Pyrazole-based photoinitiator with antibacterial activity DOI Creative Commons

Melda Altıkatoğlu Yapaöz,

Sevnur Keskin Doğruyol

Polimery, Journal Year: 2024, Volume and Issue: 69(3), P. 167 - 172

Published: April 16, 2024

1-(naphthalen-2-yl)-2-(1H-pyrazol-1-yl) ethanone (MPPY) was synthesized. The structure characterized by spectral analysis (1H-NMR, FTIR). molar absorptivity of MPPY is high enough, similarly to acetonaphthone derivatives, be used as an efficient type I photoinitiator. influence concentration and the addition co-initiator N-methyldiethanolamine (MDEA) on methyl methacrylate (MMA) polymerization were also investigated. Additionally, showed good antibacterialactivity against Escherichia coli Staphylococcus aureus (diffusion method).

Language: Английский

Coumarin based glyoxylate photoinitiators for free radical and cationic Photopolymerizations with UV-Visible LED irradiation DOI
Xun Sun, Xianglong He, Mei Yi

et al.

European Polymer Journal, Journal Year: 2024, Volume and Issue: 211, P. 113025 - 113025

Published: April 6, 2024

Language: Английский

Citations

7
A Multicomponent Visible-Light Initiating System for Rapid and Deep Photocuring through UV-Opaque Polyimide Films DOI

Daihyun Hwang,

Woojin Jeon,

Seokju Lee

et al.

ACS Applied Polymer Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 5, 2025

Language: Английский

Citations

1
Recent Advances in Monocomponent Visible Light Photoinitiating Systems Based on Sulfonium Salts DOI Open Access
Frédéric Dumur

Polymers, Journal Year: 2023, Volume and Issue: 15(21), P. 4202 - 4202

Published: Oct. 24, 2023

During the last decades, multicomponent photoinitiating systems have been focus of intense research efforts, especially for design visible light systems. Although highly reactive three-component and even four-component designed, complexity to elaborate such mixtures has incited researchers monocomponent Type II photoinitiators. Using this approach, photosensitizer radical/cation generator can be combined within a unique molecule, greatly simplifying elaboration photocurable resins. In field, sulfonium salts are remarkable photoinitiators but these structures lack absorption in range. Over years, various structural modifications carried out order redshift their absorptions region. work, an overview different activable under reported date is proposed.

Language: Английский

Citations

9
Recent advances on naphthoquinone-imidazolyl and naphthoquinone-thiazolyl derivatives as photoinitiators of photopolymerization DOI
Frédéric Dumur

European Polymer Journal, Journal Year: 2024, Volume and Issue: 219, P. 113401 - 113401

Published: Aug. 27, 2024

Language: Английский

Citations

3
Visible to near-infrared light activated photoacids: Molecular architecture for chemical and biological applications DOI

Jiayang Jiang,

Zihan Xu, Tang Li

et al.

Journal of Organometallic Chemistry, Journal Year: 2025, Volume and Issue: 1027, P. 123525 - 123525

Published: Jan. 18, 2025

Language: Английский

Citations

0
Novel sulfonylimide photo-acid generators for deep ultraviolet photoresist with improved acid diffusion inhibition performance through retarding the anion diffusion DOI
Guangju Liu, Na Li, Xiang Gao

et al.

Journal of Photochemistry and Photobiology A Chemistry, Journal Year: 2025, Volume and Issue: unknown, P. 116279 - 116279

Published: Jan. 1, 2025

Language: Английский

Citations

0
Bicyclic Sulfonium Pincer Ligand with a Thiatriptycenium Backbone - Synthesis and Applications in π-Acid Catalysis DOI Creative Commons
Mohammad Zafar,

Donia Shamali,

Nitsan Barel

et al.

Chemical Communications, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

A bicyclic PSP-pincer sulfonium ligand with a triptycene-like scaffold was synthesized and coordinated to bis-cationic Pt( ii ) center The resulting photostable tris-cationic complex demonstrated an excellent performance as π-acid catalyst.

Language: Английский

Citations

0
Cationic ligands – from monodentate to pincer systems DOI
Mohammad Zafar, Vasudevan Subramaniyan,

Françoise Tibika

et al.

Chemical Communications, Journal Year: 2024, Volume and Issue: 60(73), P. 9871 - 9906

Published: Jan. 1, 2024

For a long time, the small group of cationic ligands stood out as obscure systems within general landscape coordinative chemistry. However, this situation has started to change rapidly during last decade, with more and examples metal-coordinated species being reported. The growing interest in these is not only purely academic nature, but also driven by accumulating evidence their high catalytic utility. Overcoming inherently poor coordinating ability often required additional structural stabilization. In numerous cases was realized functionalizing them pair chelating side-arms, effectively constructing pincer-type scaffold. This comprehensive review aims encompass all possessing such pincer architecture reported date. Herein every that ever been embedded framework described terms its electronic structure, followed an in-depth discussion donor/acceptor properties, based on computational studies (DFT) available experimental data (IR, NMR or CV). We then elaborate how positive charge affects spectroscopic redox well reactivity, complexes, compared those structurally related neutral ligands. Among other discussed, surveys our own contribution field, namely, introduction sulfonium-based recently group.

Language: Английский

Citations

2
Pyrazole-based photoinitiator with antibacterial activity DOI Creative Commons

Melda Altıkatoğlu Yapaöz,

Sevnur Keskin Doğruyol

Polimery, Journal Year: 2024, Volume and Issue: 69(3), P. 167 - 172

Published: April 16, 2024

1-(naphthalen-2-yl)-2-(1H-pyrazol-1-yl) ethanone (MPPY) was synthesized. The structure characterized by spectral analysis (1H-NMR, FTIR). molar absorptivity of MPPY is high enough, similarly to acetonaphthone derivatives, be used as an efficient type I photoinitiator. influence concentration and the addition co-initiator N-methyldiethanolamine (MDEA) on methyl methacrylate (MMA) polymerization were also investigated. Additionally, showed good antibacterialactivity against Escherichia coli Staphylococcus aureus (diffusion method).

Language: Английский

Citations

0