Controllable and facile preparation of Co9S8–Ni3S2 heterostructures embedded with N,S,O-tri-doped carbon for electrocatalytic oxidation of 5-hydroxymethylfurfural DOI
Yibin Zhang, Zhimin Xue, Xinhui Zhao

et al.

Green Chemistry, Journal Year: 2022, Volume and Issue: 24(4), P. 1721 - 1731

Published: Jan. 1, 2022

Co 9 S 8 –Ni 3 2 @N,S,O-tri-doped carbon heterostructures, prepared by pyrolysis of the designed deep eutectic solvents, exhibited excellent electrooxidation performance 5-hydroxymethylfurfural to produce 2,5-furandicarboxylic acid.

Language: Английский

Deep eutectic solvents as a green toolbox for synthesis DOI Creative Commons
Dongkun Yu, Zhimin Xue, Tiancheng Mu

et al.

Cell Reports Physical Science, Journal Year: 2022, Volume and Issue: 3(4), P. 100809 - 100809

Published: March 15, 2022

Energy and environmental issues are increasingly prominent, sustainable synthetic strategies needed in response. As a class of green easily modified solvent, deep eutectic solvents (DESs) may contribute to this goal. Composed monomers from biological sources, they biodegradable with low toxicity, facilitating large-scale use. Indeed, their applications already widespread on both the laboratory industrial scales. This review focuses application DESs materials synthesis. After brief summary use organic synthesis, four for synthesis surveyed: solvothermal methods, electrodeposition, calcination, polymerization. Materials synthesized using expected find among academia industry.

Language: Английский

Citations

119
Progress, Key Issues, and Future Prospects for Li‐Ion Battery Recycling DOI
Xiaoxue Wu, Jun Ma, Junxiong Wang

et al.

Global Challenges, Journal Year: 2022, Volume and Issue: 6(12)

Published: June 22, 2022

The overuse and exploitation of fossil fuels has triggered the energy crisis caused tremendous issues for society. Lithium-ion batteries (LIBs), as one most important renewable storage technologies, have experienced booming progress, especially with drastic growth electric vehicles. To avoid massive mineral mining opening new mines, battery recycling to extract valuable species from spent LIBs is essential development energy. Therefore, needs be widely promoted/applied advanced technology low consumption, emission, green reagents highlighted. In this review, necessity first discussed several different aspects. Second, various technologies that are currently used, such pyrometallurgical hydrometallurgical methods, summarized evaluated. Then, based on challenges above authors look further forward some cutting-edge direct repair regeneration. addition, also discuss prospects selected strategies next-generation solid-state Li-metal batteries. Finally, overall conclusions future perspectives sustainability devices presented in last chapter.

Language: Английский

Citations

109
Comprehensive Understandings of Hydrogen Bond Chemistry in Aqueous Batteries DOI
Ming Li, Xuanpeng Wang, Jiashen Meng

et al.

Advanced Materials, Journal Year: 2023, Volume and Issue: 36(3)

Published: Nov. 1, 2023

Aqueous batteries are emerging as highly promising contenders for large-scale grid energy storage because of uncomplicated assembly, exceptional safety, and cost-effectiveness. The unique aqueous electrolyte with a rich hydrogen bond (HB) environment inevitably has significant impact on the electrode materials electrochemical processes. While numerous reviews have focused design assembly batteries, utilization HB chemistry is overlooked. Herein, instead merely compiling recent advancements, this review presents comprehensive summary analysis profound implication exerted by all components batteries. Intricate links between novel various ingeniously constructed within critical aspects, such self-discharge, structural stability materials, pulverization, solvation structures, charge carrier diffusion, corrosion reactions, pH sensitivity, water splitting, polysulfides shuttle, H

Language: Английский

Citations

75
Lignin dissolution and lignocellulose pretreatment by carboxylic acid based deep eutectic solvents DOI
Haitao Yu, Zhimin Xue,

Ruifen Shi

et al.

Industrial Crops and Products, Journal Year: 2022, Volume and Issue: 184, P. 115049 - 115049

Published: May 9, 2022

Language: Английский

Citations

74
Preparation strategy and stability of deep eutectic solvents: A case study based on choline chloride-carboxylic acid DOI
Man Zhang,

Rubo Tian,

Hui Han

et al.

Journal of Cleaner Production, Journal Year: 2022, Volume and Issue: 345, P. 131028 - 131028

Published: Feb. 21, 2022

Language: Английский

Citations

70
Deep eutectic solvents as an emerging green platform for the synthesis of functional materials DOI
Yunping Ma, Yang Yu, Tie Li

et al.

Green Chemistry, Journal Year: 2024, Volume and Issue: 26(7), P. 3627 - 3669

Published: Jan. 1, 2024

Deep eutectic solvents (DESs) enable many processes to be environmentally friendly. This Tutorial Review aims showcase the roles of DESs in synthesis functional materials from a green chemistry perspective.

Language: Английский

Citations

53
Kamlet–Taft Parameters of Deep Eutectic Solvents and Their Relationship with Dissolution of Main Lignocellulosic Components DOI
Luyao Zhang, Haitao Yu, Shuo Liu

et al.

Industrial & Engineering Chemistry Research, Journal Year: 2023, Volume and Issue: 62(29), P. 11723 - 11734

Published: July 18, 2023

Deep eutectic solvents (DESs) have attracted significant interest in dissolving lignocellulosic components. However, revealing the relationship between solvation properties of DESs and their ability to dissolve components remains a challenge. Herein, 56 were prepared applied This revealed that Kamlet–Taft parameters (i.e., α, β, π*) significantly affected by structures DESs. More notably, correlation solubility varied with Concretely, greater values β β–α (net basicity), are expected cellulose efficiently, net basicity, favorable lignin, xylan was linearly correlated value. These findings provided valuable information necessary theoretical guidance on designing robust based solvatochromic parameters.

Language: Английский

Citations

51
Recyclable deep eutectic solvents for recycling LiCoO2 from spent lithium-ion batteries with high selectivity DOI

Yaozhi Zhang,

Fang Wang, Wanxiang Zhang

et al.

Separation and Purification Technology, Journal Year: 2023, Volume and Issue: 330, P. 125498 - 125498

Published: Oct. 24, 2023

Language: Английский

Citations

47
Recycling of waste lithium-ion batteries via a one-step process using a novel deep eutectic solvent DOI
Yi Luo,

Chengzhe Yin,

Leming Ou

et al.

The Science of The Total Environment, Journal Year: 2023, Volume and Issue: 902, P. 166095 - 166095

Published: Aug. 8, 2023

Language: Английский

Citations

46
Low-melting mixture solvents: extension of deep eutectic solvents and ionic liquids for broadening green solvents and green chemistry DOI Creative Commons
Yu Chen, Zhi‐Wu Yu

Green Chemical Engineering, Journal Year: 2023, Volume and Issue: 5(4), P. 409 - 417

Published: Nov. 28, 2023

Green solvents such as water and ionic liquids (ILs) are pillars of the great mansion green chemistry processing. Initially proposed a new family ILs, deep eutectic (DESs) have received fast development in past two decades. In this contribution, DESs reviewed critically concept is extended to low-melting mixture (LoMMSs), which cover all kinds materials including compounds, molecular metals. Six classes LoMMSs classification system examples given. Finally, several thermodynamic issues concerning discussed. Two concepts, robustness high-entropy LoMMSs, proposed.

Language: Английский

Citations

43