Polypropylene Microplastic Photo- and Thermo-Activated Degradation by Iron-Containing Minerals: A Route to Self-Remediation Learnt from the Environment DOI
Valter Castelvetro, Andrea Corti, Enrico Mugnaioli

et al.

Published: Jan. 1, 2023

The detection of significantly different concentrations polyolefin microplastics (MPs) in two nearby marine sandy beaches northern Tuscany, Italy, prompted the present investigation on possible role matrix accelerating polymer degradation, already occurring as a result photo-oxidation. polypropylene (PP) and polyethylene (PE) MPs sand sediments was based P.I.S.A. (Polymer Identification Specific Analysis) procedure, allowing determination total mass all particles below given threshold (here 2 mm, set by preliminary sieving sampled beach sand). cause for much lower concentration one (Lecciona, within natural park stretching along coast) successfully correlated with peculiar composition, characterized relatively high content iron-containing minerals such magnetite ferrous serpentine (a hydrous magnesium iron phyllosilicate). accelerated photo-oxidative degradation PP, measured model virgin after both UV Xe lamp irradiation (the latter simulating solar light). Similarly, showed catalytic effect thermal (at T=60 °C) environmentally aged PP kept dark during treatment. These results clearly indicate that environment may possess, under appropriate conditions presence which are dispersed, combined intensive sun exposure), effective self-cleaning ability, thus better than expected resilience to ever increasing pollution so-called plastisphere.

Language: Английский

Synergistic degradation of polystyrene nanoplastics in water: Harnessing solar and water-driven energy through a Z-scheme SnO2/g-C3N4/PVDF-HFP piezo-photocatalytic system DOI Creative Commons
Arezou Fazli,

Simone Lauciello,

Rosaria Brescia

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: 353, P. 124056 - 124056

Published: April 18, 2024

The rise of nanoplastics (NPs) as a water pollutant poses threats to aquatic ecosystems and human health. This study presents an approach that combines solar water-driven energy sources with advanced materials degrade NPs. For this purpose, SnO2/g-C3N4/PVDF-HFP piezo-photocatalyst has been developed. SnO2/g-C3N4 photocatalyst Z-Scheme charge transfer demonstrates high activity under simulated light. Simultaneously, ultrasound waves, employed mimic motion, serve activate the piezoelectric properties g-C3N4, thereby enhancing separation. Moreover, immobilization onto poly (vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) nanofiber mats augments its piezocatalytic efficiency prevents dispersion in reaction media. During piezo-photocatalytic process, generated reactive species attack polystyrene (PS) NPs introduce oxygen-based functional groups. leads surface corrosion, fragmentation, 46 % mineralization just 15 h mild conditions, outperforming existing literature. Overall, research emphasizes importance harnessing renewable for NP remediation.

Language: Английский

Citations

10

Nanomaterials for the Catalytic Degradation and Detection of Microplastics: A Review DOI
Muhammad Shahzeb Khan, Muhammad Ibrar Asif, Muhammad Asif

et al.

Topics in Catalysis, Journal Year: 2024, Volume and Issue: unknown

Published: April 20, 2024

Language: Английский

Citations

9

Layered Double Hydroxide-Based Photocatalysts for the Removal of Emerging Contaminants: Progress in Past Ten Years DOI Open Access
Lingfeng Luo,

Chen Hou,

Lan Wang

et al.

Catalysts, Journal Year: 2024, Volume and Issue: 14(4), P. 252 - 252

Published: April 11, 2024

Currently, public health is seriously threatened by the massive concentrations of emerging contaminants. Treating contaminants in water using effective methods has become a major challenge worldwide. Photocatalytic technology, as an eco-friendly been recognized means removing from water. Among various photocatalysts, layered double hydroxides (LDHs), known hydrotalcite-like materials, have explored extensively photocatalytic reactions due to their switchable properties and large surface areas unique two-dimensional structures. In this article, recent advances degradation LDH-based photocatalysts are reviewed. Firstly, fundamental principles materials briefly introduced. Various LDHs applied broadly summarized into four types: pure-phase LDHs, interlayer-modified composites, oxides (LDOs). Moreover, synthesis process catalytic mechanism also An outlook on problems future development remediation provided at end.

