Development of an Antimicrobial Inorganic Polymer Based on Fly Ash and Metakaolin Incorporated by Nano-TiO 2 for Reactive Dye Removal DOI Creative Commons
Doaa Ahmed, Morsy Ahmed El‐Apasery,

Shereen Ragai

et al.

Research Square (Research Square), Journal Year: 2023, Volume and Issue: unknown

Published: Oct. 12, 2023

Abstract Advanced and eco-friendly construction materials are being developed to reduce pollution improve wastewater treatment efficiency. One such material is a photocatalytic nanocomposite that uses industrial wastes natural substances eliminate pollution. A recent study explored using an inorganic polymer composite (FM) made from mixture of 70% fly ash 30% metakaolin, with sodium hydroxide silicate as alkali activator. The evaluated the mechanical hydration characteristics FM after 28 days in 100% humidity at room temperature. also examined effect adding 2.5 wt.% Nano-TiO 2 how it affects its properties. Results indicate enhances mechanical, antibacterial, capabilities. Specifically, FM-TiO showed 90% removal reactive blue 19 dye effluent sunlight 90 minutes, making excellent choice for sustainable treatment. This presents cost-effective, solution treatment, added antimicrobial properties .

Language: Английский

Sustainable geopolymers from polyethylene terephthalate waste and industrial by-products: a comprehensive characterisation and performance predictions DOI Creative Commons
Md. Zia ul Haq, Hemant Sood, Rajesh Kumar

et al.

Journal of Materials Science, Journal Year: 2024, Volume and Issue: 59(9), P. 3858 - 3889

Published: Feb. 26, 2024

Abstract Several researchers have recently worked to create sustainable building materials. One of the fundamental prerequisites for construction methods and environmental impact assessments is use green materials manufacturing processes. In this research study, geopolymer bricks were developed using polyethylene terephthalate waste different industrial by-products (rice husk ash, ground granulated blast furnace slag, red mud, construction, demolition waste) investigated their performances. The was used as a replacement sand filler in brick up 100%. Key findings include workability decrease 14.75% compressive strength reduction 75% with 100% plastic replacement, attributed increased voids weak matrix interaction. Dry density consistently decreases, water absorption rises 13.73% full indicating porous structure. Impact resistance improves inclusion, enhancing ductility thermal conductivity by 57% at replacement. Microstructural analyses reveal correlations between physical–mechanical properties changes porosity, microcracks, bond strength. Machine learning, especially linear regression, proves effective parameter prediction (up efficacy, R-square 0.998). promising results obtained could offer substantial environmentally friendly solution industry line Circular Economy principles.

Language: Английский

Citations

19

A review on metakaolin-based porous geopolymers DOI
Chengying Bai,

Kankan Zheng,

Sun Feng

et al.

Applied Clay Science, Journal Year: 2024, Volume and Issue: 258, P. 107490 - 107490

Published: July 19, 2024

Language: Английский

Citations

14

Development of moringa seed powder-modified slag geopolymers for enhanced mechanical properties and effective dye removal DOI Creative Commons

soher hashish,

Essam Kishar,

Doaa Ahmed

et al.

Scientific Reports, Journal Year: 2025, Volume and Issue: 15(1)

Published: March 15, 2025

Abstract Crystal violet (CV), a widely used dye in paints and textiles, poses significant environmental threat due to its non-biodegradable nature. A modified slag-based geopolymer has been developed address this issue by incorporating raw moringa seed powder (MSP), an agricultural waste. The geopolymers (SM1, SM2, SM3) were created adding different percentages of MSP (0.2%, 0.6%, 1% weight) ground granulated blast furnace slag (GGBFS), using sodium silicate 10 M hydroxide as alkali activators. This combination enhances the geopolymer’s mechanical adsorbent properties, making it more effective for CV removal. composites analyzed X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM). Their properties evaluated conducting compressive strength total porosity tests. Pore structure analysis was performed nitrogen adsorption desorption techniques, point zero charges determined. Additionally, batch experiments carried out investigate dye, employing two isotherm models kinetic analysis. SM1 mix, which is containing 0.2% MSP, exhibited highest at 73 MPa after 180 days, representing 25.8% improvement compared control mix (100% slag). Furthermore, mixes showed greater activity toward crystal with SM3 achieving capacity up 322.58 mg/g. study demonstrates that capacity. indicates positive impact on composite’s surface highlights benefits utilizing industrial waste wastewater treatment.

Language: Английский

Citations

1

Olive Pomace Fly Ash as an Alternative Alkaline Activator for Electric Arc Furnace Slag for Sustainable Cementitious Materials DOI Open Access

A. Muñoz-Castillo,

Francisca Andrés-Castro,

M.A. Gómez-Casero

et al.

Materials, Journal Year: 2025, Volume and Issue: 18(3), P. 601 - 601

Published: Jan. 28, 2025

This study analyzes the potential of olive pomace fly ash (OPFA) as an alternative alkaline activator for electric arc furnace slag (EAFS) in manufacture sustainable cementitious materials. Cements were prepared by replacing 30–50 wt% EAFS with OPFA and compared control cements activated potassium hydroxide (KOH) at concentrations 4 8 M. characterized bulk density, water absorption, total porosity, compressive flexural strength, well analytical techniques such XRD, FTIR SEM-EDS. The results reveal that incorporation 40 provides optimum properties, reaching maximum strengths 20.0 MPa 5.7 MPa, respectively, after 28 days curing. These improvements are attributed to increased formation C,K-A-S-H gel, which incorporates Fe, main reaction product densifies matrix reduces porosity. However, 30 insufficient alkali content, limits reaction, while excess 50 mechanical performance due unreacted residues interconnected Compared KOH-activated cements, achieve 4.4 9.5 (EAFS/KOH-8M binders), confirm activator, significant sustainability advantages.

