Angewandte Chemie International Edition,
Год журнала:
2023,
Номер
62(44)
Опубликована: Апрель 28, 2023
Mechanochemistry
provides
an
environmentally
benign
platform
to
develop
more
sustainable
chemical
processes
by
limiting
raw
materials,
energy
use,
and
waste
generation
while
using
physically
smaller
equipment.
A
continuously
growing
research
community
has
steadily
showcased
examples
of
beneficial
mechanochemistry
applications
at
both
the
laboratory
preparative
scale.
In
contrast
solution-based
chemistry,
mechanochemical
have
not
yet
been
standardized,
thus
scaling
up
is
still
a
nascent
discipline.
The
purpose
this
Minireview
highlight
similarities,
differences
challenges
various
approaches
that
successfully
applied
for
range
scales.
We
hope
provide
discussion
starting
point
those
interested
in
further
developing
commercial
use
and/or
industrialisation.
Angewandte Chemie International Edition,
Год журнала:
2019,
Номер
59(3), С. 1018 - 1029
Опубликована: Июль 11, 2019
Abstract
Mechanochemical
solvent‐free
reactions
by
milling,
grinding
or
other
types
of
mechanical
action
have
emerged
as
a
viable
alternative
to
solution
chemistry.
Mechanochemistry
offers
not
only
possibility
eliminate
the
need
for
bulk
solvent
use,
and
reduce
generation
waste,
but
it
also
unlocks
door
different
reaction
environment
in
which
synthetic
strategies,
molecules
previously
accessible
solution,
can
be
achieved.
This
Minireview
examines
potential
mechanochemistry
chemical
materials
synthesis,
providing
cross‐section
recent
developments
using
ball
milling
formation
based
on
covalent
coordination
bonds.
Chemical Society Reviews,
Год журнала:
2019,
Номер
48(8), С. 2274 - 2292
Опубликована: Янв. 1, 2019
In
the
last
few
decades,
mechanochemistry
has
become
rapidly
established
as
a
powerful
tool
enabling
environmentally-benign
and
sustainable
chemical
syntheses.
Not
only
have
these
techniques
been
demonstrated
viable
alternatives
to
traditional
solution-based
syntheses,
but
they
also
received
attention
for
their
ability
enable
new
reactivity
"unlocking"
novel
compounds
inaccessible
by
conventional
methods.
Reflecting
rising
popularity
of
mechanochemistry,
many
excellent
reviews
highlighting
its
benefits
recently
published.
Whilst
scope
most
focuses
on
organic
chemistry,
transition-metal
catalysis,
porous
framework
materials,
coordination
supramolecular
synthesis,
addressed
use
mechanochemical
ball
milling
synthesis
containing
s-
p-block
elements.
This
tutorial
review
turns
spotlight
towards
research
in
field
inorganic
main
group
significant
advantages
that
solid-state
reactions
often
possess,
potential
drive
development
greener
methodologies
within
modern
arena.
ChemSusChem,
Год журнала:
2021,
Номер
14(10), С. 2145 - 2162
Опубликована: Апрель 9, 2021
In
recent
years,
mechanochemistry
has
been
growing
into
a
widely
accepted
alternative
for
chemical
synthesis.
addition
to
their
efficiency
and
practicality,
mechanochemical
reactions
are
also
recognized
sustainability.
The
association
between
Green
Chemistry
often
originates
from
the
solvent-free
nature
of
most
protocols,
which
can
reduce
waste
production.
However,
satisfies
more
than
one
Principles
Chemistry.
this
Review
we
will
present
series
examples
that
clearly
illustrate
how
significantly
contribute
fulfillment
in
holistic
manner.
Science,
Год журнала:
2019,
Номер
366(6472), С. 1500 - 1504
Опубликована: Дек. 20, 2019
Over
the
past
decade,
photoredox
catalysis
has
harnessed
light
energy
to
accelerate
bond-forming
reactions.
We
postulated
that
a
complementary
method
for
redox-activation
of
small
organic
molecules
in
response
applied
mechanical
could
be
developed
through
piezoelectric
effect.
Here,
we
report
agitation
materials
via
ball
milling
reduces
aryl
diazonium
salts.
This
mechanoredox
system
can
arylation
and
borylation
reactions
under
mechanochemical
conditions.
Angewandte Chemie International Edition,
Год журнала:
2018,
Номер
58(11), С. 3285 - 3299
Опубликована: Ноя. 12, 2018
Abstract
In
recent
years,
the
application
of
mechanical
energy
to
chemical
systems
has
repeatedly
proven
beneficial
facilitate
transformations
in
various
areas
chemistry.
Today,
a
systematic
body
evidence
indicates
that
mechanochemistry
holds
great
promise
become
game‐changer
synthesis.
Not
only
does
permit
access
products
are
inaccessible
by
established
means
(e.g.
purely
thermal
activation),
mechanochemical
reactions
often
outperform
their
solution‐based
counterparts
terms
sustainability.
Most
carried
out
ball
milling
techniques
involve
solids
and
liquids,
but
number
with
gaseous
reactants
is
increasing.
The
aim
this
Minireview
provide
an
overview
involving
samples
highlight
advances
technology
for
safe
handling
reagents.
Examples
proceeding
at
interface
solid–/liquid–/gas–gas
led
significant
improvements
reactivity
or
selectivity
will
also
be
highlighted.
Angewandte Chemie,
Год журнала:
2019,
Номер
132(3), С. 1030 - 1041
Опубликована: Июль 11, 2019
Abstract
Mechanochemical
solvent‐free
reactions
by
milling,
grinding
or
other
types
of
mechanical
action
have
emerged
as
a
viable
alternative
to
solution
chemistry.
Mechanochemistry
offers
not
only
possibility
eliminate
the
need
for
bulk
solvent
use,
and
reduce
generation
waste,
but
it
also
unlocks
door
different
reaction
environment
in
which
synthetic
strategies,
molecules
previously
accessible
solution,
can
be
achieved.
This
Minireview
examines
potential
mechanochemistry
chemical
materials
synthesis,
providing
cross‐section
recent
developments
using
ball
milling
formation
based
on
covalent
coordination
bonds.
