Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 359, P. 130550 - 130550
Published: Nov. 14, 2024
Language: Английский
Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 359, P. 130550 - 130550
Published: Nov. 14, 2024
Language: Английский
Nature Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 6, 2025
Language: Английский
Citations
7Chemical Engineering Science, Journal Year: 2025, Volume and Issue: unknown, P. 121148 - 121148
Published: Jan. 1, 2025
Language: Английский
Citations
1ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 29, 2025
Sulfur dioxide (SO2), a pervasive air pollutant, poses significant environmental and health risks, necessitating advanced materials for its efficient capture. Nanoporous organic polymers (NOPs) have emerged as promising candidates; however, their development is often hindered by high synthesis temperatures, complex precursors, limited SO2 selectivity. Herein, we report room-temperature, cost-effective of carbazole-based nanoporous (CNOPs) using 1,3,5-trioxane paraldehyde, offering advancement over traditional Friedel-Crafts alkylation methods. The resulting CNOPs exhibit surface area up to 842 m2·g-1 feature ultramicroporous structures optimized adsorption. At 298 K 1 bar, the demonstrated adsorption capacities 9.39 mmol·g-1. Ideal adsorbed solution theory (IAST) calculations revealed outstanding selectivities 105 SO2/CO2 6139 SO2/N2 mixtures, supported breakthrough experiments demonstrating superior separation performance. This work not only provides straightforward synthetic route but also offers valuable insights into design porous tailored enhanced capture, addressing critical challenges.
Language: Английский
Citations
1Chinese Chemical Letters, Journal Year: 2024, Volume and Issue: unknown, P. 110172 - 110172
Published: June 1, 2024
Language: Английский
Citations
8Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 342, P. 126974 - 126974
Published: March 2, 2024
Language: Английский
Citations
7Small, Journal Year: 2024, Volume and Issue: 20(35)
Published: April 28, 2024
Abstract Porous ionic polymers with unique features have exhibited high performance in various applications. However, the fabrication of functional porous custom functionality and porosity for efficient removal low‐concentration SO 2 remains challenging. Herein, a novel nitrogen‐enriched polymer NH Py‐PIP is prepared featuring high‐content nitrogen sites (15.9 wt.%), adequate (1.22 mmol g −1 ), hierarchical structure. The proposed construction pathway relies on tailored nitrogen‐functionalized cross‐linker Py, which effectively introduces abundant improves polymers. well‐engineered ‐affinity environment achieves excellent /CO selectivity (1165) adsorption capacity (1.13 at 0.002 bar), as well enables highly reversible dynamic separation performance. Modeling studies further elucidate that bromide anions collaboratively promote preferential . design this work provides new insights into constructing high‐efficiency separations.
Language: Английский
Citations
5Microporous and Mesoporous Materials, Journal Year: 2024, Volume and Issue: 377, P. 113206 - 113206
Published: June 6, 2024
Language: Английский
Citations
5Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: unknown
Published: Nov. 27, 2024
The development of highly efficient sensors for low-concentration SO
Language: Английский
Citations
5Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 346, P. 127513 - 127513
Published: April 17, 2024
Language: Английский
Citations
4Talanta, Journal Year: 2024, Volume and Issue: 281, P. 126844 - 126844
Published: Sept. 10, 2024
Language: Английский
Citations
4