Synthesis ofN-(acyloxy)-N-alkynylamidesviageneration of “C2” from hypervalent alkynyliodane and a weak base DOI

Kentaro Kagami,

Xueying Liang,

Nanako Ishibashi

et al.

Chemical Communications, Journal Year: 2023, Volume and Issue: 59(53), P. 8274 - 8277

Published: Jan. 1, 2023

The first synthesis of N-(acyloxy)ynamides was realized through the coupling N-(acyloxy)amides and hypervalent alkynyliodane under mild conditions. This reaction probably involves biradical species ("C2") generation radical processes. Furthermore, we also demonstrated that N-(acyloxy)ynamide could be transformed into a N-sulfonylimidate derivative by copper catalyst. study provides new building blocks for synthetic organic chemistry reactions improves understanding chemical reactivity "C2".

Language: Английский

Synthesis ofN-(acyloxy)-N-alkynylamidesviageneration of “C2” from hypervalent alkynyliodane and a weak base DOI

Kentaro Kagami,

Xueying Liang,

Nanako Ishibashi

et al.

Chemical Communications, Journal Year: 2023, Volume and Issue: 59(53), P. 8274 - 8277

Published: Jan. 1, 2023

The first synthesis of N-(acyloxy)ynamides was realized through the coupling N-(acyloxy)amides and hypervalent alkynyliodane under mild conditions. This reaction probably involves biradical species ("C2") generation radical processes. Furthermore, we also demonstrated that N-(acyloxy)ynamide could be transformed into a N-sulfonylimidate derivative by copper catalyst. study provides new building blocks for synthetic organic chemistry reactions improves understanding chemical reactivity "C2".

Language: Английский

Citations

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