Journal of Materials Chemistry C,
Год журнала:
2021,
Номер
10(3), С. 994 - 1002
Опубликована: Дек. 7, 2021
Tunable
and
thermally
stable
NIR
photoluminescence
has
been
realized
in
Na
3
Sc
2
(PO
4
)
:Cr
3+
phosphors
by
co-doping
Ga
ions.
Their
application
as
a
luminescence
converter
for
LEDs
is
also
demonstrated.
Bioactive Materials,
Год журнала:
2022,
Номер
17, С. 49 - 70
Опубликована: Фев. 1, 2022
As
a
kind
of
nature-derived
bioactive
materials,
polyphenol-based
hydrogels
possess
many
unique
and
outstanding
properties
such
as
adhesion,
toughness,
self-healing
due
to
their
specific
crosslinking
structures,
which
have
been
widely
used
in
biomedical
fields
including
wound
healing,
antitumor,
treatment
motor
system
injury,
digestive
disease,
oculopathy,
bioelectronics.
In
this
review,
starting
with
the
classification
common
hydrogels,
pyramid
evolution
process
from
structures
derived
then
applications
is
elaborated,
well
efficient
reverse
design
considerations
hydrogel
systems
are
proposed.
Finally,
existing
problems
development
prospects
these
materials
discussed.
It
hoped
that
perspective
review
can
promote
further
innovation
breakthroughs
future.
RSC Advances,
Год журнала:
2023,
Номер
13(21), С. 14443 - 14460
Опубликована: Янв. 1, 2023
This
review
summarizes
the
common
inorganic
and
organic
photothermal
nanoagents
their
applications
in
tumor
therapy.
Additionally,
challenges
future
prospects
of
nanomaterial-based
therapy
cancer
treatment
are
discussed.
Advanced Functional Materials,
Год журнала:
2023,
Номер
33(29)
Опубликована: Июнь 9, 2023
Abstract
Growing
concern
about
photothermal
tumor
therapy
(PTT)
as
a
promising
alternative
to
conventional
liver
cancer
treatment,
which
is
treatment
strategy
that
utilizes
near‐infrared
(NIR)
light‐induced
agents
(PTAs)
yield
effects
localize
thermal
damage
for
tumors.
Herein,
given
the
gap
between
experimental
research
and
clinical
application,
this
review
seeks
timely
summarize
highlight
recent
progress
of
PTAs
used
in
vivo
vitro
last
five‐year.
The
implications
various
on
multifunctional
conversion
capability,
structure‐performance
correlations
PTT,
together
with
evaluation
their
potential
application
are
systematically
dissected
further
dig
out
what
buried
mechanism
is.
Besides,
higher
requirements
put
forward
discrepancies
crucial
issues
faced
by
different
PTT
related
medical
technical
obstacles
being
conquered,
lays
solid
theoretical
foundation
field
oncology
whole,
especially
cancer.
Finally,
it
expected
can
present
valuable
guidance
design
efficient,
photostability,
biosafety‐aware
anticancer
while
stepping
into
fast
traffic
lane
from
bench
bedside
foreseeable
future.
Journal of the American Chemical Society,
Год журнала:
2023,
Номер
145(9), С. 5474 - 5485
Опубликована: Фев. 22, 2023
Stable
redox-active
conjugated
molecules
with
exceptional
electron-donating
abilities
are
key
components
for
the
design
and
synthesis
of
ultralow
band
gap
polymers.
While
hallmark
electron-rich
examples
such
as
pentacene
derivatives
have
been
thoroughly
explored,
their
poor
air
stability
has
hampered
broad
incorporation
into
polymers
practical
applications.
Herein,
we
describe
electron-rich,
fused
pentacyclic
pyrazino[2,3-b:5,6-b']diindolizine
(PDIz)
motif
detail
its
optical
redox
behavior.
