Modeling Analysis of Nocturnal Nitrate Formation Pathways during Co-Occurrence of Ozone and PM2.5 Pollution in North China Plain DOI Creative Commons

Wei Dai,

Ke Cheng,

Xiangpeng Huang

et al.

Atmosphere, Journal Year: 2024, Volume and Issue: 15(10), P. 1220 - 1220

Published: Oct. 13, 2024

The rapid formation of secondary nitrate (NO3−) contributes significantly to the nocturnal increase PM2.5 and has been shown be a critical factor for aerosol pollution in North China Plain (NCP) region summer. To explore NO3− pathways influence ozone (O3) on production, WRF-CMAQ model was utilized simulate O3 co-pollution events NCP region. simulation results demonstrated that heterogeneous hydrolysis dinitrogen pentoxide (N2O5) accounts 60% 67% production at night (22:00 05:00) is main source NO3−. enhances NO3 radicals, thereby further promoting N2O5 production. In evening (20:00 21:00), sustains hydroxyl (OH) resulting reaction between OH radicals nitrogen dioxide (NO2), which 48% 64% formation. Our suggest effective control can also reduce night.

Language: Английский

Trends of source apportioned PM2.5 in Tianjin over 2013–2019: Impacts of Clean Air Actions DOI
Qili Dai, Jiajia Chen, Xuehan Wang

et al.

Environmental Pollution, Journal Year: 2023, Volume and Issue: 325, P. 121344 - 121344

Published: March 4, 2023

Language: Английский

Citations

28

Nitrate pollution deterioration in winter driven by surface ozone increase DOI Creative Commons

Zekun Zhang,

Bingqing Lu, Chao Liu

et al.

npj Climate and Atmospheric Science, Journal Year: 2024, Volume and Issue: 7(1)

Published: July 4, 2024

Abstract Recently, nitrate (NO 3 – ) levels in winter pollution eastern China have been increasing yearly and become the main component of PM 2.5 . The factors contributing to this rise surface NO concentrations remain unclear, complicating development targeted control measures. This study utilizes observational data from Shanghai during 2019, alongside box model simulations, recreate − event identify key growth process. analysis demonstrated that a ozone significantly promotes production by facilitating x conversion via gas-phase heterogeneous reactions. These findings could explain correlation between synchronous increase recent years. Furthermore, simulation strategies for volatile organic compounds (VOCs) identified an approach centered on reduction as notably effective mitigating Yangtze River Delta.

Language: Английский

Citations

6

Examining the implications of photochemical indicators for O3–NOx–VOC sensitivity and control strategies: a case study in the Yangtze River Delta (YRD), China DOI Creative Commons
Xun Li, Momei Qin, Lin Li

et al.

Atmospheric chemistry and physics, Journal Year: 2022, Volume and Issue: 22(22), P. 14799 - 14811

Published: Nov. 22, 2022

Abstract. Ozone (O3) has become a significant air pollutant in China recent years. O3 abatement is challenging due to the nonlinear response of precursors nitrogen oxides (NOx) and volatile organic compounds (VOCs). Photochemical indicators are widely used estimate O3–NOx–VOC sensitivity, this important policy implications. However, effectiveness seldom been evaluated. This study examined applications four that include ratio production rates H2O2 HNO3 (PH2O2/PHNO3), HCHO/NO2, HCHO/NOy, reactive (NOy) Yangtze River Delta (YRD) with localized thresholds. The overall accuracy was high (>92 %) for all not significantly reduced different simulation periods or locations region. By comparing isopleths, it found HCHO/NO2 HCHO/NOy showed most consistency, whereas PH2O2/PHNO3 tended underestimate (overestimate) positive NOx. Additionally, less likely attribute formation mixed sensitivity than other indicators, demonstrated preference single-pollutant control strategy. also revealed details methodology derive threshold values impacted results, may produce uncertainties application photochemical indicators.

Language: Английский

Citations

21

Evolution of atmospheric age of particles and its implications for the formation of a severe haze event in eastern China DOI Creative Commons
Xiaodong Xie,

Jianlin Hu,

Momei Qin

et al.

