Multispatially Localized DNA Walker Coupling Covalent Organic Framework for Dual-Mode Detection of Nucleocapsid Protein Using the Walking-Recycling-Conversion Strategy DOI

Guan-Xia Qiu,

Yuqi Wang, Wanwan Zhang

и другие.

Analytical Chemistry, Год журнала: 2024, Номер 96(46), С. 18464 - 18473

Опубликована: Ноя. 6, 2024

DNA walkers have emerged as a powerful tool in bioanalysis; however, many existing approaches are still restricted by low reaction kinetics and inaccurate single-mode detection. Herein, fluorescence (FL) electrochemical (EC) dual-mode biosensor was proposed based on multispatially localized walker (m-DNA walker) coupling covalent organic framework (COF) using the walking-recycling-conversion strategy. Specifically, functionalized COF not only served three-dimensional nanocarrier but also acted an effective quencher of walking tracks. In presence target, activated m-DNA moved fast along numerous quenching tracks, leading to cleavage Cy3-H1 recovery FL signal. To further improve detection sensitivity, fragments' recycling process implemented with generation large amount S1 S2, which caused assembly DNA-Fe

Язык: Английский

DNA nanotechnology in tumor liquid biopsy: Enrichment and determination of circulating biomarkers DOI Creative Commons

Yitong Zhu,

Wenbin Li,

Fei Lan

и другие.

Deleted Journal, Год журнала: 2023, Номер 2(1)

Опубликована: Дек. 19, 2023

Abstract Monitoring tumor biomarkers in a non‐invasive manner for diagnosis has attracted increasing attention. Liquid biopsy mainly includes three types of biomarkers: circulating cells, extracellular vesicles, and nucleic acids. These released by cells can travel to other parts the circulation system. The analysis markers enables early diagnosis, progression evolution, treatment monitoring, which are important individualized clinical decisions. In this study, we summarize different DNA nanotechnology strategies that be used capture, amplify, measure discuss current challenges outlook.

Язык: Английский

Процитировано

23

Applications and Prospects of Micro/nanoelectrodes in Single-cell Imaging and Electrochemical Detection DOI
Xiaoyang Zhang, Ke Huang, Xiangdong Lai

и другие.

TrAC Trends in Analytical Chemistry, Год журнала: 2025, Номер unknown, С. 118161 - 118161

Опубликована: Янв. 1, 2025

Язык: Английский

Процитировано

0

The Trend of Nonenzymatic Nucleic Acid Amplification: Strategies and Diagnostic Application DOI Creative Commons
Junyou Li,

Ting Li,

Zheng Zou

и другие.

Precision Chemistry, Год журнала: 2025, Номер 3(4), С. 187 - 205

Опубликована: Март 3, 2025

Nonenzymatic nucleic acid amplification reactions, especially nonenzymatic DNA reactions (NDARs), are thermodynamically driven processes that operate without enzymes, relying on toehold-mediated strand displacement (TMSD) and branch migration. With their sensitive efficient signal capabilities, NDARs have become essential tools for biomarker detection intracellular imaging. They encompass four primary methods: catalytic hairpin assembly (CHA), hybridization chain reaction (HCR), DNAzyme-based amplification, entropy-driven circuits (EDC). Based mechanisms, can be categorized into three types: stimuli-responsive NDARs, which employ single strategies triggered by specific stimuli like pH, light, or biomolecules; cascade integrate two more stepwise enhancement; autocatalytic achieve exponential through self-sustained cycling. These advanced designs progressively improve efficiency, enhance sensitivity, minimize background noise, enabling precise of proteins, viruses, acids as well applications in cancer cell imaging therapy. Compared with classical these approaches significantly reduce leakage, offering broader applicability diagnostics, imaging, therapeutic contexts. This review summarizes recent advancements, addresses existing challenges, explores future directions, providing insights the development NDARs.

Язык: Английский

Процитировано

0

Electrochemical Biosensors for Cancer Diagnosis: Multitarget Analysis to Present Molecular Characteristics of Tumor Heterogeneity DOI Creative Commons
Ya Cao, Jianan Xia, Lijuan Li

и другие.

