Rhodium(iii)-catalyzed C–H alkylation of arylhydrophthalazinediones with α-Cl ketones as sp3-carbon alkylated agents DOI
He Li,

Haichun Gu,

Ning Xu

et al.

Organic & Biomolecular Chemistry, Journal Year: 2023, Volume and Issue: 21(10), P. 2096 - 2100

Published: Jan. 1, 2023

A C–H alkylation of arylhydrophthalazinediones catalyzed by [Cp*RhCl 2 ] is developed using α-Cl ketones as sp 3 -carbon alkylated agents.

Language: Английский

Annulation of enaminones with quinonediimides/quinoneimides for selective synthesis of indoles and 2-aminobenzofurans DOI

Zukang Zhong,

Lihua Liao, Yunyun Liu

et al.

Chemical Communications, Journal Year: 2023, Volume and Issue: 59(45), P. 6885 - 6888

Published: Jan. 1, 2023

The annulation reactions of enaminones with quinonediimides/quinoneimides for the selective synthesis indoles and 2-aminobenzofurans have been realized. With Zn(II) catalysis, quinonediimides reacted to give via HNMe2-elimination-based aromatization. Fe(III) quinoneimides provided a key dehydrogenative

Language: Английский

Citations

19
Regioselective [3+2]‐Spiroannulation and [4+n]‐Annulation Approaches through Activation of C−H Bond Facilitated by Ru(II) as Catalyst: Role of Solvent Selectivity DOI
Rahul Dev Mandal, Anindita Sarkar, Dwaipayan Das

et al.

Advanced Synthesis & Catalysis, Journal Year: 2024, Volume and Issue: 366(8), P. 1863 - 1876

Published: Feb. 21, 2024

Abstract Ru(II)‐catalyzed and solvent‐switched [3+2]‐spiroannulation [4+n] (n=1, 2, 3) annulations of 2‐aryl quinazolinone or 2‐aryl‐2,3‐dihydrophthalazine‐1,4‐diones with ynones alkynyl alcohol 1,3‐diynes under mild reaction conditions have been analyzed. These reactions take place in the presence appropriate solvent features a redox‐neutral pathway. Ynone serves as an ‘atypical one‐carbon unit’ [4+1] annulation generates tetrasubstituted carbon center bearing diverse heterocycles through [3+2] strategies. Post transformations synthesized spiro‐products augments potential developed methodology.

Language: Английский

Citations

4
The literature of heterocyclic chemistry, part XXII, 2022 DOI
Галина А. Газиева, Yu. B. Evdokimenkova, N. O. Soboleva

et al.

Advances in heterocyclic chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Language: Английский

Citations

0
Rhodium-Catalyzed Enantioselective Spiroannulation of 2-Alkenylphenols with Alkynes DOI Open Access

Suzhen Zhang,

Wenwen Zhang, Hui Yang

et al.

Chinese Journal of Organic Chemistry, Journal Year: 2023, Volume and Issue: 43(8), P. 2926 - 2926

Published: Jan. 1, 2023

84%收率和 81% ee 对映选择性获得手 性螺环己烯酮化合物.该反应条件温和, 具有良好的官能团耐受性.

Language: Английский

Citations

6
Rhodium(iii)-catalyzed C–H alkylation of arylhydrophthalazinediones with α-Cl ketones as sp3-carbon alkylated agents DOI
He Li,

Haichun Gu,

Ning Xu

et al.

Organic & Biomolecular Chemistry, Journal Year: 2023, Volume and Issue: 21(10), P. 2096 - 2100

Published: Jan. 1, 2023

A C–H alkylation of arylhydrophthalazinediones catalyzed by [Cp*RhCl 2 ] is developed using α-Cl ketones as sp 3 -carbon alkylated agents.

Language: Английский

Citations

2