Intrinsically Healable and Photoresponsive Electrospun Fabrics: Integrating PVDF-HFP, TPU, and Azobenzene Ionic Liquids DOI Creative Commons

Chun‐Chi Chang,

Lin-Ruei Lee,

Sheng Zheng

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 17(1), P. 2215 - 2223

Published: Dec. 23, 2024

In recent years, the integration of multifunctional properties into electrospun fabrics has garnered significant attention for applications in wearable devices and smart textiles. A major challenge lies achieving a balance among intermolecular interactions, structural stability, responsiveness to external stimuli. this study, we address by developing intrinsically healable photoresponsive composed poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP), thermoplastic polyurethane (TPU), an azobenzene-based ionic liquid ([AzoC6MIM][TFSI]). The interactions between PVDF-HFP [AzoC6MIM][TFSI] enable intrinsic self-healing light-induced responsiveness, while incorporation TPU prevents fiber fusion during electrospinning, maintaining integrity porosity. Our results demonstrate that these can recover up 97% their original mechanical after exhibit reversible changes electrical conductivity under UV visible lights. This versatile approach paves way high concentrations functional liquids fabrics, enabling development textiles with potential advanced sensors.

Language: Английский

Dual Cross-Linked Chitosan-Based Films with pH-Sensitive Coloration and Drug Release Kinetics for Smart Wound Dressings DOI Creative Commons
Jongjit Chalitangkoon,

Arnat Ronte,

Tanaporn Sintoppun

et al.

ACS Omega, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 17, 2025

In this study, we developed dual-cross-linked hydrogel films based on carboxyethyl chitosan (CECS) and sodium alginate (SA), utilizing dialdehyde β-cyclodextrin (DA-βCD) gluconic acid δ-lactone (GDL) as cross-linkers. Designed smart wound dressings, the exhibit pH sensitivity due to incorporation of carboxyethylated phenol red-grafted (CS-PR-AA), which allows them change color from orange purple in response variations. FT-IR TGA analyses confirmed formation imine bonds polyelectrolyte complexes, indicating successful cross-linking. The demonstrated high cell viability, confirming their biocompatibility nontoxicity. swelling behavior varied with pH, underscoring adaptability different environments. Additionally, drug release kinetics were studied for incorporating diclofenac (DCF) at various levels, revealing that rate was influenced by cross-linking density environmental pH. These findings suggest have significant potential offering controlled pH-responsive suitable care applications.

Language: Английский

Citations

1
Wound dressings using electrospun nanofibers: mechanisms, applications, and future directions DOI
Ruiyu Zhou, Yunqi Ma, Min Yang

et al.

European Polymer Journal, Journal Year: 2025, Volume and Issue: unknown, P. 113900 - 113900

Published: March 1, 2025

Language: Английский

Citations

1
Exploring the impact of HAp on the surface morphology, mechanical, wettability, and biodegradation rate of PVA-collagen nanofiber bone scaffolds DOI Creative Commons

Hartatiek,

Maulia Ingganis Wuriantika,

W E S Ayu

et al.

Materials Research Express, Journal Year: 2025, Volume and Issue: 12(1), P. 015405 - 015405

Published: Jan. 1, 2025

Abstract Nanofibers are considered promising materials for tissue engineering applications due to their ability promote cell adhesion and form desired environments where new can grow. Furthermore, we evaluated the impact of increasing concentration (1–6 wt%) HAp on morphology subsequent consequences regarding mechanical properties, wettability, biodegradative nature wrinkle-free PVA/collagen nanofiber scaffolds fabricated by electrospinning. FTIR SEM were used analyze functional groups surface observe morphological characteristics those particles. revealed that when was enhanced, a finer fiber with diameters in range 80–500 nm obtained. The test demonstrated better properties composites load. In addition, water contact angle decreased (a faster degradation rate), which consistent higher suitability degradation.

Language: Английский

Citations

0
Electrospun composite nanofibers for wound healing: synthesis, characterization, and clinical potential of biopolymer-based materials DOI Creative Commons
Prashant D. Yadav,

Pramod V. Londhe,

Sachin Chavan

et al.

Discover Materials, Journal Year: 2024, Volume and Issue: 4(1)

Published: Dec. 20, 2024

The recent advancements in nanotechnology have significantly impacted wound healing, particularly through the development of electrospun nanofibers (NFs). This review summarizes research on NFs made from chitosan, gelatin, curcumin, and rutin, focusing their potential for healing applications. Chitosan is noted its antimicrobial biocompatible properties, gelatin excellent biocompatibility biodegradability, curcumin rutin strong antioxidant anti-inflammatory effects. Electrospinning employed to produce these with controlled diameters morphologies. discusses preparation methods, optimal electrospinning parameters, challenges like solution viscosity environmental conditions. It also includes an assessment using SEM, TEM, FTIR, XRD, tensile testing, DSC evaluate morphology, chemical composition, mechanical thermal biodegradability. In vitro vivo testing NFs' efficacy, including biocompatibility, activity, hemocompatibility, closure rates animal models. highlights that NF combining show enhanced due synergistic which promote cell proliferation, reduce inflammation, prevent infection. Despite promising results, optimizing synthesis process ensuring consistent clinical performance remain. Further needed address advance application NFs. aims guide future contribute more effective wound-healing therapies.

Language: Английский

Citations

3
Intrinsically Healable and Photoresponsive Electrospun Fabrics: Integrating PVDF-HFP, TPU, and Azobenzene Ionic Liquids DOI Creative Commons

Chun‐Chi Chang,

Lin-Ruei Lee,

Sheng Zheng

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 17(1), P. 2215 - 2223

Published: Dec. 23, 2024

In recent years, the integration of multifunctional properties into electrospun fabrics has garnered significant attention for applications in wearable devices and smart textiles. A major challenge lies achieving a balance among intermolecular interactions, structural stability, responsiveness to external stimuli. this study, we address by developing intrinsically healable photoresponsive composed poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP), thermoplastic polyurethane (TPU), an azobenzene-based ionic liquid ([AzoC6MIM][TFSI]). The interactions between PVDF-HFP [AzoC6MIM][TFSI] enable intrinsic self-healing light-induced responsiveness, while incorporation TPU prevents fiber fusion during electrospinning, maintaining integrity porosity. Our results demonstrate that these can recover up 97% their original mechanical after exhibit reversible changes electrical conductivity under UV visible lights. This versatile approach paves way high concentrations functional liquids fabrics, enabling development textiles with potential advanced sensors.

Language: Английский

Citations

0