Green Chemistry, Год журнала: 2022, Номер 24(4), С. 1721 - 1731
Опубликована: Янв. 1, 2022
Co 9 S 8 –Ni 3 2 @N,S,O-tri-doped carbon heterostructures, prepared by pyrolysis of the designed deep eutectic solvents, exhibited excellent electrooxidation performance 5-hydroxymethylfurfural to produce 2,5-furandicarboxylic acid.
Язык: Английский
Cell Reports Physical Science, Год журнала: 2022, Номер 3(4), С. 100809 - 100809
Опубликована: Март 15, 2022
Energy and environmental issues are increasingly prominent, sustainable synthetic strategies needed in response. As a class of green easily modified solvent, deep eutectic solvents (DESs) may contribute to this goal. Composed monomers from biological sources, they biodegradable with low toxicity, facilitating large-scale use. Indeed, their applications already widespread on both the laboratory industrial scales. This review focuses application DESs materials synthesis. After brief summary use organic synthesis, four for synthesis surveyed: solvothermal methods, electrodeposition, calcination, polymerization. Materials synthesized using expected find among academia industry.
Язык: Английский
Процитировано
120
Global Challenges, Год журнала: 2022, Номер 6(12)
Опубликована: Июнь 22, 2022
The overuse and exploitation of fossil fuels has triggered the energy crisis caused tremendous issues for society. Lithium-ion batteries (LIBs), as one most important renewable storage technologies, have experienced booming progress, especially with drastic growth electric vehicles. To avoid massive mineral mining opening new mines, battery recycling to extract valuable species from spent LIBs is essential development energy. Therefore, needs be widely promoted/applied advanced technology low consumption, emission, green reagents highlighted. In this review, necessity first discussed several different aspects. Second, various technologies that are currently used, such pyrometallurgical hydrometallurgical methods, summarized evaluated. Then, based on challenges above authors look further forward some cutting-edge direct repair regeneration. addition, also discuss prospects selected strategies next-generation solid-state Li-metal batteries. Finally, overall conclusions future perspectives sustainability devices presented in last chapter.
Язык: Английский
Процитировано
112
Advanced Materials, Год журнала: 2023, Номер 36(3)
Опубликована: Ноя. 1, 2023
Aqueous batteries are emerging as highly promising contenders for large-scale grid energy storage because of uncomplicated assembly, exceptional safety, and cost-effectiveness. The unique aqueous electrolyte with a rich hydrogen bond (HB) environment inevitably has significant impact on the electrode materials electrochemical processes. While numerous reviews have focused design assembly batteries, utilization HB chemistry is overlooked. Herein, instead merely compiling recent advancements, this review presents comprehensive summary analysis profound implication exerted by all components batteries. Intricate links between novel various ingeniously constructed within critical aspects, such self-discharge, structural stability materials, pulverization, solvation structures, charge carrier diffusion, corrosion reactions, pH sensitivity, water splitting, polysulfides shuttle, H
Язык: Английский
Процитировано
80
Industrial Crops and Products, Год журнала: 2022, Номер 184, С. 115049 - 115049
Опубликована: Май 9, 2022
Язык: Английский
Процитировано
76
Journal of Cleaner Production, Год журнала: 2022, Номер 345, С. 131028 - 131028
Опубликована: Фев. 21, 2022
Язык: Английский
Процитировано
74
Green Chemistry, Год журнала: 2024, Номер 26(7), С. 3627 - 3669
Опубликована: Янв. 1, 2024
Deep eutectic solvents (DESs) enable many processes to be environmentally friendly. This Tutorial Review aims showcase the roles of DESs in synthesis functional materials from a green chemistry perspective.
Язык: Английский
Процитировано
57
Industrial & Engineering Chemistry Research, Год журнала: 2023, Номер 62(29), С. 11723 - 11734
Опубликована: Июль 18, 2023
Deep eutectic solvents (DESs) have attracted significant interest in dissolving lignocellulosic components. However, revealing the relationship between solvation properties of DESs and their ability to dissolve components remains a challenge. Herein, 56 were prepared applied This revealed that Kamlet–Taft parameters (i.e., α, β, π*) significantly affected by structures DESs. More notably, correlation solubility varied with Concretely, greater values β β–α (net basicity), are expected cellulose efficiently, net basicity, favorable lignin, xylan was linearly correlated value. These findings provided valuable information necessary theoretical guidance on designing robust based solvatochromic parameters.
Язык: Английский
Процитировано
53
Separation and Purification Technology, Год журнала: 2023, Номер 330, С. 125498 - 125498
Опубликована: Окт. 24, 2023
Язык: Английский
Процитировано
48
Green Chemical Engineering, Год журнала: 2023, Номер 5(4), С. 409 - 417
Опубликована: Ноя. 28, 2023
Green solvents such as water and ionic liquids (ILs) are pillars of the great mansion green chemistry processing. Initially proposed a new family ILs, deep eutectic (DESs) have received fast development in past two decades. In this contribution, DESs reviewed critically concept is extended to low-melting mixture (LoMMSs), which cover all kinds materials including compounds, molecular metals. Six classes LoMMSs classification system examples given. Finally, several thermodynamic issues concerning discussed. Two concepts, robustness high-entropy LoMMSs, proposed.
Язык: Английский
Процитировано
48
The Science of The Total Environment, Год журнала: 2023, Номер 902, С. 166095 - 166095
Опубликована: Авг. 8, 2023
Язык: Английский
Процитировано
47