Atmospheric chemistry and physics, Journal Year: 2023, Volume and Issue: 23(18), P. 10563 - 10578

Published: Sept. 25, 2023

Abstract. Atmospheric age reflects how long particles have been suspended in the atmosphere, which is closely associated with evolution of air pollutants. Severe regional haze events occur frequently China, influencing quality, human health, and climate. Previous studies explored characteristics mass concentrations compositions fine particulate matter (PM2.5) during events, but atmospheric remains unclear. In this study, age-resolved University California, Davis/California Institute Technology (UCD/CIT) model was developed applied to simulate concentration distribution PM2.5 a severe episode eastern China. The results indicated that North China Plain (NCP) gradually accumulated due stagnant weather conditions beginning stage event. Accordingly, elemental carbon (EC), primary organic aerosol (POA), sulfate (SO42-), secondary (SOA) increased. subsequent growth driven by local chemical formation nitrate (NO3-) under high relative humidity. newly formed NO3- led decrease mean particles. During transport stage, aged from NCP moved downwind Yangtze River Delta (YRD) region, leading sharp increase average EC, POA, SO42-, SOA YRD. contrast, ammonium remained unchanged or even slightly decreased continuous YRD region. Different among these components provides unique perspective on information can also be used for designing effective control strategies different PM2.5.

Language: Английский

Citations

11

Quantifying Contributions of Factors and Their Interactions to Aerosol Acidity with a Multiple-Linear-Regression-Based Framework: A Case Study in the Pearl River Delta, China DOI Creative Commons
Hong Ling,

Mingqi Deng,

Qi Zhang

et al.

Atmosphere, Journal Year: 2024, Volume and Issue: 15(2), P. 172 - 172

Published: Jan. 29, 2024

This study presents an approach using multiple linear regression to quantify the impact of meteorological parameters and chemical species on aerosol pH variance in urban setting Pearl River Delta, China. Additionally, it assesses contributions interactions among these factors pH. The analysis successfully explains over 96% variance, attributing 85.8% original variables 6.7% bivariate interactions, with further 2.3% 1.0% from trivariate quadrivariate respectively. Our results highlight that factors, particularly temperature humidity, are more influential than components affecting variance. Temperature alone accounts for 37.3% while humidity contributes approximately 20%. On front, sulfate ammonium most significant contributors, adding 14.3% 9.1% In realm interplay between components, especially TNO3–RH pair, is exceptionally impactful, constituting 58.1% total contribution interactions. summary, this illuminates their interplay, suggesting integration statistical methods thermodynamic models enhanced understanding acidity dynamics future.

Language: Английский

Citations

4

Light absorption enhancement of black carbon and its impact factors during winter in a megacity of the Sichuan Basin, China DOI

Yuting Lan,

Li Zhou, Song Liu

et al.

The Science of The Total Environment, Journal Year: 2024, Volume and Issue: 918, P. 170374 - 170374

Published: Feb. 2, 2024

Language: Английский

Citations

4

An Analysis of Primary Contributing Sources to the PM2.5 Composition in a Port City in Canada Influenced by Traffic, Marine, and Wildfire Emissions DOI Creative Commons
Seyed Hamid Delbari,

Maryam Zare Shahne,

Vahid Hosseini

et al.

Atmospheric Environment, Journal Year: 2024, Volume and Issue: 334, P. 120712 - 120712

Published: July 24, 2024

Ambient air quality, specifically fine particulate matter (PM2.5) pollution, poses a global health concern due to its associations with adverse effects and persistent presence in urban settings. This study investigates PM2.5 exposure traffic-influenced residential area Vancouver, employing chemical speciation data sampled the vicinity of major road throughout 2018. Using receptor-oriented models, Positive Matrix Factorization (PMF), Principal Component Analysis (PCA), emission sources contributing total mass were identified. The Organic Elemental carbon concentration time series analysis reveals impacts from traffic episodic influences wildfires heating. Applying PMF, we attribute identified factors specific sources: (33%), secondary aerosols (27%), dust (14%), Marine Heavy Fuel Combustion (HFC) (12%), Local (9%), rare metallic elements (5%), respectively. apportioning is subsequently verified by PCA, which introduces sea salt factor analysis. conditional probability function on integrated wind speed direction, PM further confirms partial apportionment marine HFC, elements, local factors. Lastly, comparing results 2015 inventory Vancouver shows similarities share primary while overlooking emissions latter, emphasizing importance field sampling for accurate source characterization. highlights necessity receptor modeling coupled quantifying contribution characteristics sources, particularly near neighborhoods. Precise characterization aids studies that contribute informed quality management policy regulations.

