Exploring the Role of pH and Solar Light-Driven Decontamination with Singlet Oxygen in Removing Emerging Pollutants from Agri-Food Effluents: The Case of Acetamiprid DOI Creative Commons
Víctor Fabregat

Physchem, Journal Year: 2025, Volume and Issue: 5(1), P. 9 - 9

Published: Feb. 22, 2025

Previously synthesized and tested water-dispersible photoactive polymeric microparticles have been employed as heterogenous photosensitizers to evaluate their performance in generating singlet oxygen through direct solar irradiation. This study utilizes these photocatalysts for the degradation of Acetamiprid IWWTP wastewater effluents from Agri-food industry, exploring, addition or simulated irradiation, influence pH on photooxidation process. Over a thousand emerging pollutants, including pesticides like Acetamiprid, detected aquatic environments recent years, posing challenges due limitations current treatment technologies. The developed method is particularly effective under basic slightly conditions, aligning with natural addressing limitation conventional methods, which typically require medium acidification be effective. Polymers P3 P4 exhibited high photocatalytic activity, achieving over 99% oxidation via generated by Rose Bengal supported polymer matrix, while maintaining catalytic efficiency across multiple cycles. results confirm that removal industrial irradiation feasible, though constrained availability sufficient sunlight hours.

Language: Английский

Biochar as Sustainable Alternative and Green Adsorbent for the Remediation of Noxious Pollutants: A Comprehensive Review DOI Creative Commons

Stuti Jha,

Rama Gaur, Syed Shahabuddin

et al.

Toxics, Journal Year: 2023, Volume and Issue: 11(2), P. 117 - 117

Published: Jan. 25, 2023

The current water crisis necessitates the development of new materials for wastewater treatment. A variety nanomaterials are continuously being investigated their potential as adsorbents environmental remediation. Researchers intend to develop a low-cost, simple, and sustainable material that can cater removal pollutants. Biochar derived from biowaste is candidate existing problem pollution. review focuses on various aspects biochar, such its sources, preparation methods, mechanism, applications treatment, regeneration. Compared with other adsorbents, biochar considered an environmentally friendly, sustainable, cost-effective substitute waste management, climate protection, soil improvement, etc. special properties porosity, surface area, charge, functional groups be easily modified by chemical resulting in improved adsorption properties. Therefore, view increasing pollution problems encountered researchers treating pollutants, great importance. This also highlights challenges prospective areas explored studied more detail future.

Language: Английский

Citations

98

Advanced Polymeric Nanocomposite Membranes for Water and Wastewater Treatment: A Comprehensive Review DOI Open Access
Abhispa Sahu, Raghav Dosi, Carly O. Kwiatkowski

et al.

Polymers, Journal Year: 2023, Volume and Issue: 15(3), P. 540 - 540

Published: Jan. 20, 2023

Nanomaterials have been extensively used in polymer nanocomposite membranes due to the inclusion of unique features that enhance water and wastewater treatment performance. Compared pristine membranes, incorporation nanomodifiers not only improves membrane performance (water permeability, salt rejection, contaminant removal, selectivity), but also intrinsic properties (hydrophilicity, porosity, antifouling properties, antimicrobial mechanical, thermal, chemical stability) these membranes. This review focuses on applications different types nanomaterials: zero-dimensional (metal/metal oxide nanoparticles), one-dimensional (carbon nanotubes), two-dimensional (graphene associated structures), three-dimensional (zeolites frameworks) nanomaterials combined with polymers towards novel polymeric nanocomposites for applications. will show combinations impart enhanced into membrane; however, underlying issues modification processes environmental impact are less obvious. highlights utility computational methods toward understanding structural functional Here, we highlight fabrication methods, advantages, challenges, impact, future scope advanced based systems

Language: Английский

Citations

58

Green synthesis and characterization of magnetic gamma alumina nanoparticlesfor copper ions adsorption from synthetic wastewater DOI Creative Commons
Ayman K. El‐Sawaf,

Saly R. El-Dakkony,

M.A. Zayed

et al.

Results in Engineering, Journal Year: 2024, Volume and Issue: 22, P. 101971 - 101971

Published: March 12, 2024

Green synthesis of magnetic gamma alumina nanoparticles (MGAl-NPs) for heavy metal adsorption: A novel approach wastewater treatment. This study investigates the potential magnetically modified removing copper (II) ions from aqueous solutions. The MGAl-NPs involves mixture aluminum hydroxide and iron oxide, resulting in a composite material with both adsorptive properties. adsorption capacity was found to be 34.48 mg/g at optimal conditions pH 5.0, initial concentration 50 mg/L, adsorbent dosage 0.1 g.The kinetics followed pseudo-second-order model, indicating that chemisorption dominant mechanism. Langmuir isotherm model best described data an R2 value 0.995, suggesting occurred through monolayer coverage. efficiency increased decreasing pH, confirming electrostatic attraction played significant role adsorption.Our findings demonstrate green is effective eco-friendly method metals wastewater. properties enable easy separation recovery adsorbed metals, making them promising candidate practical applications. provides valuable insights into developing sustainable adsorbents water pollution remediation.

Language: Английский

Citations

43

Synthesis Methods, Properties, and Modifications of Biochar-Based Materials for Wastewater Treatment: A Review DOI Creative Commons

B. Sánchez Díaz,

Alicia E. Sommer-Márquez, Paola E. Ordóñez

et al.