The
PDIz
ring
system
exhibits
a
lower
oxidation
potential
reduced
than
isoelectronic
while
retaining
greater
in
both
solution
solid
state.
enhanced
electron
density,
together
readily
installed
solubilizing
groups
polymerization
handles,
allow
use
series
gaps
small
0.71
eV.
tunable
absorbance
throughout
biologically
relevant
near-infrared
I
II
regions
enables
these
PDIz-based
efficient
photothermal
therapeutic
reagents
laser
ablation
cancer
cells.
Advanced Functional Materials,
Год журнала:
2024,
Номер
34(38)
Опубликована: Апрель 23, 2024
Abstract
Currently,
microbial
infections
have
posed
an
arduous
challenge
to
global
public
health,
whereas
the
rise
of
antibiotic
resistance
is
rendering
traditional
therapies
futile,
prompting
development
new
antimicrobial
technologies.
Photoactive
nanomaterials
thus
garnered
a
thriving
interest
for
disinfection
owing
their
superior
antibacterial
efficaciousness,
favorable
biosafety,
and
rapidness
spatiotemporal
precision
in
excreting
bactericidal
actions.
The
review
summarizes
recent
advances
emerging
trends
design,
nanoengineering,
bioapplications
photoactive
antimicrobials.
It
commences
by
elaborating
fundamental
theories
on
bacterial
resistance,
mechanisms
phototherapy.
Subsequently,
regulation
effectiveness
comprehensively
discussed,
centering
criteria
strategies
tuning
photoabsorption
spectra,
photothermal
conversion,
photocatalytic
efficiency,
alongside
tactics
enabling
synergistic
therapies.
This
followed
comparative
analyses
techniques
modalities
synthesizing
engineering
with
diverse
structures,
forms,
functionalities.
Thereafter,
state‐of‐the‐art
applications
phototherapies
across
various
medical
sectors
are
portrayed,
key
challenges
opportunities
finally
discussed
spur
future
innovations
translation.
envisaged
provide
useful
guidance
devising
developing
nanomaterials‐based
photoresponsive
antimicrobials
application‐specific
materials
properties
biological
functions.
Angewandte Chemie International Edition,
Год журнала:
2024,
Номер
63(11)
Опубликована: Янв. 16, 2024
Abstract
Achieving
photothermal
therapy
(PTT)
at
ultralow
laser
power
density
is
crucial
for
minimizing
photo‐damage
and
allowing
higher
maximum
permissible
skin
exposure.
However,
this
requires
agents
to
possess
not
just
superior
conversion
efficiency
(PCE),
but
also
exceptional
near‐infrared
(NIR)
absorptivity.
J
‐aggregates,
exhibit
a
significant
redshift
narrower
absorption
peak
with
extinction
coefficient.
Nevertheless,
achieving
predictable
‐aggregates
through
molecular
design
remains
challenge.
In
study,
we
successfully
induced
desirable
J‐
aggregation
(λ
abs
max
:
968
nm,
ϵ:
2.96×10
5
M
−1
cm
,
λ
em
972
Φ
FL
6.2
%)
by
tuning
electrostatic
interactions
between
π‐conjugated
planes
manipulating
surface
potential
of
aromatic
ring‐fused
aza‐BODIPY
dyes.
Notably,
controlling
the
preparation
method
encapsulating
dyes
into
F‐127
polymer,
were
able
selectively
generate
H
‐/
respectively.
Furthermore,
exhibited
two
controllable
morphologies:
nanospheres
nanowires.
Importantly,
shortwave‐infrared
‐aggregated
nanoparticles
impressive
PCE
72.9
%
effectively
destroyed
cancer
cells
mice‐tumors
an
0.27
W
−2
(915
nm).
This
phototherapeutic
nano‐platform,
which
generates
behavior,
can
controllably
form
/
H‐
aggregates
selectable
aggregate
morphology,
valuable
paradigm
developing
tumor‐treatment
density.