3D-Printed Acrylated Soybean Oil Scaffolds with Vitrimeric Properties Reinforced by Tellurium-Doped Bioactive Glass DOI Open Access
Matteo Bergoglio,

Matthias Udo Kriehuber,

Bernhard Sölle

et al.

Polymers, Journal Year: 2024, Volume and Issue: 16(24), P. 3614 - 3614

Published: Dec. 23, 2024

In this study, we present novel, vitrimeric and biobased scaffolds that are designed for hard tissue applications, composed of acrylated, epoxidized soybean oil (AESO) reinforced with bioactive glass is Tellurium doped (BG-Te) BG-Te silanized, to tune the mechanical antibacterial properties. The manufacture’s method consisted a DLP 3D-printing method, enabling precise resolution possibility manufacture hollow complex structure. resin formulation was optimized biobased, reactive diluent adjust viscosity an optimal process. in vitro biological evaluation 3D-printed scaffolds, combined BG-Te-Sil, showed sample’s surfaces remained safe hBMSCs’ attachment proliferation. number S. aureus adhered 87% 54% lower than on pristine (control) respectively, eradication microbiofilm aggregates. This work highlights effect polymer matrix doped, manufacturing biocompatible, scaffold used application.

Language: Английский

Molecularly engineered cardanol derived epoxy vitrimers based on dynamic disulfide and dynamic ester exchanges with desirable dynamic response, degradability, and recyclability DOI
Yun Hu,

Shanyuan Tong,

Lihong Hu

et al.

Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 477, P. 147284 - 147284

Published: Nov. 13, 2023

Language: Английский

Citations

31
Epoxy vitrimers: from essence to utility DOI

H. Supriya,

Sandeep Tripathi, Neetika Singh

et al.

International Polymer Processing, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 20, 2025

Abstract Concerns about the effect on environment and non-renewable nature of plastics have sparked a substantial field study towards creation recyclable polymers. Vitrimers are potential class reusable polymers that recently attracted lot interest. Like conventional thermosets in strength, durability, chemical resistance, these materials offer added benefit being at end their useful life. Their structure, which includes dynamic covalent crosslinks to provide stability while enabling reprocessing, is credited with this special characteristic. We lay out an overview recent developments applications epoxy based vitrimeric by using different types adaptable networks (CANs) – single, dual triple paper attention design tactics make it easier create circular future. Covalent Adaptable Networks (CAN), novel polymer family can bridge gap between thermoplastics, emerged years uses chemistry crosslinked networks. The was enhanced 2011 Leibler colleagues when they introduced notion vitrimers, retain integrity network even after heating allow connections be reallocated within them associative exchange reactions. This review also demonstrates how vitrimer community paying need for sustainable material development demonstrating use biobased building blocks synthesis high-performing vitrimers. Having outlined primary characteristics commercialization vitrimers emphasized portray benefits self-healing, malleability, orthogonal processability, various shape memories along solutions synthetic materials.

Language: Английский

Citations

1
Silanized and Cu-doped bioactive glass as filler for biobased photocurable 3D printed scaffolds DOI Creative Commons
Matteo Bergoglio, Ziba Najmi, Andrea Cochis

et al.

Materials Today Chemistry, Journal Year: 2025, Volume and Issue: 44, P. 102559 - 102559

Published: Feb. 8, 2025

Language: Английский

Citations

1
From biomass to vitrimers: Latest developments in the research of lignocellulose, vegetable oil, and naturally-occurring carboxylic acids DOI

Yanfan Yang,

Haibo Liu,

Biying Lin

et al.

Industrial Crops and Products, Journal Year: 2023, Volume and Issue: 206, P. 117690 - 117690

Published: Oct. 28, 2023

Language: Английский

Citations

20
Simultaneous robustness, reprocessing and self-healing of castor oil-based polyurethane vitrimers enabled by supramolecular nitrogen-coordinated dynamic covalent boronic ester DOI

Shihong Ren,

Zhunhan Li,

Wenjuan Zhou

et al.

Industrial Crops and Products, Journal Year: 2023, Volume and Issue: 206, P. 117738 - 117738

Published: Oct. 31, 2023

Language: Английский

Citations

17
Multi-Material 3D Printing of Biobased Epoxy Resins DOI Open Access
Matteo Bergoglio, Elisabeth Rossegger, Sandra Schlögl

et al.