Resources, Journal Year: 2024, Volume and Issue: 13(1), P. 8 - 8

Published: Jan. 5, 2024

The global impact of water and soil contamination has become a serious issue that affects the world all living beings. In this sense, multiple treatment alternatives have been developed at different scales to improve quality. Among them, biochar suitable alternative for environmental remediation due its high efficiency low cost, raw material used production comes from residual biomass. A is carbonaceous with interesting physicochemical properties (e.g., surface area, porosity, functional groups), which can be prepared by synthesis methods using agricultural wastes (branches banana rachis, cocoa shells, cane bagasse, among others) as feedstock. This state-of-the-art review based on general description remediation. Biochar’s production, synthesis, uses also analyzed. addition, work shows some thus several applications, like removing heavy metals, oil, dyes, other toxic pollutants. Physical chemical modifications, precursors, dopants, promoting agents Fe N species) discussed. Finally, primary corresponding mechanism quality (via adsorption, heterogeneous photocatalysis, advanced oxidation processes) described, both laboratory medium large scales. Considering advantages, methods, promising potential mitigate problems improving quality, reducing greenhouse gas emissions, circular economy through biomass, generating value-added products uses.

Language: Английский

Citations

34

Exploring zeolite-based composites in adsorption and photocatalysis for toxic wastewater treatment: Preparation, mechanisms, and future perspectives DOI

Iqra Liaquat,

Ruba Munir, Naseer Ahmed Abbasi

et al.

Environmental Pollution, Journal Year: 2024, Volume and Issue: 349, P. 123922 - 123922

Published: April 3, 2024

Language: Английский

Citations

32

A comprehensive review of nanomaterials for efficient heavy metal ions removal in water treatment DOI
Nur Azalina Suzianti Feisal, Noor Haziqah Kamaludin, Mohd Azwan Ahmad

et al.

Journal of Water Process Engineering, Journal Year: 2024, Volume and Issue: 64, P. 105566 - 105566

Published: June 7, 2024

Language: Английский

Citations

18

Synthesis, characterization and application of Zeolite/Bi2O3 nanocomposite in removal of Rhodamine B dye from wastewater DOI Creative Commons
William George,

Pachris Muamba Kapanga,

Muhammad Ntale

et al.

Cleaner Water, Journal Year: 2024, Volume and Issue: 1, P. 100004 - 100004

Published: Jan. 26, 2024

Many factories use a variety of colours to enhance product aesthetics, leading untreated wastewater being discharged into natural water bodies. This not only poses threat aquatic life but also endangers human health, causing issues like skin diseases, as some dyes are carcinogenic. Rhodamine B dye (RhB) is commonly used in industries such textiles, paper, etc. study focuses on synthesizing, characterizing, and applying Zeolite/Bi2O3 nanocomposites efficiently remove RhB dye. Nanocomposites were synthesized using the sol-gel method characterized techniques including FTIR, SEM-EDS, XRD, DLS, point zero charge determination, surface resonance analysis. The removal process an aqueous solution achieved its maximum efficiency 100% under following optimal conditions: initial concentration (0.5 mg/L), time (10 min), adsorbent dose (0.55 g), pH (4), temperature (298 K). Real testing confirmed nanocomposite's efficiency, removing significant 98.12% Reusability tests showed stability, with efficiencies 100%, 97.08%, 88.9% over three cycles. Isotherm analysis adhered Freundlich Model (R2 = 0.9953), signifying favourable adsorption behaviour. Kinetic supported pseudo-second-order model, indicating chemisorption mechanism. Thermodynamic suggested spontaneous (negative ΔG°) endothermic (positive ΔH°) adsorption, reduced randomness ΔS°) at solid-liquid interface. In conclusion, removal, especially B, vital for environmental public health protection. nanocomposite emerges efficient, sustainable, eco-friendly both synthetic solutions real wastewater.

Language: Английский

Citations

17

2D MXenes and their composites; design, synthesis, and environmental sensing applications DOI
Naseer Ahmad, Sufian Rasheed,

Abrar Mohyuddin

et al.

Chemosphere, Journal Year: 2024, Volume and Issue: 352, P. 141280 - 141280

Published: Jan. 24, 2024

Language: Английский

Citations

16

Molecular Simulation and ANN modelling for Cadmium (Cd) and Lead (Pb) Adsorption from Water using Zeolites DOI Creative Commons
Noor e Hira, Serene Sow Mun Lock, Lam Ghai Lim

et al.

Results in Engineering, Journal Year: 2025, Volume and Issue: unknown, P. 104517 - 104517

Published: Feb. 1, 2025

Language: Английский

Citations

2

Ion Exchange in Natural Clinoptilolite: Aspects Related to Its Structure and Applications DOI Open Access
Inocente Rodrı́guez-Iznaga, Marina G. Shelyapina, Vitalii Petranovskii

et al.

Minerals, Journal Year: 2022, Volume and Issue: 12(12), P. 1628 - 1628

Published: Dec. 17, 2022

Clinoptilolite is one of the most common, widespread and abundant zeolites in nature. Its availability, low cost, outstanding ion exchange properties make clinoptilolite an excellent candidate for both direct use various modifications to create new low-cost functional materials sustainable development. Specific applications which already being used include water treatment heavy metal removal, agricultural purposes, storage conversion unwanted gaseous emissions into atmosphere, production catalysts photocatalysts, bioactive materials, a number others. Unlike some other zeolites, difficult synthesize, why publications refer this zeolite its natural form, either directly from deposit or after applying processes mineral improve properties. Among modification methods used, stands out. This review devoted study with two goals: first, as strategic property cation fundamentally necessary; second, way modify it composite predetermined desired

Language: Английский

Citations

39