Russian Chemical Reviews, Journal Year: 2025, Volume and Issue: 94(4), P. RCR5164 - RCR5164
Published: April 1, 2025
The discovery of reversible deactivation radical polymerization (RDRP), or controlled (CRP) has revolutionized the chemistry synthetic polymers. This strategy opened up way to polymer materials with architecture, composition, and functions. Currently, owing use novel approaches related chain deactivation, gone beyond synthesis. It can be used obtain not only macromolecular organic compounds, but also organic-inorganic hybrid materials, bioconjugates, promising polymers for electronics, energy production, medicine, other high-tech fields. is exceptionally important that some CRP methods have a clear-cut environmental component, since they are focused on compliance most principles green development nature-like processes in targeted synthesis well-defined specified set properties characteristics. review considers particular examples analyzes possible prospects practical application environmentally benign functional A comparative analysis performed classical living wide range monomers (reversible inhibition, addition fragmentation transfer, atom transfer involving transition metal complexes), concept photoredox catalysis, methodology as applied gives above aspects, including procedural details photoinitiation their relationship key principles. In our opinion, this will interest specialists field chemistry, chemists scientists. <br> bibliography includes 242 references.
Language: Английский