JACS Au, Год журнала: 2024, Номер 4(12), С. 4655 - 4672

Опубликована: Дек. 11, 2024

Electrochemical biosensors are gaining attention as powerful tools in cancer diagnosis, particularly liquid biopsy, due to their high efficiency, rapid response, exceptional sensitivity, and specificity. However, the complexity of intra- intertumor heterogeneity, with variations genetic protein expression profiles epigenetic modifications, makes electrochemical susceptible false-positive or false-negative diagnostic outcomes. To address this challenge, there is growing interest simultaneously analyzing multiple biomarkers reveal molecular characteristics tumor heterogeneity for precise diagnosis. In Perspective, we highlight recent advancements utilizing a specific emphasis on multitarget analysis including tumor-associated nucleic acids, markers, extracellular vesicles, cells. These hold significant promise improving precision early diagnosis monitoring, well potentially offering new insights into personalized management.

Язык: Английский

Процитировано

3

Dual-Targeting PET Tracers Enable Enzyme-Mediated Self-Assembly for the PET Imaging of Legumain Activity DOI

Chunmei Lu,

Ke Li,

Hongjie Xi

и другие.

ACS Applied Materials & Interfaces, Год журнала: 2023, Номер 15(38), С. 44654 - 44664

Опубликована: Сен. 13, 2023

Legumain, a lysosomal cysteine protease overexpressed in variety of tumors, has been considered promising biomarker for various cancers. Precise detection legumain activity the lysosome represents an important strategy early diagnosis and prognosis tumors. Small-molecule probes with property target-enabled self-assembly hold great potential molecular imaging. In this study, we reported two dual-targeting radiotracers ([18F]SF-AAN-M [18F]SF-AAN-HEM) legumain-mediated positron emission tomography (PET) Both were synthesized high labeling yield (>50%) radiochemical purity was over 99% via one-step straightforward 18F-labeling. tracers efficiently activated by reducing agent to self-assemble into aggregates showed enhanced retention legumain-overexpressed MDA-MB-468 cells indicating that introduction lysosome-targeting morpholine increased tumor uptake extended addition, [18F]SF-AAN-HEM hydrophilic (histidine-glutamate)3 tag displayed significantly reduced liver no conspicuous reduction uptake, affording signal-to-noise ratios (tumor/liver tumor/muscle). All these results suggest tracer could provide tool vivo monitoring

Язык: Английский

Процитировано

5

Protease-activatable nanoprobe based on peptide decorated Titanium carbide engineering for synchronous monitoring of cancer biomarkers with different spatial distributions DOI
Qi Zhang,

Hailan Jia,

Dongxue Chen

и другие.

Chemical Engineering Journal, Год журнала: 2024, Номер unknown, С. 157896 - 157896

Опубликована: Ноя. 1, 2024

Язык: Английский

Процитировано

1

Multispatially Localized DNA Walker Coupling Covalent Organic Framework for Dual-Mode Detection of Nucleocapsid Protein Using the Walking-Recycling-Conversion Strategy DOI

Guan-Xia Qiu,

Yuqi Wang, Wanwan Zhang

и другие.

Analytical Chemistry, Год журнала: 2024, Номер 96(46), С. 18464 - 18473

Опубликована: Ноя. 6, 2024

DNA walkers have emerged as a powerful tool in bioanalysis; however, many existing approaches are still restricted by low reaction kinetics and inaccurate single-mode detection. Herein, fluorescence (FL) electrochemical (EC) dual-mode biosensor was proposed based on multispatially localized walker (m-DNA walker) coupling covalent organic framework (COF) using the walking-recycling-conversion strategy. Specifically, functionalized COF not only served three-dimensional nanocarrier but also acted an effective quencher of walking tracks. In presence target, activated m-DNA moved fast along numerous quenching tracks, leading to cleavage Cy3-H1 recovery FL signal. To further improve detection sensitivity, fragments' recycling process implemented with generation large amount S1 S2, which caused assembly DNA-Fe

Язык: Английский

Процитировано

0