Language: Английский

Citations

6

A review of methods for mitigating microplastic contamination in biosolids from wastewater treatment plants before agricultural soil application DOI Creative Commons

Sadique Anyame Bawa,

K. L. Andrew Chan, Anna Wrobel-Tobiszewska

et al.

The Science of The Total Environment, Journal Year: 2024, Volume and Issue: 957, P. 177360 - 177360

Published: Nov. 16, 2024

Wastewater treatment plants (WWTP) are recognized as major sources of microplastic (MP) particles in terrestrial environments, particularly agricultural soils through biosolids application. While many reviews have focused on the distribution, detection, and mitigation MPs wastewater effluent to limit their discharge into oceans, our understanding methods mitigate biosolid contamination remains limited. This review focuses for mitigating at various intervention points, including sources, WWTP primary secondary stages where sludge is generated, post-contamination. These categorized physical, physicochemical, biological approaches, advantages limitations discussed. For instance, physicochemical methods, especially froth flotation, cost-effective but hindered by contaminants reagents. Physical like microfibre filtration devices (MFD) safe efficiency depends filter pore size design. Biological microbial degradation, limited varying efficiencies microorganisms breaking down extended time required effective degradation. Other physical dissolved air ultrasonication already exist WWTPs may require retrofitting or optimization enhance MP removal from biosolids. As each method inherently has limitations, key achieving MP-free biosolids, thus preventing release soil, lies integrating these multi-coupling strategies.

Language: Английский

Citations

5

Green synthesis of Bio-CuS quantum dots by sulfate reducing bacteria for solid-phase photocatalytic degradation of polyethylene film DOI

Jian Cheng,

Xu Wang,

Gongchu Shi

et al.

Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 354, P. 129374 - 129374

Published: Aug. 25, 2024

Language: Английский

Citations

4

Solar thermoplasmonic convection for sustainable removal of microplastics DOI

Suqin Zhang,

Qingyuan Liu, Ting Chen

et al.

Solar Energy Materials and Solar Cells, Journal Year: 2025, Volume and Issue: 282, P. 113416 - 113416

Published: Jan. 11, 2025

Language: Английский

Citations

0

Microplastics in the Environment: A Review Linking Pathways to Sustainable Separation Techniques DOI Creative Commons

Lin Zeng,

Long Tu Li,

Jueyan Xiao

et al.

Separations, Journal Year: 2025, Volume and Issue: 12(4), P. 82 - 82

Published: March 30, 2025

Since the mid-20th century, quantity of microplastics (MPs) has increased significantly, becoming a persistent environmental pollutant widely distributed in global water bodies, soils, and atmosphere. While plastic materials have brought significant convenience to daily life, MPs resulting from their degradation pose increasing threats ecosystems human health. This comprehensive review examines sources, migration pathways, ecological impacts MPs, critically evaluates current separation techniques physical, chemical, biological perspectives. In particular, numerical simulations hydrocyclone technique reveal its unique flow characteristics, including turbulent velocity gradients axial pressure differences, with efficiency up 93%. offers advantages such as high efficiency, low energy consumption, friendliness. response growing microplastic pollution issue, this emphasizes that development future should prioritize sustainability, compatibility. Continued research field will provide theoretical support for optimizing control technologies contribute achieving protection sustainable goals.

Language: Английский

Citations

0

Advancing photocatalytic strategies for microplastic degradation in aquatic systems: Insights into key challenges and future pathways DOI Creative Commons

Karina J. Ramírez-Escárcega,

Karla J. Amaya-Galván,

Juan C. García-Prieto

et al.

Journal of environmental chemical engineering, Journal Year: 2025, Volume and Issue: unknown, P. 115594 - 115594

Published: Jan. 1, 2025

Language: Английский

Citations

0

Light-driven degradation of microplastics: mechanisms, technologies, and future directions DOI Creative Commons
Yao Wu, Ran Yi,

Yankun Wang

et al.

Journal of Hazardous Materials Advances, Journal Year: 2025, Volume and Issue: 17, P. 100628 - 100628

Published: Feb. 1, 2025

Language: Английский

Citations

0

Sustainable strategies for microplastic waste management: utilizing nickel oxide nanoparticles as photocatalysts DOI

Jameel Mohammed Musthafa,

Badal Kumar Mandal

Journal of Polymer Research, Journal Year: 2025, Volume and Issue: 32(3)

Published: Feb. 20, 2025

Language: Английский

Citations

0