Journal of Applied Polymer Science,
Journal Year:
2024,
Volume and Issue:
141(43)
Published: Aug. 17, 2024
Abstract
A
CO
2
‐based
thermoplastic
elastomer,
poly(propylene
carbonate)‐multiblock‐polyamide6
(PPC‐
mb
‐PA6)
copolymer,
was
constructed
through
coupling
amorphous/soft
PPC
blocks
with
crystalline/hard
PA6
blocks.
The
PPC‐
‐PA6
copolymers
different
block
length
pairs
were
designed
and
synthesized,
then
fully
characterized
by
structural,
thermal,
mechanical
analysis.
proton
nuclear
magnetic
resonance
(
1
H‐NMR),
diffusion
ordered
spectroscopy
(DOSY),
heteronuclear
multiple‐bond
correlation
(HMBC)
gel
permeation
chromatography
(GPC)
results
confirm
that
the
multiblock
sequence
structure
of
‐PA6.
differential
scanning
calorimetry
(DSC)
tests
show
all
PPC‐mb‐PA6s
possess
melting
points
around
179–206°C.
thermal
analysis
indicates
improved
service
temperatures
T
5%
up
to
270°C)
tensile
strength
ranging
from
15.8
39.6
MPa
higher
content.
dynamic
demonstrates
excellent
shape
memory
effect
stimuli
responsiveness
derived
micro
phase
separation
between
soft
hard
domains.
And
characteristic
strain
fixity
parameter
R
f
)
deformation
recovery
rate
r
are
98%
100%,
respectively,
which
comparable
other
polymers.
Polymers,
Journal Year:
2025,
Volume and Issue:
17(2), P. 145 - 145
Published: Jan. 9, 2025
Despite
the
impressive
properties
of
additively
manufactured
products,
their
inherent
anisotropy
is
a
crucial
challenge
for
polymeric
parts
made
via
fused
filament
fabrication
(FFF).
This
study
compared
tensile,
thermophysical,
smoke
density,
and
toxicity
characteristics
Ultem
9085
(a
blend
polyetherimide
polycarbonate)
samples
printed
in
various
orientations
(X,
Y,
Z).
The
results
revealed
that
mechanical
properties,
such
as
elastic
modulus
tensile
strength,
significantly
differed
from
Z
printing
orientation,
particularly
X
Y
layer
orientations.
Thermomechanical
analysis
had
high
anisotropic
effects
coefficient
thermal
expansion,
indicating
superior
along
orientation.
density
test
proved
complies
with
aviation
safety
standards.
Smoke
tests
showed
all
samples,
regardless
print
orientation
or
thickness,
stayed
well
below
regulatory
limit,
making
them
suitable
aircraft
interiors.
Polymers,
Journal Year:
2025,
Volume and Issue:
17(3), P. 299 - 299
Published: Jan. 23, 2025
Joining
materials
with
different
physicochemical
properties
presents
significant
challenges.
This
study
investigates
the
one-step
anodization
of
aluminum
in
a
mixed
phosphoric
acid
and
hydrogen
peroxide
solution,
followed
by
direct
injection
molding
polymer
resin
to
enhance
joint
properties.
The
anodizing
treatment
is
performed
at
constant
electrical
current
solutions
various
concentrations.
Phosphoric
enables
formation
3D
channeling
pore
structure
micropits
uniform
nanopores
on
surface.
Hydrogen
acts
as
an
oxidizing
agent
promotes
dissolution
reaction,
thereby
increasing
size
nanopores.
Larger
pores
facilitated
penetration
into
oxide
layer
during
molding,
resulting
bonding
strengths
up
40.34
MPa.
improvement
substantial
when
compared
achieved
through
conventional
processes.
These
results
highlight
that
increase
nanopore
due
addition
played
critical
role
enhancing
strength,
it
better
interlocking
within
anodized
layer.
Furthermore,
three-dimensional
(3D)
printing
process
was
able
join
resins
surface,
where
larger
more
beneficial
than
is.
alternative
approach
addresses
environmental
issues
associated
use
Cr(VI)-based
lightweight
composites
applicability
industries
could
be
produced
using
this
method.
Macromolecules,
Journal Year:
2024,
Volume and Issue:
57(15), P. 7315 - 7330
Published: July 31, 2024
This
study
investigates
the
influence
of
a
ethylene-glycidyl
methacrylate
copolymer
(EGMA)
on
shape
memory
effect
(SME)
and
impact
resistance
PETG/EGMA
thermoplastic
vulcanizates
(TPVs).
