Construction of dense SiO2 layers by ferric phytate to enhance flame retardancy of polydimethylsiloxane foam composites
Materials Letters,
Journal Year:
2025,
Volume and Issue:
unknown, P. 138486 - 138486
Published: March 1, 2025
Language: Английский
Facile and Efficient Synthesis of Fluorosilicone Polymers by Using an Optimized Gradient Ring‐Opening Reaction
Jinping Li,
No information about this author
Pan Hong-tao,
No information about this author
Fan Yang
No information about this author
et al.
Macromolecular Rapid Communications,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Oct. 29, 2024
Fluorosilicone
rubber
is
essential
for
sealing
in
extreme
temperatures
and
non-polar
environments
due
to
its
exceptional
adaptability.
However,
achieving
a
high
yield
of
fluorosilicone
polymers
with
medium
fluorine
content
remains
challenge.
Herein,
facile
gradient
strategy
developed
that
involves
modifying
the
method
cyclic
monomer
addition
based
on
rate
ring-opening
polymerization
(ROP),
improve
adjust
precisely.
The
process
designed
tailored
reaction
rates
anionic
(AROP)
cationic
(CROP)
via
an
efficient
strategy.
effects
viscosity
vinyl
hydrofluorosilicone
are
investigated
optimized.
Notably,
as-prepared
vinyl-terminated
fluoromethylsilane
60%
(FMS-Vi-60F)
has
(86.6%)
(150
000
mPa·s)
short
time,
which
superior
previous
methods.
Clearly,
this
work
provides
synthesis
fabricating
tunable
content.
Language: Английский
Enhanced dielectric and mechanical properties of silicone rubber composites using the coordination effect between different dimensional fillers of Ti 3 C 2 T x MXene, and CNT
Yu Zeng,
No information about this author
Lu Tang
No information about this author
Composite Interfaces,
Journal Year:
2024,
Volume and Issue:
unknown, P. 1 - 20
Published: Dec. 18, 2024
Low-dimensional
carbon
materials
have
been
widely
used
to
enhance
the
properties
of
polymer
composites.
However,
low-dimensional
are
easy
agglomerate
in
matrix
due
their
nanoscale
effects.
It
may
be
a
good
choice
use
coordination
effect
between
nanomaterials
different
dimensions
dispersion
fillers
and
performance
In
this
paper,
two-dimensional
Ti3C2Tx
MXene
one-dimensional
nanotubes
(CNT)
was
prepare
methyl
vinyl
silicone
rubber
(VMQ)
composites
with
enhanced
properties.
The
research
shows
that
appropriate
proportion
CNT
can
improve
VMQ
optimize
conduction
path,
leading
interfacial
polarization
micro-capacitor
effect,
thus
improved
dielectric
property
Dielectric
constant
7.85
(2.7
times
pure
VMQ)
obtained
composites,
while
loss
tangent
0.00122
at
1
kHz.
addition,
mechanical
were
also
improved,
Young's
modulus
value
lower
than
500
kPa.
prepared
by
adding
nano-fillers
display
properties,
which
has
certain
guiding
significance
for
high
Language: Английский