Kinetics and Reusability of Hydrophobic Eutectic Solvents in Continuous Extraction Processes in a Pilot Setting DOI Open Access
А. В. Кожевникова, D. V. Lobovich, Н. А. Милевский

et al.

Processes, Journal Year: 2024, Volume and Issue: 12(12), P. 2879 - 2879

Published: Dec. 16, 2024

Hydrophobic eutectic solvents (HES) show significant promise as extractants for metal ions. At their current stage of development, however, they have many disadvantages, such high costs, limited data on reusability and, often, lower extraction efficiency when compared with traditional systems. This study investigates the physico-chemical properties five HES formulations based 1-octanol in combination camphor, 2′-hydroxypropiophenone, menthol, 1-octanoic acid, and thymol. The 1-octanol/camphor exhibited substantially higher Fe(III) ions than a solution toluene at same concentration. Furthermore, it showed stability used mixer-settler type extractor. achieved rapid re-extraction rate, phase contact time reduced to just 2 min, without loss efficiency. Using supported liquid membrane method, proposed Oct/Cam enabled threefold concentration iron raffinate under continuous operation, confirming its potential reusability.

Language: Английский

Regioselectivity for Nucleophilic Substitutions of Aryl Halides with DMF in Deep Eutectic Solvent DOI

Chen Shuang-ping,

Pan Tong, Qi Jiang

et al.

Tetrahedron, Journal Year: 2025, Volume and Issue: unknown, P. 134543 - 134543

Published: Feb. 1, 2025

Language: Английский

Citations

0

A Novel Formulation of Fosamprenavir Calcium: Therapeutic Deep Eutectic Solvent with Enhanced Properties DOI Creative Commons
Jasna Prlić Kardum, Iva Zokić, Aleksandra Sander

et al.

Crystals, Journal Year: 2025, Volume and Issue: 15(4), P. 350 - 350

Published: April 9, 2025

In the pharmaceutical industry, deep eutectic solvents can be used to enhance solubility, permeability, and absorption of active ingredients. this paper, were prepared by combining ingredient fosamprenavir calcium with lactic acid in certain molar ratios. The aim study was create a therapeutic solvent same effect as ingredient, but enhanced properties. 1H NMR FTIR spectroscopy identify characterize chemical composition structural changes THEDES. Maximum release from solvent, permeability tested. Different mathematical models chosen describe kinetic behavior drug release.

Language: Английский

Citations

0

Advancements in deep eutectic solvent-based membranes for the extraction, separation, and preconcentration of organic compounds DOI Creative Commons

Nur Fitrah Abdullah Sani,

Rico Ramadhan, Noorfatimah Yahaya

et al.

Advances in Sample Preparation, Journal Year: 2025, Volume and Issue: unknown, P. 100181 - 100181

Published: April 1, 2025

Language: Английский

Citations

0

Exploration of novel eco-friendly techniques to utilize bioactive compounds from household food waste: special reference to food applications DOI Creative Commons
Farzana Siddique,

Zoha Ali,

Muhammad Sajid Arshad

et al.

Frontiers in Food Science and Technology, Journal Year: 2024, Volume and Issue: 4

Published: May 3, 2024

The issue of household waste management is a pervasive global concern. Household waste, especially food comprises reservoir compounds with potential economic value, among which bioactive prominently feature. These compounds, derived from natural chemical substances inherent in animal and protein sources, offer nutritional benefits. Extracted find versatile applications various domains including textiles, cosmetics, nutraceuticals, additives, the agriculture sector. extraction such achieved through diversity techniques, conventional methods alongside non-conventional green approaches as using enzymes, microwaves, or supercritical fluids. However, there an increasing need for sustainable approaches, leading to bioactive-rich extracts low environmental impact. This review thoroughly summarizes origins, kinds, characteristics chemicals found waste. It also addresses most promising innovative methodologies recovery functional materials that have been published recently. New technologies can meaningfully manage are valuable industrial applications.

Language: Английский

Citations

3

Innovative CO2 capture technologies: Exploring the potential of porous liquids containing deep eutectic solvents and hypercrosslinked polymers DOI Creative Commons
Shokat Sarmad, Dariush Nikjoo, Jyri‐Pekka Mikkola

et al.

Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 352, P. 128189 - 128189

Published: May 29, 2024

The current study presented a porous liquid (PL) prepared from propylene glycol-based deep eutectic solvent (DES) and hyper-crosslinked polymers (HCP) that are liquids over wide temperature ranges, including ambient temperature. It was shown the molecules too large to penetrate pores of HCP, so PL is maintained as suspension with permanent free volume for several months can absorb amounts gases. This marks pioneering use DESs medium, replacing ionic due their closely matched properties. structural features both DES HCP retained; increase in CO2 absorption capacity compared pure presence solid proportional amount solid. absorbed rises 1.0105 mmol·g−1 1.3232, 1.6027, 1.2168 PL-1, PL-2, PL-3, respectively. Thermodynamic analysis revealed enthalpy gas allows straightforward regeneration PLs studied cases. investigated show great potential absorbents, incorporation just 0.5 wt% polymer material leading an impressive capacity, up 59 %.

Language: Английский

Citations

3

Facile fractionation of lignocellulosic biomass: a review on promising green technology of deep eutectic solvent for bioethanol production DOI
Fouziya Parveen, Ayush Saxena, Akhtar Hussain

et al.

Biomass Conversion and Biorefinery, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 20, 2024

Language: Английский

Citations

3

Applications and microscopic mechanism analysis of deep eutectic solvents in liquid–liquid extraction DOI

Jiuxu Ruan,

Chunliang Liu,

Zihao Su

et al.

Journal of Industrial and Engineering Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 1, 2024

Language: Английский

Citations

2

Natural Deep Eutectic Solvents as Rust Removal Agents from Lithic and Cellulosic Substrates DOI Creative Commons
Francesco Gabriele, C. Casieri, Nicoletta Spreti

et al.

Molecules, Journal Year: 2024, Volume and Issue: 29(3), P. 624 - 624

Published: Jan. 28, 2024

The peculiar physicochemical features of deep eutectic solvents (DESs), in particular their tunability, make them ideal media for various applications. Despite ability to solubilize metal oxides, use as rust removers from valuable substrates has not yet been thoroughly investigated. In this study, we chose three known DESs, consisting choline chloride and acetic, oxalic or citric acid evaluating remove corrosion products a cellulose-based material linen fabric two different lithotypes, travertine granite. artificial staining was achieved by placing rusty iron grid on surfaces. DESs were applied means cellulose poultice the fabrics, while rusted stone surfaces with cotton swab. Macro- microscopic observations, colorimetry SEM/EDS analysis employed ascertain cleaning effectiveness absence side effects samples after treatment. Oxalic acid-based DES capable removing stains both samples, chloride/citric effective only specimens. results suggest new practical application elimination lithic cellulosic precious artistic value.

Language: Английский

Citations

1

The Rising Potential of Deep Eutectic Solvents: A Patent Analysis of Extraction and Energy Storage Applications DOI Open Access
Muhammad Saqib Iqbal, Zulhasni Abdul Rahim

Authorea (Authorea), Journal Year: 2024, Volume and Issue: unknown

Published: April 20, 2024

Sustainable alternatives to traditional solvents (deep eutectic (DESs) are now in the works. Because of their unique qualities, they may be used various contexts. The potential DESs extraction processes and energy storage technologies has been evaluated by looking at recently issued patents. Compared toxic solvents, DES procedures safer more environmentally friendly for isolating desired chemicals. electrolytes well-suited high-performance batteries supercapacitors due high ionic conductivity electrochemical stability. However, significant commercial use still needs improved issues with scalability, economic feasibility, legislation. Despite these challenges, there rising prospects move from academic curiosity practical solutions, as evidenced patent applications research advancements. platform can improve process efficiency lessen environmental consequences if implemented, coordinated, removed barriers. This provides insight into future technology directions releasing DESs’ full potential.

Language: Английский

Citations

1

The Rising Potential of Deep Eutectic Solvents: A Patent Analysis of Extraction and Energy Storage Applications DOI Open Access
Muhammad Saqib Iqbal, Zulhasni Abdul Rahim

Authorea (Authorea), Journal Year: 2024, Volume and Issue: unknown

Published: June 6, 2024

Sustainable alternatives to traditional solvents (deep eutectic (DESs) are now in the works. Because of their unique qualities, they may be used various contexts. The potential DESs extraction processes and energy storage technologies has been evaluated by looking at recently issued patents. Compared toxic solvents, DES procedures safer more environmentally friendly for isolating desired chemicals. electrolytes well-suited high-performance batteries supercapacitors due high ionic conductivity electrochemical stability. However, significant commercial use still needs improved issues with scalability, economic feasibility, legislation. Despite these challenges, there rising prospects move from academic curiosity practical solutions, as evidenced patent applications research advancements. platform can improve process efficiency lessen environmental consequences if implemented, coordinated, removed barriers. This provides insight into future technology directions releasing DESs’ full potential.

Language: Английский

Citations

1