Language: Английский

Citations

0

Development of Polymer Composites Using Recycled Polymer Waste of Textile Industry: A Review DOI
Bhabatosh Biswas, Ankush Sharma, Partha Bairi

et al.

Springer Proceedings in Materials, Journal Year: 2025, Volume and Issue: unknown, P. 75 - 90

Published: Jan. 1, 2025

Language: Английский

Citations

0

Synthesis of Electrolytic Manganese Slag–Solid Waste-Based Geopolymers: Compressive Strength and Mn Immobilization DOI Creative Commons
Bao Xiu Mi, Hui Zhao,

Meng Lu

et al.

Materials, Journal Year: 2024, Volume and Issue: 17(6), P. 1431 - 1431

Published: March 21, 2024

The massive stockpiling of electrolytic manganese residue (EMR) has caused serious environmental pollution. In this study, EMR, coal gangue (CG), and fly ash (FA) were used as raw materials to obtain the optimal mix ratio based on Design-Expert mixture design. effects activator modulus, liquid–solid (L/S) ratio, curing temperature mechanical properties geopolymers investigated. results showed that compressive strength prepared geopolymer was 12.0 MPa, 28d leaching Mn 0.123 mg/L under conditions EMR:CG:FA = 0.43:0.34:0.23, L/S 0.9, a 60 °C, time 24 h. This indicates is an environmentally friendly material with high strength. mineral composition mainly hydrated calcium silicate gel. addition, more stable new phase, MnSiO3, generated. Fourier transform infrared (FTIR) spectrogram peak at 1100 m−1 shifted 1112 cm−1, which indicated geopolymerization reaction had occurred. Through scanning electron microscopy (SEM) energy dispersive spectrum (EDS) analysis, it identified produced large amount amorphous gelatinous substances relatively dense structure, major elements being oxygen, silicon, aluminum, calcium, sodium.

Language: Английский

Citations

3

Determination of Radium concentration and Radon Exhalation Rates Using CR-39 Detector for Different Geopolymer Cement Samples Containing Industrial Wastes DOI

M.Y. Shoeib,

Morsy Ahmed El‐Apasery, Doaa Ahmed

et al.

Radiation Physics and Chemistry, Journal Year: 2024, Volume and Issue: 222, P. 111790 - 111790

Published: April 25, 2024

Language: Английский

Citations

2

Utilization of peanut shell: investigating the adsorption mechanism and optimization of red 195 and reactive black-5 DOI
Hakan Çelebi,

T. Bahadir,

Şevket Tulun

et al.

International Journal of Environmental Science and Technology, Journal Year: 2024, Volume and Issue: unknown

Published: April 29, 2024

Language: Английский

Citations

2

Development of an eco-friendly geopolymer mortar using slag and fly ash with high bentonite content for thermal and environmental applications DOI Creative Commons

Aya allah M. Ebrahim,

Doaa Ahmed,

Reham Abu-Elwafa

et al.

Scientific Reports, Journal Year: 2024, Volume and Issue: 14(1)

Published: Nov. 5, 2024

Abstract The construction industry is exploring the use of low-cost waste materials to create eco-friendly geopolymer mortar binders. Our study aims develop various environmentally friendly mixes for thermal and adsorption applications using natural like bentonite industrial by-products such as ground-granulated blast furnace slag fly ash. Ternary pastes are prepared equimolar amounts (GBFS) ash (FA), with 6%, 8%, 10%, 12% weight (BC) from total replacement effect. tested their physico-chemical, mechanical, adsorption, stability properties (300 °C 900 °C). behavior against crystal violet dye in aqueous solutions also identified. found that adding 6% slag/fly ash-based mix yielded highest mechanical characteristics. Moreover, all ternary exhibited excellent up °C. In study, results indicated had capacities adhered well Freundlich isotherm model, suggesting potential treating wastewater. Using offers a sustainable, cost-effective, heat-resistant alternative traditional cement

Language: Английский

Citations

2

Development of an antimicrobial inorganic polymer based on fly ash and metakaolin incorporated by nano-TiO2 for reactive dye removal DOI Creative Commons
Doaa Ahmed, Morsy Ahmed El‐Apasery,

Shereen Ragai

et al.

Scientific Reports, Journal Year: 2023, Volume and Issue: 13(1)

Published: Nov. 14, 2023

Advanced and eco-friendly construction materials are being developed to reduce pollution improve wastewater treatment efficiency. One such material is a photocatalytic nanocomposite that uses industrial wastes natural substances eliminate pollution. A recent study explored using an inorganic polymer composite (FM) made from mixture of 70% fly ash 30% metakaolin, with sodium hydroxide silicate as alkali activator. The evaluated the mechanical hydration characteristics FM after 28 days in 100% humidity at room temperature. also examined effect adding 2.5 wt.% Nano-TiO2 how it affects its properties. Results indicate enhances mechanical, antibacterial, capabilities. Specifically, FM-TiO2 showed 90% removal reactive blue 19 dye effluent sunlight 90 min, making excellent choice for sustainable treatment. This presents cost-effective, solution treatment, added antimicrobial properties Nano-TiO2.

Language: Английский

Citations

5