A comparison of results of determining the hydrocarbon group-type composition of petroleum samples obtained using various test methods of open-column liquid chromatography
Industrial laboratory Diagnostics of materials,
Journal Year:
2025,
Volume and Issue:
91(1), P. 5 - 14
Published: Jan. 26, 2025
The
hydrocarbon
group-type
composition
(so-called
SARA
-composition)
is
one
of
the
main
characteristics
oil,
providing
an
information
about
its
chemical
nature
and
determining
quality
obtained
petroleum
products.
In
world
laboratory
practice,
data
on
feedstock
are
widely
used
to
assess
colloidal
stability
compatibility
with
crude
reactivity
in
various
conversion
processes,
predicting
physical
properties,
etc.
Traditionally,
determined
accordance
standard
research
chromatographic
methods
that
differ
significantly
from
each
other,
which
often
leads
obtaining
incomparable
analytical
results.
this
paper,
a
comparative
analysis
results
two
test
within
open-column
liquid
chromatography
method
carried
out
for
samples
Russian
origin
(commercial
oils
different
classes
products).
Using
ASTM
D4124
(method
B)
developed
by
JSC
VNII
NP,
content
identical
groups
maltene
part
was
determined:
saturated
hydrocarbons
(SH)
paraffinic-naphthenic
(PNH),
naphthenic
aromatic
(NAH)
(AH),
polar
(PAH)
resins
(R),
respectively.
It
shown
increase
density
viscosity
samples,
less
(SH
PNH)
their
decreases
more
(PAH
R)
obviously
increases,
there
no
pronounced
distribution
pattern
NAH
AH
groups.
Statistical
processing
revealed
insignificant
differences
«heavy
viscous»
oils,
despite
large
error
those
according
method.
Obtaining
comparable
justifies
use
both
not
only
high-boiling
products,
but
also
oil
samples.
Language: Английский
Supervised Learning to Improve Software for Crude Oil Analysis Using Low-Field NMR Relaxometry
Salim Ok,
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Talha Furkan Canan,
No information about this author
Sohaib Kholosy
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et al.
Energy & Fuels,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 11, 2025
Language: Английский
Hydrocracking of Various Vacuum Residues
Fuels,
Journal Year:
2025,
Volume and Issue:
6(2), P. 35 - 35
Published: May 7, 2025
The
residue
conversion
processes,
coking,
visbreaking,
and
fluid
catalytic
cracking
(FCC),
have
demonstrated
that
feedstock
quality
is
the
single
factor
most
affects
process
performance.
While,
for
FCC,
it
known
heavy
oil
at
a
maximum
gasoline
yield
point
can
vary
between
50
85
wt.
%,
vacuum
hydrocracking,
no
reports
appeared
yet
to
reveal
dependence
of
on
being
hydrocracked.
In
order
search
such
dependence,
eight
residues
derived
from
medium,
heavy,
extra
crude
oils
been
hydrocracked
in
laboratory
unit
different
reaction
temperatures.
current
study
has
witnessed
hydrocracking
obeys
same
rule
as
other
confirming
great
influence
A
variation
45
%
be
observed
when
sediment
content
atmospheric
within
acceptable
limit,
guaranteeing
planned
cycle
length.
An
intercriteria
analysis
was
performed,
revealed
negative
consonances
with
contents
nitrogen
metals.
Correlations
were
developed
which
predict
constant
operating
conditions
uncertainty
measurement
1.7
correlation
coefficient
0.964.
(HCAR)
predicted
0.985.
correlations
this
work
disclosed
higher
metals,
nitrogen,
asphaltenes,
lower
sulfur,
is.
It
also
shown
residues,
reactivity
(the
identical
conditions),
indicate
significant
difference
HCAR
due
their
diverse
propensity
form
sediments
hydrocracking.
Language: Английский