Language: Английский

Citations

4

Water quality assessment using IRWQIsc and NSFWQI water quality indicators; A case study: Talar River (Iran) DOI Creative Commons

Mohammad Roshani-Sefidkouhi,

Fatemeh Mortezazadeh, Masoumeh Eslamifar

et al.

Heliyon, Journal Year: 2025, Volume and Issue: 11(2), P. e41812 - e41812

Published: Jan. 1, 2025

One of the driest countries in world, Iran has been facing several challenges related to water shortage, leading serious social, economic, and environmental impacts. Given escalating urbanization industrial development within Iran, a comprehensive assessment surface quality utilizing both US National Sanitation Foundation Water Quality Index (NSFWQI) for (IRWQIsc) is imperative. This study aimed evaluate Talar River Mazandaran, 2023, through IRWQIsc NSFWQI. was conducted River, located Mazandaran Province Iran. samples from were collected assess 11 physicochemical parameters 10 sampling Points. A total 60 monthly during winter summer 2023. The NSFWQI selected overall River. Nitrate (NO3 -) concentrations ranged 29.32 85.89 mg/L across seasons, with average values falling World Health Organization (WHO) standards. Phosphate (PO4 3-) Chemical Oxygen Demand (COD) levels exceeded WHO limits on occasion, while turbidity electrical conductivity (EC) consistently surpassed Environmental Protection Agency (EPA) guidelines. pH Biochemical (BOD) remained acceptable ranges. indicated generally poor all sites, slight seasonal variations suggesting slightly better conditions indicates that NO3 - PO4 3- meet limits, but COD, turbidity, EC exceed recommended threshold. highlight resulting agricultural pollution. Urgent integrated management essential mitigate these impacts safeguard river health face pressures.

Language: Английский

Citations

0

Impacts of irrigation on ozone and fine particulate matter (PM2.5) air quality: implications for emission control strategies for intensively irrigated regions in China DOI Creative Commons

Tiangang Yuan,

Tzung‐May Fu, Aoxing Zhang

et al.

Atmospheric chemistry and physics, Journal Year: 2025, Volume and Issue: 25(7), P. 4211 - 4232

Published: April 14, 2025

Abstract. Intensive irrigation is known to alleviate crop water stress and alter regional climate, which can in turn influence air quality, with ramifications for human health food security. However, the interplay between irrigation, climate pollution especially simultaneously intensively irrigated heavily polluted regions China has rarely been studied. Here we incorporated a dynamic scheme into climate–air quality coupled model examine potential impacts of on ozone (O3) fine particulate matter (PM2.5) China. Results show that increases PM2.5 by 12 µg m−3 (28 %) but reduces O3 concentration 3–4 ppb (6 %–8 %). Among PM2.5, nitrate ammonium aerosols rise 70 % 40 %, respectively, upon introducing secondary formation contributing ∼ 60 10 %–30 respectively. High humidity low temperature promote aerosols. To mitigate these adverse effects found 20 reduction NH3 NOx emissions more effective compared individual emission reductions, while enhancement due be completely offset itself. Our study highlights benefits regarding problems under currently prevalent modes anthropogenic scenarios, emphasizing need an integrated approach balance conservation, pollution, change mitigation security face development needs.

Language: Английский

Citations

0

Characteristics of the Long-Term Variations in Sulfate–Nitrate–Ammonium Aerosols in a Coastal City in Northern China—Interpretability Analysis from a Machine Learning Perspective DOI

Jianbin Huang,

Xiaoyun Zhang,

Yuanzhe Ni

et al.

Atmospheric Environment, Journal Year: 2025, Volume and Issue: unknown, P. 121245 - 121245

Published: April 1, 2025

Language: Английский

Citations

0