The
TPVs
were
prepared
by
dynamic
vulcanization
through
simple
melt
blending
polymers
without
need
for
curing
agents
such
as
DCP
or
sulfur.
Simultaneously,
in
situ
reactive
compatibilization
was
achieved
solely,
any
compatibilizer.
SME,
mechanical,
thermomechanical,
rheological,
chemical,
morphological
properties
characterized.
Surprisingly,
(80/20)
blend
exhibited
an
strength
835.9
J/m,
which
is
15
times
higher
than
that
neat
PETG
(53.5
J/m).
Increasing
EGMA
concentration
significantly
improved
effect.
(50/50)
demonstrated
excellent
recovery
(Rr)
84.2%,
approximately
2.5
(33.4%),
with
fixity
(Rf)
100%.
approach
presented
this
work
offers
practical,
simple,
low-cost
obtaining
high
effect,
opening
up
possibilities
application
material
various
fields.
Buildings,
Journal Year:
2024,
Volume and Issue:
14(8), P. 2345 - 2345
Published: July 29, 2024
Civil
infrastructures
are
constantly
exposed
to
environmental
effects
that
can
contribute
deterioration.
Early
detection
of
damage
is
crucial
prevent
catastrophic
failures.
Structural
Health
Monitoring
(SHM)
systems
essential
for
ensuring
the
safety
and
reliability
structures
by
continuously
monitoring
recording
data
identify
damage-induced
changes.
In
this
context,
self-sensing
composites,
formed
incorporating
conductive
nanomaterials
into
a
matrix,
offer
intrinsic
sensing
capabilities
through
piezoresistivity
various
conduction
mechanisms.
The
paper
reviews
how
SHM
with
materials
be
applied
civil
infrastructure
while
also
highlighting
important
research
articles
in
field.
result
demonstrates
increased
dissemination
engineering
worldwide.
Their
use
core
components
enhances
functionality,
safety,
transportation
efficiency.
Among
used
as
additions
produce
small
portions,
carbon
nanotubes
have
most
citations
and,
consequently,
studies,
followed
fiber
steel
fiber.
This
highlight
identifies
knowledge
gaps,
benchmark
technologies,
outlines
future
research.
Advanced Engineering Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 16, 2025
Four‐dimensional
printing
has
revolutionized
traditional
three‐dimensional
(3D
printing)
by
using
smart
materials
such
as
shape
memory
polymers
(SMPs).
As
nonmagnetic
materials,
SMPs
require
direct
exposure
to
heat
for
the
effect
be
triggered.
This
limitation
can
addressed
incorporating
magnetic
nanoparticles,
allowing
SMP/nanocomposite
remotely
heated
through
induction
heating.
work
focuses
on
(LSMO)
manganite
with
an
optimized
stoichiometry
of
x
=
0.3.
Polycrystalline
LSMO
is
sintered
from
pure
powders
and
later
added
SMP
solution
mixing
route,
finally
extruded
into
filaments
used
3D
printing.
Significant
improvements
in
elastic
modulus,
yield,
ultimate
strengths
are
observed
following
addition.
All
composites
exhibit
moments
near
3.5
μ
B
Mn
−1
at
ground
state
indicating
desirable
properties.
Shape
properties
evaluated
application
programming
recovery
cycles
as‐printed
single‐cell
auxetic
structure.
The
evaluation
bulk
strain
structure
0
20
wt%
LSMO/SMP
nanocomposite
reveals
no
change
fixity,
a
slight
decrease
ratio
88
81%,
significant
improvement
rate
124.3
179.5%
min
.
Journal of Polymer Science,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 17, 2025
ABSTRACT
The
discovery
of
novel
thermoset
shape
memory
polymers
(TSMPs)
for
additive
manufacturing
can
be
accelerated
through
the
use
a
deep‐generative
algorithm,
minimizing
need
laborious
traditional
laboratory
experiments.
This
study
is
first
to
introduce
an
innovative
approach
that
uses
deep
generative
learning
model,
namely
conditional
variational
autoencoder
(CVAE),
discover
TSMPs
with
lower
glass
transition
temperature
()
and
high
recovery
stress
values
().
In
this
study,
specific
chemical
groups,
such
as
epoxy,
amine,
thiol,
vinyl,
are
integrated
constraints
generate
while
preserving
essential
reaction
properties.
To
address
challenges
posed
by
small
dataset,
CVAE
model
used
graph‐extracted
features.
Unlike
previous
studies
focused
on
single‐polymer
systems,
research
extends
two‐monomer
samples,
discovering
22
TSMPs.
has
practical
implications
in
manufacturing,
biomedical
devices,
aerospace,
robotics
samples
from
limited
data.