Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 496, P. 153865 - 153865
Published: July 9, 2024
Language: Английский
Journal of Energy Storage, Journal Year: 2024, Volume and Issue: 82, P. 110550 - 110550
Published: Jan. 18, 2024
Language: Английский
Citations
48
Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 482, P. 148807 - 148807
Published: Jan. 17, 2024
Language: Английский
Citations
42
Chemical Society Reviews, Journal Year: 2024, Volume and Issue: 53(15), P. 7742 - 7783
Published: Jan. 1, 2024
Aqueous Zn-metal batteries have attracted increasing interest for large-scale energy storage owing to their outstanding merits in terms of safety, cost and production. However, they constantly suffer from inadequate density poor cycling stability due the presence zinc ions fully hydrated solvation state. Thus, designing dehydrated structure can effectively address current drawbacks aqueous batteries. In this case, considering lack studies focused on strategies dehydration ions, herein, we present a systematic comprehensive review deepen understanding zinc-ion regulation. Two fundamental design principles component regulation pre-desolvation are summarized environment formation interfacial desolvation behavior. Subsequently, specific strategy based distinct carefully discussed, including preparation methods, working mechanisms, analysis approaches performance improvements. Finally, general summary issues addressed using strategies, four critical aspects promote presented as an outlook, involving updating (de)solvation theories, revealing evolution, enhancing techniques developing functional materials. We believe that will not only stimulate more creativity optimizing electrolytes but also provide valuable insights into other battery systems.
Language: Английский
Citations
42
Energy storage materials, Journal Year: 2024, Volume and Issue: 68, P. 103364 - 103364
Published: March 24, 2024
Language: Английский
Citations
39
Journal of Energy Storage, Journal Year: 2024, Volume and Issue: 85, P. 111040 - 111040
Published: March 1, 2024
Electrolyte is a crucial component in electrochemical energy storage devices (EESDs) such as rechargeable batteries and supercapacitors (SCs). While substantial effort has been directed to engineering the electrodes, fewer but effective continuous efforts have devoted improve devices' performance through modification of their electrolytes. Among these approaches, strategic integration minor amounts additives led formation appropriate solid-electrolyte interphase (SEI) cathode-electrolyte (CEI), well modifying ionic conductivity, preventing dendrite growth, improving charge kinetics. various electrolytes, carbon quantum dots (CDs) graphene (GQDs) emerged favorable options due positive influence on electrolytes for EESDs. These QDs are soluble specific solvents numerous functional moieties allow them act electrolyte polyanions. Furthermore, excellent physiochemical properties make candidates fillers solid-state The excellence verified by characterization methods affirming parameters ion-diffusion kinetics, capacity, resistance. application CDs GQDs EESDs new ruling mechanisms not well-known yet. This review article provides an overview both liquid solid lithium-, sodium-, potassium-, zinc-ion lithium metal besides SCs. Herein, we aim offer valuable insights into designing fabricating class based realizing novel
Language: Английский
Citations
24
Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(26)
Published: Feb. 29, 2024
Abstract Aqueous Zn metal batteries are emerging as a promising candidate for the next‐generation largescale energy storage system due to their high safety, low lost, and eco‐friendliness. Nevertheless, practical application is restricted by uncontrollable dendrite growth limited utilization of anode. Herein, room temperature electrodeposition strategy based on an optimized rate relationship between diffusion consumption Cu 2+ prepare (111)‐textured current collector construction dendrite‐free anode with reversibility developed. Attributed lattice match (002) facet (111) Cu, deposition along its [001] orientation achieved Cu. The facets horizontally aligned endow planar superior corrosion resistance, resulting in long life‐span over 2186 cycles. Impressively, resultant anodes can stabilize operation pouch cells extremely demanding negative‐to‐positive capacity ratio 2. This work provides new avenue development collectors low‐cost sustainable storage.
Language: Английский
Citations
23
Advanced Energy Materials, Journal Year: 2024, Volume and Issue: unknown
Published: March 4, 2024
Abstract Electrolytes play a crucial role in facilitating the ionic movement between cathode and anode, which is essential for flow of electric current during charging discharging process rechargeable batteries. In particular, electrolyte additives are considered as effective economical approaches into advancements battery technologies both conventional non‐aqueous burgeoning aqueous systems. Herein, systematic comprehensive review reported interfacial engineering Li Zn metal anodes electrolytes, respectively. The types their corresponding functionalities protection these two discussed along with electrochemical features solid interphase (SEI) derived from additives. recent progress on systems also addressed perspectives electrode, electrolyte, associated SEI. Finally, outlook perspective issues future directions field additive presented next‐generation beyond Li‐ion
Language: Английский
Citations
22
Advanced Energy Materials, Journal Year: 2024, Volume and Issue: 14(30)
Published: May 21, 2024
Abstract As the energy storage sector gains prominence, sodium batteries have garnered attention due to their affordability and abundance of raw materials. Among methods aimed at enhancing battery performance, electrolyte additives are notably cost‐effective. Despite typically comprising no more than 5% components, these play a crucial role in improving cycle life overall functionality. This review begins by analyzing factors propelling development diverse roles additives, extensively examines common functional groups (fluorine(F)‐containing, sulfonyl, sulfoxide, phosphate ester, nitrogenous, boron, silyl groups, etc.) additives. Furthermore, it categorizes latest into five distinct types. Lastly, provides an overview potential for designing that both sustainable efficient. comprehensive aims be valuable resource informing strategic selection enhancement thereby facilitating future progress field.
Language: Английский
Citations
18
Advanced Functional Materials, Journal Year: 2023, Volume and Issue: 33(42)
Published: Aug. 30, 2023
Abstract Uncontrolled Zn dendrites and undesirable side reactions such as self‐corrosion hydrogen evolution reaction (HER) remain major challenges for the further development of aqueous batteries (AZBs). In this study, macrolide antibiotics are proposed to be added electrolyte, serving ionophores modulate 2+ solvation structure, regulate electrodeposition, suppress parasitic reactions. Azithromycin (Azi), a representative antibiotic, is demonstrated undergo bidentate coordination with ions remodel structure into [ZnAzi(H 2 O) 4 ] . Meanwhile, HER at anode significantly suppressed, evidenced quantitatively by on‐line production monitoring. Furthermore, promotion dense uniform electrodeposition also confirmed. The repeated plating/stripping test 0.1 m Azi in electrolyte reaches high cumulative capacity 10 Ah cm −2 current density mA an area mAh Moreover, corresponding Zn‐V O 5 pouch cell achieves stable operation 100 cycles without bulging caused gas evolution. Thus, engineering approach presents practically viable strategy AZBs.
Language: Английский
Citations
40
Materials Today Physics, Journal Year: 2024, Volume and Issue: 45, P. 101453 - 101453
Published: May 7, 2024
Language: Английский
Citations
15