IMPREGNASI ZEOLIT ALAM ENDE DENGAN TITANIUM MENJADI BAHAN FOTOKATALIS DOI Creative Commons

Gregorio Antonny Bani,

Jennilien Merinda Ghello,

Victorius Alupan

et al.

Dalton Jurnal Pendidikan Kimia dan Ilmu Kimia, Journal Year: 2024, Volume and Issue: 7(2), P. 123 - 123

Published: Aug. 13, 2024

Karakteristik alami zeolit alam sangat mempengaruhi kemampuannya untuk mengadsorpsi logam aktif di dalam kerangkanya. Oleh karena itu, penelitian ini bertujuan mengetahui konsentrasi titanium oksida yang sesuai memodifikasi Ende menjadi bahan fotokatalis. Berdasarkan hasil penelitian, disimpulkan bahwa (TiO2) adalah sebesar 0,2 M diimpregnasikan ke kerangka Ende. Zeolit merupakan jenis mordenit dan tidak mengalami perubahan struktur setelah dengan kerangkanya, tetapi terjadi pergesaran sudut 2θ° sebanyak 0,02 arah lebih besar. Luas permukaan terbesar berada perlakuan yaitu 23,365 m2/gram, penampakan morfologi padat rapi, serta peningkatan rasio Si/Al. Perlakuan larutan terbaik mampu memberikan 16,40%

Enhancing manganese sorption: Batch and fixed-bed column studies on activated zeolite DOI Creative Commons

Silmara Sanzana,

Norberto J. Abreu, Marcela Levío-Raimán

et al.

Environmental Technology & Innovation, Journal Year: 2023, Volume and Issue: 33, P. 103495 - 103495

Published: Dec. 21, 2023

Dissolved Mn2+ in groundwater is dangerous for human health since it may act as a neurotoxin. To address this issue, sorption has emerged an environmentally-friendly technology removal. This study aimed to assess the effect of activation Chilean natural zeolite, by modification its compensating cations with NaCl, on capacity removal using batch and fixed-bed column studies. The activated zeolites were characterized SEM-EDS, TXRF, XRD, N2 adsorption assays. results studies demonstrate that Na+ enhances these from 4.55 5.92 mg g-1, negligible changes pore structure. experimental data fitted well pseudo-second-order kinetic Langmuir models. Furthermore, MnOx(s) formed during was identified surface zeolite XRD SEM-EDS analysis. conducted at two bed heights: H1 (5 cm) H2 (10 cm). breakthrough curves adjusted models Thomas Dose-response. dose-response model adequately described both R2>0.90. system (qmdr) 2.38 5.13 H2, respectively. regeneration achieved NaCl solution improving efficiency after reuse. work highlights potential effective material viable improve water quality affected geogenic contamination.

Language: Английский

Citations

3

Electrocoagulation Combined with Synthetic Zeolite—Does the Size of Zeolite Particles Matter? DOI Open Access
Nediljka Vukojević Medvidović, Ladislav Vrsalović, Sandra Svilović

et al.

Minerals, Journal Year: 2023, Volume and Issue: 13(9), P. 1141 - 1141

Published: Aug. 29, 2023

Although electrocoagulation combined with zeolite (ECZ) shows higher efficiency in wastewater treatment, the actual contribution of particle size has not been fully explored. In this work, influence synthetic SZ (<90, 90–160, and 160–600 μm) on ECZ treatment compost leachate very high organic load is investigated together different electrode materials (Fe, Al, Zn), current densities (0.003, 0.009 0.018 A/cm2), contact times (10, 20 30 min). The results positively highlight that largest should be used ECZ, as it leads to a lower increase pH temperature, decrease chemical oxygen demand (COD) turbidity, consumption, while causing more damage surface. estimated energy costs ranged from 3.960 kW/m3–1313.657 kW/m3. Taguchi L9 orthogonal configuration showed highest COD turbidity under conditions µm particles. powder X-ray diffractometer (PXRD) analysis interplanar spacing decreases when smaller medium sizes are used, effect was observed larger size. SEM-EDS oxygen, silicon, aluminium predominant elements electrogenerated sludge coupled zeolite.

