Sustainability,
Journal Year:
2025,
Volume and Issue:
17(5), P. 2084 - 2084
Published: Feb. 28, 2025
Maize
and
wheat
grains
are
at
significant
risk
of
accumulating
excessive
heavy
metals
in
acidic
soils,
but
relatively
few
comparative
studies
have
been
conducted
on
the
two.
This
study
employed
Spearman
correlation
analysis,
random
forest
modeling,
structural
equation
modeling
to
systematically
investigate
interdependences
between
soil
properties
metal
accumulation
(Cd,
Cr,
As,
Pb,
Hg)
cereal
grains.
The
results
revealed
distinct
patterns
content
sequences
maize
grains:
exhibited
Cr
>
Pb
As
Cd
Hg,
while
followed
Hg.
Bioconcentration
factor
(BCF)
differed
significantly,
showing
Hg
versus
wheat.
Soil
cation
exchange
capacity
demonstrated
strongest
influence
both
crops.
Arsenic
mechanisms
displayed
species-specific
dependencies,
with
primarily
regulated
by
organic
matter
clay
content.
Notably,
a
positive
(p
≤
0.05)
concentrations
was
observed
crops,
suggesting
potential
homologous
pollution
sources.
These
findings
elucidate
crop-specific
governed
physicochemical
properties.
demonstrates
that
under
similar
growing
conditions,
(BCF
=
0.068)
exhibits
weaker
ability
accumulate
compared
0.467).
Moreover,
showed
responses
properties,
particularly
their
Cd.
By
addressing
contamination
this
work
supports
development
safer
agricultural
practices
improved
crop
quality
control.
Chemosensors,
Journal Year:
2025,
Volume and Issue:
13(2), P. 62 - 62
Published: Feb. 9, 2025
This
study
investigated
the
morphological
dependence
of
ZnO
nanostructures,
specifically
nanotube-
and
nanorod-based
electrodes,
on
their
electrochemical
performance
for
detection
lead
ions
(Pb2⁺)
in
aqueous
solutions.
The
results
demonstrate
that
nanotubes
exhibit
significantly
enhanced
sensitivity
compared
to
nanorods
during
CV
measurements.
During
SWV
measurements,
(116.79
mA·mM−1)
a
lower
limit
0.0437
μM
were
determined.
hollow,
high-aspect-ratio
structure
provides
larger
active
surface
area
facilitates
better
ion
accessibility,
resulting
superior
electron
transfer
efficiency
catalytic
activity.
These
underscore
critical
role
morphology
optimizing
ZnO-based
sensors.
Analysis
real
water
samples
from
various
natural
reservoirs
revealed
no
detectable
lead,
while
was
identified
exclusively
artificially
prepared
containing
exposed
hunting
shot.
Over
30-day
period,
sensor
retained
over
95%
its
initial
when
stored
under
vacuum
conditions,
demonstrating
minimal
signal
degradation.
Under
ambient
stability
loss
attributed
moisture
adsorption
porous
nanostructure.
also
displayed
outstanding
reproducibility,
with
current
response
variations
across
multiple
probes
remaining
within
4%.
cost-effective
simple
fabrication
process
nanostructures
further
highlights
potential
scalable
production,
environmental
monitoring,
integration
into
portable
sensing
devices.
Sustainability,
Journal Year:
2025,
Volume and Issue:
17(5), P. 2084 - 2084
Published: Feb. 28, 2025
Maize
and
wheat
grains
are
at
significant
risk
of
accumulating
excessive
heavy
metals
in
acidic
soils,
but
relatively
few
comparative
studies
have
been
conducted
on
the
two.
This
study
employed
Spearman
correlation
analysis,
random
forest
modeling,
structural
equation
modeling
to
systematically
investigate
interdependences
between
soil
properties
metal
accumulation
(Cd,
Cr,
As,
Pb,
Hg)
cereal
grains.
The
results
revealed
distinct
patterns
content
sequences
maize
grains:
exhibited
Cr
>
Pb
As
Cd
Hg,
while
followed
Hg.
Bioconcentration
factor
(BCF)
differed
significantly,
showing
Hg
versus
wheat.
Soil
cation
exchange
capacity
demonstrated
strongest
influence
both
crops.
Arsenic
mechanisms
displayed
species-specific
dependencies,
with
primarily
regulated
by
organic
matter
clay
content.
Notably,
a
positive
(p
≤
0.05)
concentrations
was
observed
crops,
suggesting
potential
homologous
pollution
sources.
These
findings
elucidate
crop-specific
governed
physicochemical
properties.
demonstrates
that
under
similar
growing
conditions,
(BCF
=
0.068)
exhibits
weaker
ability
accumulate
compared
0.467).
Moreover,
showed
responses
properties,
particularly
their
Cd.
By
addressing
contamination
this
work
supports
development
safer
agricultural
practices
improved
crop
quality
control.