The photoinduced electron transfer (PET) reactions of silyl ethers and their application

Tetrahedron Chem, Journal Year: 2024, Volume and Issue: 9, P. 100067 - 100067

Published: Feb. 24, 2024

Photocatalyzed organic reaction has been greatly developed and applied at the last 20 years, because photochemical synthesis is an efficiently green synthetic strategy, featuring simple operation, high chemical selectivity low price etc. Meanwhile, organosilicon reagents have widely used in field of since they were discovered. reactions compounds, especially silyl ethers, taken advantages mild condition, good atom economy performed synthesizing silicon-containing molecules carbon skeleton which difficultly acquired by traditional approaches. This review mainly introduced enol cyclopropyl acetals, ethers ketene acetals via PET triggered sensitizers/co-sensitizers, photocatalysts, electron donor-acceptor (EDA) complex, no photocatalysts sensitizers so on.

Language: Английский

Nickel-catalyzed stereospecific reductive cross-coupling of vinyl chlorosilanes with axially chiral biaryl electrophiles

Chemical Communications, Journal Year: 2024, Volume and Issue: 60(96), P. 14204 - 14207

Published: Jan. 1, 2024

Nickel-catalyzed stereospecific reductive cross-coupling of vinyl chlorosilanes with chiral biaryl electrophiles for the synthesis axially organosilanes.

Language: Английский