Language: Английский

Citations

2

Facile Synthesis of Sodium Dodecyl Sulfate Intercalated Mg‐Al LDH and its Excellent Adsorption Performances for Cu2+ from Aqueous Solution DOI
Naicai Xu,

Xun Wen,

Dandan Shi

et al.

ChemistrySelect, Journal Year: 2024, Volume and Issue: 9(14)

Published: April 11, 2024

Abstract In this study, the magnesium aluminum layered double hydroxide intercalated with sodium dodecyl sulfate (Mg‐Al S‐LDH) was synthesized by using a roasting–restoration method based on Mg‐Al LDH precursor, and their effectiveness in removing Cu 2+ from aqueous solutions investigated. Detailed microstructural characterization of these adsorption materials involved employing X‐ray diffraction (XRD), Fourier‐transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), transmission (TEM), nitrogen adsorption/desorption isotherms (N 2 ad/desorption), thermogravimetric‐differential thermal gravimetric analysis (TG‐DTG). The experimental results revealed that S‐LDH displayed plate‐like structure larger surface area enhanced ability. Specifically, maximum capacity, reaching 96.15 mg ⋅ g −1 , achieved at temperature 298 K, accompanied rapid rate. kinetics adhered to pseudo‐second‐order model, suggesting chemisorption controlled behavior. Furthermore, followed Freundlich signifying multi‐site mechanism onto layers S‐LDH. Thermodynamic investigations indicated higher temperatures facilitated dissolution strengthened affinity S‐LDH, positive Δ H Θ value process endothermic temperature‐enhancing. Ion selectivity experiments demonstrated Cd Pb ions had significant impact adsorption, while effects Zn Fe were less pronounced. primary mechanisms encompassed precipitation, complexation layers, isomorphous substitution. This study sheds light promising potential as an effective adsorbent for heavy metal removal provides valuable insights into its performance different environmental conditions.

Language: Английский

Citations

0

Adsorption−desorption of Zn2+ ions using hydroxyapatite and recovery of zinc by electrochemical precipitation method into deep eutectic solvent DOI
Lê Thị Duyên,

Công Tiến Dũng,

Đinh Thị Mai Thanh

et al.

Polyhedron, Journal Year: 2024, Volume and Issue: 261, P. 117126 - 117126

Published: Oct. 1, 2024

Language: Английский

Citations

0

IMPREGNASI ZEOLIT ALAM ENDE DENGAN TITANIUM MENJADI BAHAN FOTOKATALIS DOI Creative Commons

Gregorio Antonny Bani,

Jennilien Merinda Ghello,

Victorius Alupan

et al.

Dalton Jurnal Pendidikan Kimia dan Ilmu Kimia, Journal Year: 2024, Volume and Issue: 7(2), P. 123 - 123

Published: Aug. 13, 2024

Karakteristik alami zeolit alam sangat mempengaruhi kemampuannya untuk mengadsorpsi logam aktif di dalam kerangkanya. Oleh karena itu, penelitian ini bertujuan mengetahui konsentrasi titanium oksida yang sesuai memodifikasi Ende menjadi bahan fotokatalis. Berdasarkan hasil penelitian, disimpulkan bahwa (TiO2) adalah sebesar 0,2 M diimpregnasikan ke kerangka Ende. Zeolit merupakan jenis mordenit dan tidak mengalami perubahan struktur setelah dengan kerangkanya, tetapi terjadi pergesaran sudut 2θ° sebanyak 0,02 arah lebih besar. Luas permukaan terbesar berada perlakuan yaitu 23,365 m2/gram, penampakan morfologi padat rapi, serta peningkatan rasio Si/Al. Perlakuan larutan terbaik mampu memberikan 16,40%

Citations

0