Water, Journal Year: 2024, Volume and Issue: 16(24), P. 3703 - 3703
Published: Dec. 22, 2024
Emerging pollutants such as butylparaben (BP) are often difficult to remove via conventional wastewater treatment. Therefore, this study aimed produce and characterize graphene oxide (GO) evaluate the adsorption of BP on adsorbent. The GO was made using Hummers method characterized by TGA/DTA, XRD, XRF, BET, point zero charge (pHpzc), SEM, Boehman method. Adsorption experiments were performed in a batch system. removal efficiency from Box–Behnken experimental design 84.3% at concentration 600 µg∙L−1, adsorbent five g∙L−1, pH 7 solution. first-order (PFO) kinetics obtained best fit data compared other models tested study: pseudo-second-order (PSO), Elovich (ELC), intra-particle diffusion (IPD). Langmuir isotherm provided Freundlich isotherm. temperature effect showed that system has spontaneous process, with Gibbs energy lower than zero, increasing increases capacity. ionic salt 1 M increased repulsive forces but did not decrease regeneration cycle rate 85% up second cycle. toxicity analysis confirmed process before after GO.
Language: Английский