from an Industrial Area in the Lower Danube Basin: Levels, Transfer to Crops (Wheat, Corn, Sunflower) and Health Risk
Published: May 29, 2024
The
study
aimed
to
evaluate
for
the
first
time
degree
of
contamination
soil
and
crops
with
major
trace
elements
(Cd,
Co,
Cr,
Cu,
Ni,
Pb,
Zn,
F,
Na,
Mg,
Si,
P,
Cl,
Fe,
Al)
in
agricultural
lands
situated
Lower
Danube
Basin,
Galati
Braila
counties
(SE
Romania),
impacted
by
steel
industry.
Soil
samples
from
two
depths
(0–5
cm
5–30
cm),
as
well
leaves
seeds
wheat,
corn,
sunflower,
were
collected
11
different
sites.
Along
elemental
mineralogical
analysis,
performed
HR-CS
AAS,
PIGE,
SEM-EDX
ATR-FTIR,
pH,
texture,
organic
matter,
electric
conductivity
CaCO3
content
investigated.
results
showed
that
levels
Cr
(83.270–383.100
mg
kg-1),
Cu
(17.110–68.151
Ni
(30.157–55.656
F
(319–544
kg-1)
exceeded
Romanian
regulations
sensitive
use
land.
pollution
indices
(Igeo,
EF,
PI,
PERI)
indicate
is
moderate
highly
contaminated
while
CSI
mERMQ
suggested
a
relatively
low
risk
metal
contamination.
concentrations
plant
tissues
bioaccumulation
factors
(BFs)
show
soil-plant
relation
health
risk,
but
also
selectivity
vegetal
compartments.
Thus,
wheat
plants
tend
exclude
certain
their
tissues,
Zn
pattern
different.
In
case
most
BFs
below
1,
indicating
limited
phytoaccumulation
capacity.
However,
exceptions
observed
Cd,
Cu.
Sunflower
higher
bioconcentration
both
compared
other
elements.
Chromium
(Cr)
contributes
non-carcinogenic
dermal
contact
ingestion
hazards,
children
being
more
susceptible
adverse
effects
this
contaminant.
Language: Английский