Polymers, Journal Year: 2024, Volume and Issue: 16(11), P. 1510 - 1510

Published: May 27, 2024

Additive manufacturing (AM) has revolutionised the industry, offering versatile capabilities for creating complex geometries directly from a digital design. Among various 3D printing methods polymers, vat photopolymerisation combines photochemistry and printing. Despite fact that single-epoxy been explored, fabrication of multi-material bioderived epoxy thermosets remains unexplored. This study introduces feasibility potential by means dual-vat Digital Light Processing (DLP) technology, focusing on resins such as ELO (epoxidized linseed oil) DGEVA (vanillin alcohol diglycidyl ether). By integrating different materials with mechanical properties into one sample, this approach enhances sustainability offers versatility applications. Through experimental characterisation, including thermal analysis, demonstrates ability to produce structures composed tailored shapes change demand. The findings underscore promising technology DLP applied sustainable monomers, allowing material production structure fabrication.

Language: Английский

Citations

6
Phosphorus acid: an asset for flame-retardant sustainable vitrimers DOI Creative Commons
Florian Cuminet,

Nathan Vanachte,

Chloé Farina

et al.

Polymer Chemistry, Journal Year: 2024, Volume and Issue: 15(12), P. 1212 - 1226

Published: Jan. 1, 2024

Three biobased epoxy resins from vanillic alcohol, linseed oil and cardanol were crosslinked with phosphoric acid to prepare vitrimers.

Language: Английский

Citations

5
Cationic UV-curing of bio-based epoxidized castor oil vitrimers with electrically conductive properties DOI Creative Commons
Matteo Bergoglio,

Gabriele Palazzo,

David Reisinger

et al.

Reactive and Functional Polymers, Journal Year: 2024, Volume and Issue: 200, P. 105936 - 105936

Published: May 5, 2024

The growing appeal of carbon nanotube composites in the contemporary market derives from their exceptional thermal and chemical stability, coupled with electrical conductivity. In this study, we combined these salient features a biobased epoxy matrix having vitrimeric properties, hence being reprocessable resheapable, to obtain conductive coating. Epoxidised castor oil (ECO) was chosen as monomer precursor for straightforward synthesis. synthesis relied on cationic UV-curing process, embedding nanotubes matrix. Photo DSC transmission FTIR analysis were conducted determine final conversion rings photocuring process. Thermo-mechanical properties evaluated by tensile tests, DMTA. Thermal stability assessed TGA. Dielectric spectroscopy confirmed increased conductivity presence increasing CNT content, reaching percolation threshold at 0.5 phr CNTs. Vitrimeric proved stress relaxation experiments, UV-cured composite underwent thermo-activated transesterification reaction starting 70 °C, catalysed dibutyl phosphate. Overall, ECO-CNT showed high resistance (up 400 °C) concentration, properties. study can be, therefore, considered promising point sustainable electrically vitrimers.

Language: Английский

Citations

5
Renewable Photopolymers: Transformation of Biomass Resources into Value-Added Products Under Light DOI
Haiwang Lai, Jing Zhang, Pu Xiao

et al.

ACS Sustainable Chemistry & Engineering, Journal Year: 2023, Volume and Issue: 11(46), P. 16365 - 16406

Published: Nov. 8, 2023

Light-induced cross-linking of liquid monomers has found widespread applications in various fields, such as dentistry, coatings, tissue engineering, and 3D printing. These processes typically rely on derived from petrochemicals, which are volatile price becoming increasingly depleted, compelling researchers to explore alternative sources forestry agricultural crops. The renewability these resources makes them a promising option for developing substitutive materials with similar or superior properties. structural subunits biomass offer building blocks petroleum-based photopolymers including the double bond-containing hydrophobic fatty acids terpenes, hydrophilic carbohydrates proteins, aromatic furfural compounds carbohydrates, phenolic moieties lignin. They can be transformed into by inherent chemically introduced photocurable bonds. This review seeks highlight recent advancements transforming renewable platform chemicals systems photopolymerization examines thermomechanical properties resulting cured materials. Furthermore, potential issues improvement also identified, cost-effectiveness biomass-based risk competition food production. perspectives future directions improving this area given.

Language: Английский

Citations

11
Biobased Vitrimeric Epoxy Networks DOI Creative Commons
Marco Sangermano, Matteo Bergoglio,

Sandra Schögl

et al.

Macromolecular Materials and Engineering, Journal Year: 2023, Volume and Issue: 309(9)

Published: Dec. 24, 2023

Abstract The scientific strategies reported in the literature for developing biobased epoxy vitrimers are summarized. Biomass resources such as lignin, cellulose, or different vegetable oils can be exploited building blocks thermosets an alternative to bisphenol‐A‐based ones. Biorenewable have been synthesized introducing dynamic covalent bonds cross‐linked networks. This combination allows achieve networks with thermoset‐like properties at a temperature of use, but showing (re)processability, recyclability, and self‐healing above well‐defined named topology freezing transition ( T v ).

Language: Английский

Citations

11